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US6235630B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Silicide pattern structures and methods of fabricating the same

Assignee: Micron Technology Inc
•
Filing: 1998-08-19
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Granted: 2001-05-22
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Expires: 2018-08-19
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Abstract

Abstract Silicide interfaces for integrated circuits, thin film devices, and backend integrated circuit testing devices are formed using a barrier layer, such as titanium nitride, disposed over a porous, thin dielectric layer which is disposed between a silicon-containing substrate and a silicidable material which is deposited to form the silicide interfaces for such devices. The barrier layer prevents the formation of a silicide material within imperfections or voids which form passages through the thin dielectric layer when the device is subjected to a high temperature anneal to form the silicide contact from the reaction of the silicidable material and the silicon-containing substrate.

Inventors

  • 👤 Salman Akram
  • 👤 Y. Jeff Hu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:18
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/032; H10W20/047; G; G01; G01R; G01R1/00; G01R1/02; G01R1/06; G01R1/067; G01R1/073; G01R1/07307; G01R1/07314; H10D; H10D64/00; H10D64/01; H10D64/011; H10D64/0111; H10D64/0112; H10D64/01125; H10P; H10P14/00; H10P14/40; H10P14/412; H10P14/414; H10W20/033; H10W20/071; H10W20/081; H10B; H10B12/00; H10B12/01; H10B12/02; H10B12/03; H10B12/033; H10B12/0335; H10B12/30; H10B12/48; H10B12/485; Y; Y10; Y10S; Y10S438/00; Y10S438/942; Y10S438/948; Y10S438/952

