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Process for producing aminosilane compounds

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1998-11-06
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Granted: 2000-10-24
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Expires: 2018-11-06
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Abstract

Abstract The present invention provides a process for producing aminosaline compounds which are useful as precursors for ligands in the transition metal complexes, said process avoiding handling of solid which is troublesome in isolation and purification and combustible upon contact with air, having smaller number of reaction steps, and giving a high yield, in industrial scale. The present invention has a great value that said process for production could be carried out at an industrially advantageous temperature of -20° or higher.

Inventors

  • 👤 Masaaki Nabika
  • 👤 Kotohiro Nomura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:08
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/10; C07F7/12; C07F7/121; C07F7/122

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 210 words
A process for producing an aminosilane compound represented by the general formula (1) described below, which comprises carrying out steps (A), (B) and (C) in this order without an intervenient isolation nor purification treatment: (A): reacting a compound having a cyclopentadiene skeleton with a strong base; (B): reacting the reaction product obtained in the step (A) with a silane compound represented by the general formula (2); and (C): reacting the reaction product obtained in the step (B) with an amine compound represented by the general formula (3) or an alkali metal amide compound represented by the general formula (4); ##STR4## wherein, for the respective general formulae (1), (2), (3) and (4), Cp represents a group having a cyclopentadiene skeleton; M represents an alkali metal atom; R 1 and R 2 independently represent a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a substituted silyl group; R 3 and R 4 independently represent an alkyl group, an aralkyl group, an aryl group, a substituted silyl group, an alkoxy group, an aralkyloxy group or an aryloxy group; (R 1 and R 2 ) and/or (R 3 and R 4 ) may be linked to form a ring; and X 1 and X 2 independently represent a halogen atom.
Claim 2
Dependent Claim 210 words
A process for producing an aminosilane compound represented by the general formula (1) described below, which comprises carrying out steps (A), (B) and (C) in this order without an intervenient isolation nor purification treatment: (A): reacting a compound having a cyclopentadiene skeleton with a strong base; (B): reacting the reaction product obtained in the step (A) with a silane compound represented by the general formula (2); and (C): reacting the reaction product obtained in the step (B) with an amine compound represented by the general formula (3) or an alkali metal amide compound represented by the general formula (4); ##STR4## wherein, for the respective general formulae (1), (2), (3) and (4), Cp represents a group having a cyclopentadiene skeleton; M represents an alkali metal atom; R 1 and R 2 independently represent a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a substituted silyl group; R 3 and R 4 independently represent an alkyl group, an aralkyl group, an aryl group, a substituted silyl group, an alkoxy group, an aralkyloxy group or an aryloxy group; (R 1 and R 2 ) and/or (R 3 and R 4 ) may be linked to form a ring; and X 1 and X 2 independently represent a halogen atom.
Claim 3
Dependent Claim 31 words
A process for producing an aminosilane compound according to claim 1, wherein each of the steps (A), (B) and (C) is carried out at a temperature of -20° C. or higher.
Claim 4
Dependent Claim 30 words
A process for producing an aminosilane compound according to claim 1, wherein the compound having a cyclopentadiene skeleton is used in the form of a solution in an ethereal solvent.
Claim 5
Dependent Claim 30 words
A process for producing an aminosilane compound according to claim 1, wherein the strong base is used in the form of a solution in an aliphatic or aromatic hydrocarbon solvent.
Claim 6
Dependent Claim 20 words
A process for producing an aminosilane compound according to claim 1, wherein the strong base is an organo-alkali metal compound.
Claim 7
Dependent Claim 30 words
A process for producing an aminosilane compound according to claim 1, wherein the Cp is a group having a cyclopentadiene skeleton containing at least one substituent on its five-membered ring.
Claim 8
Dependent Claim 38 words
A process for producing an aminosilane compound according to claim 1, wherein Cp is a member selected from the group consisting of a tetramethylcyclopentadienyl group, a dimethylcyclopentadienyl group, a di-tert-butylcyclopentadienyl group, a diisopropylcyclopentadienyl group and an isopropyl-tert-butylcyclopentadienyl group.
Claim 9
Dependent Claim 35 words
A process for producing an aminosilane compound according to claim 1, wherein one of R 1 and R 2 is a hydrogen atom and the other is an alkyl group or a substituted silyl group.
Claim 10
Dependent Claim 22 words
A process for producing an aminosilane compound according to claim 1, wherein M in the general formula (4) is a lithium atom.
Claim 11
Dependent Claim 29 words
A process for producing an aminosilane compound according to claim 1, wherein the reaction in the step (A) is carried out at a temperature of -20 to 30° C.
Claim 12
Dependent Claim 31 words
A process for producing an aminosilane compound according to claim 1, wherein both reactions in the steps (B) and (C) are carried out at a temperature of -10 to 100° C.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-10-24 2004-04-24 2004-10-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-10-24 2008-04-24 2008-10-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-10-24 2012-04-24 2012-10-24 $7700.00 Window Closed / Lapsed

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