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Rhodium-rich oxygen barriers

Assignee: Mosaid Technologies Inc
•
Filing: 2001-02-20
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Granted: 2003-02-11
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Expires: 2021-02-20
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Abstract

Abstract A structure and method are disclosed for forming a capacitor for an integrated circuit. The capacitor includes a rhodium-rich structure, a rhodium oxide layer in direct contact with the rhodium-rich structure, a capacitor dielectric in direct contact with the rhodium oxide layer and a top electrode over the capacitor. The rhodium-rich structure can include rhodium alloys and the capacitor dielectric preferably has a high dielectric constant.

Inventors

  • 👤 Haining Yang
  • 👤 Dan Gealy
  • 👤 Gurtej S. Sandhu
  • 👤 Howard Rhodes
  • 👤 Mark Visokay

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:00
CPC Classifications
H; H10; H10B; H10B12/00; H10D; H10D1/00; H10D1/60; H10D1/68; H10D1/692; H10D1/696; H10D1/682; H10P; H10P14/00; H10P14/40; H10P14/418

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 113 words
A capacitor within an integrated circuit comprising: a first conductive layer in contact with a portion of a substrate assembly, where a material for the first conductive layer is selected from the group consisting of a noble metal, a metal alloy, a metal compound, polysilicon, and combinations thereof; a rhodium-rich structure in contact with the first conductive layer, where the rhodium-rich structure is between 20 nm and 100 nm thick; a rhodium oxide layer in direct contact with the rhodium-rich structure, where the rhodium oxide layer is between 1 nm to 20 nm thick; a capacitor dielectric in direct contact with the rhodium oxide layer; and a top electrode over the capacitor dielectric.
Claim 2
Dependent Claim 113 words
A capacitor within an integrated circuit comprising: a first conductive layer in contact with a portion of a substrate assembly, where a material for the first conductive layer is selected from the group consisting of a noble metal, a metal alloy, a metal compound, polysilicon, and combinations thereof; a rhodium-rich structure in contact with the first conductive layer, where the rhodium-rich structure is between 20 nm and 100 nm thick; a rhodium oxide layer in direct contact with the rhodium-rich structure, where the rhodium oxide layer is between 1 nm to 20 nm thick; a capacitor dielectric in direct contact with the rhodium oxide layer; and a top electrode over the capacitor dielectric.
Claim 3
Dependent Claim 15 words
The capacitor of claim 1 , wherein the top electrode comprises a second rhodium-rich structure.
Claim 4
Dependent Claim 15 words
The capacitor of claim 2 , wherein the top electrode comprises a pure rhodium layer.
Claim 5
Dependent Claim 17 words
The capacitor of claim 2 , wherein the second rhodium-rich structure comprises a noble metal alloy layer.
Claim 6
Dependent Claim 24 words
The capacitor of claim 4 , wherein the noble metal alloy layer comprises a Rh-Pt alloy containing more than about 50 atomic percent Rh.
Claim 7
Dependent Claim 28 words
The capacitor of claim 2 , wherein the top electrode comprises a second rhodium oxide layer between the dielectric and the second rhodium-rich structure of the top electrode.
Claim 8
Dependent Claim 20 words
The capacitor of claim 6 , wherein each of the rhodium oxide layers is 1 nm to 20 nm thick.
Claim 9
Dependent Claim 20 words
The capacitor of claim 2 , wherein each of the rhodium-rich structures is between 20 nm and 100 nm thick.
Claim 10
Dependent Claim 15 words
The capacitor of claim 1 , wherein the capacitor is formed in a container shape.
Claim 11
Dependent Claim 15 words
The capacitor of claim 1 , wherein the capacitor is formed in a stud shape.
Claim 12
Dependent Claim 21 words
The capacitor of claim 1 , wherein the capacitor dielectric comprises a material having a dielectric constant greater than about 5.
Claim 13
Dependent Claim 21 words
The capacitor of claim 1 , wherein the capacitor dielectric comprises a material having a dielectric constant greater than about 10.
Claim 14
Dependent Claim 21 words
The capacitor of claim 1 , wherein the capacitor dielectric comprises a material having a dielectric constant greater than about 20.
Claim 15
Dependent Claim 15 words
The capacitor of claim 1 , wherein the capacitor dielectric comprises barium strontium titanate (BST).
Claim 16
Dependent Claim 17 words
The capacitor of claim 14 , wherein the BST thickness is between 8 nm and 40 nm.
Claim 17
Dependent Claim 18 words
The capacitor of claim 1 , wherein the capacitor dielectric comprises tantalum oxide (Ta 2 O 5 ).
Claim 18
Dependent Claim 20 words
The capacitor of claim 16 , wherein the Ta 2 O 5 thickness is between 3 nm and 20 nm.
Claim 19
Dependent Claim 40 words
An electrode for a semiconductor device consisting of a series of layers comprising: a first layer comprising a noble metal comprising a Rh-Pt alloy with at least 70% Rh; and a second layer containing more than 50 atomic percent rhodium.
Claim 20
Dependent Claim 40 words
An electrode for a semiconductor device consisting of a series of layers comprising: a first layer comprising a noble metal comprising a Rh-Pt alloy with at least 70% Rh; and a second layer containing more than 50 atomic percent rhodium.
Claim 21
Dependent Claim 20 words
The electrode of claim 18 , wherein the thickness of the first layer is between 20 nm and 100 nm.
Claim 22
Dependent Claim 12 words
The electrode of claim 18 , wherein the first layer comprises Pt.
Claim 23
Dependent Claim 13 words
The electrode of claim 20 , wherein the first layer further comprises Rh.
Claim 24
Dependent Claim 42 words
An integrated circuit capacitor comprising: a dielectric layer having a dielectric constant greater than about 5; and electrodes in contact with the dielectric layer, the electrodes comprising rhodium-rich structures with a Rh-Pt alloy, wherein the Rh-Pt alloy contains at least 70% Rh.
Claim 25
Dependent Claim 42 words
An integrated circuit capacitor comprising: a dielectric layer having a dielectric constant greater than about 5; and electrodes in contact with the dielectric layer, the electrodes comprising rhodium-rich structures with a Rh-Pt alloy, wherein the Rh-Pt alloy contains at least 70% Rh.
Claim 26
Dependent Claim 19 words
The capacitor of claim 22 , formed in electrical contact with an underlying semiconductor substrate through a polysilicon plug.

References Cited (Backward Citations)

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