Claims Analysis

Total Claims: 45
Claim 1
Independent Claim 162 words
A method of forming a contact interface, comprising: providing a semiconductor substrate having at least one active-device region; forming a dielectric layer over said semiconductor substrate; forming a barrier layer over said dielectric layer; etching said barrier layer and said dielectric layer to define a contact opening extending through said barrier layer and said dielectric layer to expose at least a portion of said at least one active-device region of said semiconductor substrate; depositing an electrically conductive silicidable material over said barrier layer and into said contact opening wherein a portion of said electrically conductive silicidable material contacts said exposed at least one active-device region of the semiconductor substrate, said electrically conductive silicidable material being different from a material of the barrier layer; and annealing said electrically conductive silicidable material to said semiconductor substrate so as to form a silicide contact from said portion of electrically conductive silicidable material in contact with said at least one active-device region of said semiconductor substrate.
Claim 2
Independent Claim 162 words
A method of forming a contact interface, comprising: providing a semiconductor substrate having at least one active-device region; forming a dielectric layer over said semiconductor substrate; forming a barrier layer over said dielectric layer; etching said barrier layer and said dielectric layer to define a contact opening extending through said barrier layer and said dielectric layer to expose at least a portion of said at least one active-device region of said semiconductor substrate; depositing an electrically conductive silicidable material over said barrier layer and into said contact opening wherein a portion of said electrically conductive silicidable material contacts said exposed at least one active-device region of the semiconductor substrate, said electrically conductive silicidable material being different from a material of the barrier layer; and annealing said electrically conductive silicidable material to said semiconductor substrate so as to form a silicide contact from said portion of electrically conductive silicidable material in contact with said at least one active-device region of said semiconductor substrate.
Claim 3
Dependent Claim 27 words
The method of claim 1 , wherein said forming said dielectric layer over said semiconductor substrate comprises depositing a layer of TEOS dioxide over said semiconductor substrate.
Claim 4
Dependent Claim 27 words
The method of claim 1 , wherein said forming said barrier layer over said dielectric layer comprises depositing a layer of titanium nitride over said dielectric layer.
Claim 5
Dependent Claim 38 words
The method of claim 1 , wherein said depositing said eletrically conductive silicidable material over said barrier layer and into said contact opening comprises depositing a layer of cobalt over said barrier layer and into said contact opening.
Claim 6
Dependent Claim 27 words
The method of claim 1 , wherein said annealing is effected by heating said semiconductor substrate to a temperature of between about 400 and about 800° C.
Claim 7
Dependent Claim 17 words
The method of claim 5 , wherein said annealing temperature is between about 450 and 600° C.
Claim 8
Dependent Claim 18 words
The method of claim 1 , further including removing a non-reacted portion of said electrically conductive silicidable material.
Claim 9
Dependent Claim 26 words
The method of claim 7 , wherein said removing said non-reacted portion of said electrically conductive silicidable material is effected by application of an HPM solution.
Claim 10
Dependent Claim 19 words
The method of claim 1 , furher including removing said barrier layer after said annealing of said semiconductor substrate.
Claim 11
Dependent Claim 18 words
The method of claim 9 , wherein said removing layer is effected by application of an APM solution.
Claim 12
Independent Claim 152 words
A method of forming a DRAM chip, comprising: providing a semiconductor substrate having an active-device region; depositing a dielectric layer over said semiconductor substrate; forming a barrier layer over said dielectric layer; etching said barrier layer and said dielectric layer to define a contact opening extending through said barrier layer and said dielectric layer to expose at least a portion of said active-device region of said semiconductor substrate; depositing an electrically conductive silicidable material over said barrier layer and into said contact opening wherein a portion of said electrically conductive silicidable material contacts said exposed portion of said active-device region of the semiconductor substrate, said electrically conductive silicidable material being different from a material of the barrier layer, and annealing said electrically conductive silicidable material to said semiconductor substrate to form a silicide contact from said portion of electrically conductive silicidable material in contact with said active-device region of said semiconductor substrate.
Claim 13
Independent Claim 152 words
A method of forming a DRAM chip, comprising: providing a semiconductor substrate having an active-device region; depositing a dielectric layer over said semiconductor substrate; forming a barrier layer over said dielectric layer; etching said barrier layer and said dielectric layer to define a contact opening extending through said barrier layer and said dielectric layer to expose at least a portion of said active-device region of said semiconductor substrate; depositing an electrically conductive silicidable material over said barrier layer and into said contact opening wherein a portion of said electrically conductive silicidable material contacts said exposed portion of said active-device region of the semiconductor substrate, said electrically conductive silicidable material being different from a material of the barrier layer, and annealing said electrically conductive silicidable material to said semiconductor substrate to form a silicide contact from said portion of electrically conductive silicidable material in contact with said active-device region of said semiconductor substrate.
Claim 14
Independent Claim 125 words
A method of forming a contact interface, comprising: providing a semiconductor substrate having at least one contact projection; forming a first dielectric layer over said semiconductor substrate and said at least one contact projection; depositing a polysilicon layer over said first dielectric layer; depositing a barrier layer over said polysilicon layer; etching said barrier layer to expose said polysilicon layer over said at least one contact projection; depositing an electrically conductive silicidable material over said barrier layer and said exposed polysilicon layer, said electrically conductive silicidable material being different from a material of said barrier layer; and annealing said electrically conductive silicidable material to said semiconductor substrate to form a silicide contact from said exposed polysilicon layer in contact with said electrically conductive silicidable material.
Claim 15
Independent Claim 125 words
