US4176212A
Expired / Lapsed
US
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Radiation and moisture curable compositions and method of use
Assignee: Design Cote Corp
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Filing: 1978-01-25
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Granted: 1979-11-27
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Expires: 1998-01-25
Abstract
Abstract Coating compositions which are curable by simultaneous or sequential exposure to radiation and moisture. In the case of pigmented compositions, rapid curing is initiated by exposure to moderate radiation and the cure completed by exposure to moisture. The various compositions include radiation reactive groups and moisture reactive oxazolidine and isocyanate groups. The moisture reactive and radiation curable groups preferably are interpolymerized during the curing process.
Inventors
- 👤 Karl Brack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 00:32
CPC Classifications
B; B05; B05D; B05D3/00; B05D3/06; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/62; C08G18/6283; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; Y; Y10; Y10S; Y10S524/00; Y10S524/901; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31855
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
28 words
A radiation curable coating composition which comprises a compound containing both radiation curable and moisture curable reaction groups, said composition also containing both an isocyanate and an oxazolidine.
Claim 2
Dependent Claim
28 words
A radiation curable coating composition which comprises a compound containing both radiation curable and moisture curable reaction groups, said composition also containing both an isocyanate and an oxazolidine.
Claim 3
Dependent Claim
53 words
The composition according to claim 1 wherein said reaction groups comprise isocyanates and oxazolidines, said oxazolidines having the formula: ##STR3## wherein "R'" represents a radiation-curable monomeric or polymeric radical containing ethylenic unsaturation or a bivalent radical; "m" represents an integer from 1 to 4; and "n" represents an integer from 1 to 10.
Claim 4
Dependent Claim
11 words
The composition of claim 2 wherein "R'" is a bivalent radical.
Claim 5
Dependent Claim
13 words
The composition of claim 3 wherein the bivalent radical represents 2 oxazolidine rings.
Claim 6
Dependent Claim
13 words
The composition of claim 2 wherein "R'" is a monomer containing ethylenic unsaturation.
Claim 7
Dependent Claim
13 words
The composition of claim 2 wherein "R'" is a polymer containing ethylenic unsaturation.
Claim 8
Dependent Claim
11 words
The composition of claim 2 which further contains a filler material.
Claim 9
Dependent Claim
43 words
The composition according to claim 1 comprising pigment dispersed in a solution of acrylate monomer, a prepolymer terminated with at least one acrylate group and at least one isocyanate group and one oxazolidine group, said composition being substantially free of volatile, inert solvent.
Claim 10
Dependent Claim
14 words
The composition according to claim 8 which further contains a photosensitizer for ultraviolet radiation.
Claim 11
Independent Claim
48 words
A method of coating or printing a substrate which comprises applying to said substrate a composition comprising a compound containing both radiation curable and moisture curable reaction groups, said composition also containing both an isocyanate and an oxazolidine and thereafter exposing said composition to radiation and to moisture.
Claim 12
Independent Claim
48 words
A method of coating or printing a substrate which comprises applying to said substrate a composition comprising a compound containing both radiation curable and moisture curable reaction groups, said composition also containing both an isocyanate and an oxazolidine and thereafter exposing said composition to radiation and to moisture.
Claim 13
Dependent Claim
37 words
The method of claim 10 which comprises exposing said composition to an amount of ultraviolet radiation effective to cure the surface thereof in order that said surface be substantially tack-free and thereafter exposing said composition to moisture.
Claim 14
Dependent Claim
52 words
The method of claim 10 wherein said reaction groups comprise isocyanates and oxazolidines, said oxazolidines having the formula: ##STR4## wherein "R'" represents a radiation-curable monomeric or polymeric radical containing ethylenic unsaturation or a bivalent radical; "m" represents an integer from 1 to 4; and "n" represents an integer from 1 to 10.
Claim 15
Dependent Claim
11 words
The method of claim 12 wherein "R'" is a bivalent radical.
Claim 16
Dependent Claim
13 words
The method of claim 13 wherein the bivalent radical represents 2 oxazolidine rings.
Claim 17
Dependent Claim
13 words
The method of claim 12 wherein "R'" is a monomer containing ethylenic unsaturation.
Claim 18
Dependent Claim
13 words
The method of claim 12 wherein "R'" is a polymer containing ethylenic unsaturation.
Claim 19
Dependent Claim
13 words
The method of claim 12 wherein the composition further contains a filler material.
Claim 20
Dependent Claim
19 words
The method of claim 10 wherein said composition contains coloring materials sufficient to restrict penetration of said radiation therethrough.
Claim 21
Independent Claim
73 words
A method of providing a solid coating on a substrate in a predetermined pattern which comprises coating said substrate substantially in the absence of polymerizing radiation with a composition comprising radiation-curable materials and reaction groups which are stable in the absence of moisture, exposing said coating to moisture sufficient to provide a solid tack-free surface, exposing said surface to radiation in said predetermined pattern, and thereafter removing the unexposed portions of the coating.
Claim 22
Independent Claim
73 words
A method of providing a solid coating on a substrate in a predetermined pattern which comprises coating said substrate substantially in the absence of polymerizing radiation with a composition comprising radiation-curable materials and reaction groups which are stable in the absence of moisture, exposing said coating to moisture sufficient to provide a solid tack-free surface, exposing said surface to radiation in said predetermined pattern, and thereafter removing the unexposed portions of the coating.
Claim 23
Dependent Claim
54 words
The method of claim 19 wherein said composition contains both isocyanate and oxazolidine reaction groups, said oxazolidines having the formula: ##STR5## wherein "R'" represents a radiation-curable monomeric or polymeric radical containing ethylenic unsaturation or a bivalent radical; "m" represents an integer from 1 to 4; and "n" represents an integer from 1 to 10.
Claim 24
Dependent Claim
13 words
The method of claim 19 wherein said composition further contains a filler material.
Claim 25
Dependent Claim
8 words
The product of the process of claim 10.
Claim 26
Dependent Claim
8 words
The product of the process of claim 19.
Claim 27
Dependent Claim
106 words
A solid cross-linked polymeric coating on a substrate which comprises the polymerization product of a first prepolymer having at least one ethylenically unsaturated group and at least one isocyanate or oxazolidine group, and a second prepolymer having at least two reactive groups one of which is the other of said oxazolidine or isocyanate group reactive with said first prepolymer, the other reactive group on said second prepolymer being an isocyanate, oxazolidine or ethylenically unsaturated group, at least a portion of said unsaturated groups being polymerized by exposure to radiation and at least a portion of said isocyanate and oxazolidine groups being polymerized by exposure to moisture.
Claim 28
Dependent Claim
106 words
A solid cross-linked polymeric coating on a substrate which comprises the polymerization product of a first prepolymer having at least one ethylenically unsaturated group and at least one isocyanate or oxazolidine group, and a second prepolymer having at least two reactive groups one of which is the other of said oxazolidine or isocyanate group reactive with said first prepolymer, the other reactive group on said second prepolymer being an isocyanate, oxazolidine or ethylenically unsaturated group, at least a portion of said unsaturated groups being polymerized by exposure to radiation and at least a portion of said isocyanate and oxazolidine groups being polymerized by exposure to moisture.
Claim 29
Dependent Claim
24 words
A cross-linked polymer on a substrate according to claim 17 wherein said prepolymers are liquid and wherein ethylenically unsaturated liquid monomer is copolymerized therewith.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-11-26 | 1983-05-28 | 1983-11-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-11-26 | 1987-05-28 | 1987-11-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-11-26 | 1991-05-28 | 1991-11-27 | $7700.00 | Window Closed / Lapsed |