Radiation curable, ethylenically unsaturated thixotropic agent and method of preparation

Claim 2

A radiation curable thixotropic agent containing terminal ethylenic unsaturation of the formula: ##STR3## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanato groups; B is an aliphatic hydrocarbon containing 1-36 carbon atoms; X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR4## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10.

Claim 3

A composition comprising a liquid curable vehicle and about 5-15% by weight of the composition of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the formula: ##STR5## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanato groups; B is an aliphatic hydrocarbon containing 1-36 carbon atoms; X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR6## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10.

Claim 4

A composition comprising a liquid curable vehicle and about 5-15% by weight of the composition of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the formula: ##STR5## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanato groups; B is an aliphatic hydrocarbon containing 1-36 carbon atoms; X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR6## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10.

Claim 5

The composition of claim 2 wherein the liquid curable vehicle is about 98 to 2 percent by weight of a liquid polyene containing at least 2 reactive unsaturated carbon to carbon bonds per molecule and about 2 to 98 percent by weight of a polythiol containing at least 2 thiol groups per molecule, the total combined functionality of (a) the reactive terminal unsaturated carbon to carbon bonds per molecule in the polyene and (b) the thiol groups per molecule in the polythiol being greater than 4.

Claim 6

The composition of claim 3 including 1-20% by weight of a photosensitizer.

Claim 7

The composition of claim 2 wherein the liquid curable vehicle is an ethylenically unsaturated monomer.

Claim 8

The composition of claim 5 wherein the ethylenically unsaturated monomer is a member of a group consisting of acrylates, triacrylates, methacrylates, dimethacrylates, trimethacrylates and mixtures thereof.

Claim 9

The process of forming a varnished printed paper product which comprises feeding the paper product to a color offset press, applying at least one UV curable colored ink in the desired design to a surface of the paper product, wet trapping the applied ink with a UV curable overprint varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR7## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR8## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the overprint varnish and ink to UV radiation for a time sufficient to simultaneously cure the ink and varnish thereby forming a glossy, hard, cured coating on the printed surface.

Claim 10

The process of forming a varnished printed paper product which comprises feeding the paper product to a color offset press, applying at least one UV curable colored ink in the desired design to a surface of the paper product, wet trapping the applied ink with a UV curable overprint varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR7## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR8## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the overprint varnish and ink to UV radiation for a time sufficient to simultaneously cure the ink and varnish thereby forming a glossy, hard, cured coating on the printed surface.

Claim 11

The process of forming a varnished printed paper product which comprises feeding the paper product to a color offset press, applying at least one conventional solvent based colored ink in the desired design to a surface of the paper product, wet trapping the applied ink with a UV curable overprint varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR9## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR10## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the overprint varnish composition to UV radiation for a time sufficient to form a glossy, hard, cured coating on the printed paper product.

Claim 12

The process of forming a varnished printed paper product which comprises feeding the paper product to a color offset press, applying at least one conventional solvent based colored ink in the desired design to a surface of the paper product, wet trapping the applied ink with a UV curable overprint varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR9## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR10## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the overprint varnish composition to UV radiation for a time sufficient to form a glossy, hard, cured coating on the printed paper product.

Claim 13

The process of forming a varnished paper product which comprises applying to the surface of said paper product a U.V. curable varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR11## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR12## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the varnish to UV radiation for a time sufficient to cure the varnish thereby forming a glossy, hard, cured coating on the surface.

Claim 14

The process of forming a varnished paper product which comprises applying to the surface of said paper product a U.V. curable varnish composition comprising a liquid photocurable vehicle and about 5-15% by weight of the vehicle of a radiation curable thixotropic agent containing terminal ethylenic unsaturation of the general formula: ##STR11## wherein Q is the residue obtained by removal of H from primary OH groups of the reaction product from the esterification of a polyhydric alcohol containing primary OH groups with only a fatty carboxylic acid containing 4 to 26 carbon atoms in a saturated aliphatic hydrocarbon chain; R' is an aliphatic or aromatic polyvalent organic moiety of a polyisocyanate after reaction of the isocyanate groups, B is an aliphatic hydrocarbon containing 1-36 carbon atoms, X is a member of the group consisting of --OCH.sub.2 CH═CH.sub.2 --CH═CH.sub.2 and ##STR12## wherein R 1 is hydrogen or a methyl group and p and y are each integers from 1-10 and, thereafter, exposing the varnish to UV radiation for a time sufficient to cure the varnish thereby forming a glossy, hard, cured coating on the surface.

Claim 15

The process according to claim 9 wherein the surface of the paper product has printing ink thereon prior to the application of the UV curable varnish.