A method of forming a contact interface, comprising: providing a semiconductor substrate having at least one contact projection; forming a first dielectric layer over said semiconductor substrate and said at least one contact projection; depositing a polysilicon layer over said first dielectric layer; depositing a barrier layer over said polysilicon layer; etching said barrier layer to expose said polysilicon layer over said at least one contact projection; depositing an electrically conductive silicidable material over said barrier layer and said exposed polysilicon layer, said electrically conductive silicidable material being different from a material of said barrier layer; and annealing said electrically conductive silicidable material to said semiconductor substrate to form a silicide contact from said exposed polysilicon layer in contact with said electrically conductive silicidable material.
Claim 16
Dependent Claim 28 words
The method of claim 12 , wherein said forming said first dielectric layer over said semiconductor substrate comprises forming a layer of silicon dioxide over said semiconductor substrate.
Claim 17
Dependent Claim 27 words
The method of claim 12 , whermin said forming said barrier layer over said polysilicon layer comprises depositing a layer of titanium nitride ovcr. said polysilicon layer.
Claim 18
Dependent Claim 38 words
The method of claim 12 , wherein said depositing said ltrically conductive silicidable material over said baiier layer aind said exposed polysilicon layer comprises depositing a layer of cobalt over said barrier layer and said exposed polysilicon layer.
Claim 19
Dependent Claim 27 words
The method of claim 12 , wherein said annealing is effected by heating said semiconductor substrate to a temperature of between about 400° and about 800° C.
Claim 20
Dependent Claim 17 words
The method of claim 16 , wherein said annealing temperature is between about 450° and 600° C.
Claim 21
Independent Claim 19 words
The method, of clai 12 , further including removing a non-reacted portion of said cl aijl ucbie silicidable material.
Claim 22
Independent Claim 19 words
The method, of clai 12 , further including removing a non-reacted portion of said cl aijl ucbie silicidable material.
Claim 23
Dependent Claim 26 words
The method of claim 18 , wherein said removing said non-reacted portionl of said electrically conductive silicidable material is effected by application of an HPM solution.
Claim 24
Dependent Claim 19 words
The method of claim 12 , further including removing said barrier layer after said annealing of said semiconductor substrate.
Claim 25
Dependent Claim 20 words
The method of claim 20 , wherein said removing said barrier layer is effected by application of an APM solution.
Claim 26
Dependent Claim 21 words
The method of claim 12 , further including disposing a second dielectric layer between said polysilicon layer and said barrier layer.
Claim 27
Dependent Claim 35 words
The method of claim 22 , wherein said disposing said second dielectric layer between said polysilicon layer and said barrier layer comprises depositing a layer of TEOS between said polysilicon layer and said barrier layer.
Claim 28
Dependent Claim 36 words
The method of claim 22 , wherein said disposing said second dielectric layer between said polysilicon layer and said barrier layer comprises depositing a layer of silicon dioxide between said polysilicon layer and said barrier layer.
Claim 29
Dependent Claim 23 words
The method of claim 1 , wherein said forming said dielectric layer comprises forming said dielectric layer with a thickness of approximately 1,000Å.
Claim 30
Dependent Claim 29 words
The method of claim 7 , wherein said removing said non-reacted portion of said electrically silicidable material is effected without substantially removing reacted electrically silicidable material of said portion.
Claim 31
Dependent Claim 28 words
The method of claim 26 , wherein said. removing said non-reacted portion of said conductivc silicidable material is effected without substantially removing said material of said bsneer layer.
Claim 32
Dependent Claim 25 words
The method of claim 9 , whereic said removing said barrier layer is effected without substantially removing reacted electrcally conductive silicidable material of said portion.
Claim 33
Dependent Claim 20 words
The method of claim 28 , wherein said removing said barrier layer is effected without substantially removing said dielectric layer.
Claim 34
Dependent Claim 19 words
The method of claim 9 , wherein said removing said barrier layer comprises substantially completely removing said barrier layer.
Claim 35
Dependent Claim 39 words
The method of claim 1 ; wherein said fonling said barrier layer comprises preventing said ct it silicidable material from reacting with said semiconductor substrate through et least one of a void and an imperfection in said dielectric layer.
Claim 36
Dependent Claim 32 words
The method of claim 1 , wherein said forming said barrier layer comprises forming a layer comprising at least one of titanium nitride, tungsten nitride, tungsten silicon nitride, and titanium silicon nitride.
Claim 37
Dependent Claim 23 words
The method of claim 12 , wherein said forming said dielectric layer comprises forming said dielectric layer with a thickness of approximately 1,000Å.
Claim 38
Dependent Claim 26 words
The method of claim 18 , wherein said removing said non-reacted portion of said electrically silicidable material is effected without substantially removing reacted electrically silicidable material.
Claim 39
Dependent Claim 28 words
The method of claim 34 , wherein said removing said non-reacted portion of said electrically silicidable material is effected without substantially removing said material of said barrier layer.
Claim 40
Independent Claim 25 words
The method of clairn 20 , wherein said removing said barrier layer is effected without substantially removing reacted electrically conductive silicidable material of said portion.
Claim 41
Independent Claim 25 words
The method of clairn 20 , wherein said removing said barrier layer is effected without substantially removing reacted electrically conductive silicidable material of said portion.
Claim 42
Dependent Claim 20 words
The method of claim 36 , wherein said removing said barrier layer is effected without substantially removing said dielectric layer.
Claim 43
Dependent Claim 19 words
The method of claim 20 , wherein said removing said barrier layer comprises substantially completely removing said barrier layer.
Claim 44
Dependent Claim 38 words
The method of claim 12 , wherein said forming said barrier layer comprises preventing said electrically silicidablc material from reacting with said semiconductor substrate through at least one of a void and an imperfection in said dielectric layer.
Claim 45
Dependent Claim 32 words
The method of claim 12 , wherein said forming said barrier layer comprises forming a layer comprising at least one of titanium nitride, tungsten nitride, tungsten silicon nitride, and titanium silicon nitride.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-05-21 2004-11-20 2005-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-05-21 2008-11-20 2009-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-05-21 2012-11-20 2013-05-22 $7700.00 Window Closed / Lapsed

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