US5453221A
Expired / Lapsed
US
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Bridged cyclopentadienylmagnesium compounds and use thereof for preparing metallocenes
Assignee: Chemtura Organometallics GmbH
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Filing: 1995-02-22
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Granted: 1995-09-26
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Expires: 2015-02-22
Abstract
Abstract Disclosed are new bridged cyclopentadienylmagnesium compounds of the general formula Q(CpR a ) (Cp'R' a' )Mg, processes for the preparation thereof, and the use thereof for preparing bridged metallocenes.
Inventors
- 👤 Richard Lisowsky
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:13
CPC Classifications
C; C07; C07F; C07F17/00; C07F17/02; C07F3/00; C07F3/02; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/0825; C07F7/0827
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
141 words
A compound of the general formula (1) Q(CpR.sub.a)(Cp'R'.sub.a ')Mg (1) wherein Cp is a cyclopentadienyl or an indenyl radical; R and R' are the same or different and each is selected from the group consisting of alkyl, phosphine, amino, alkylamino, dialkylamino, alkoxy, alkoxy-alkyl, aryl-alkyl, and aryloxy-alkyl groups; 0≦a≦4 and 0≦a'≦4; Cp' is cyclopentadienyl or indenyl, or when a' is 1, Cp'R' can be NR" wherein R" is a C 1 -C 12 alkyl or a C 6 -C 10 aryl radical; and Q is a single-membered or multi-membered bridge between Cp and Cp' and represents (R.sup.1 --Z--R.sup.2).sub.b, wherein R 1 and R 2 are identical or different and each is a hydrogen atom, a C 1 -C 10 alkyl group or a C 6 -C 10 -aryl group; Z is carbon, silicon or germanium; and b is 1, 2 or 3.
Claim 2
Dependent Claim
141 words
A compound of the general formula (1) Q(CpR.sub.a)(Cp'R'.sub.a ')Mg (1) wherein Cp is a cyclopentadienyl or an indenyl radical; R and R' are the same or different and each is selected from the group consisting of alkyl, phosphine, amino, alkylamino, dialkylamino, alkoxy, alkoxy-alkyl, aryl-alkyl, and aryloxy-alkyl groups; 0≦a≦4 and 0≦a'≦4; Cp' is cyclopentadienyl or indenyl, or when a' is 1, Cp'R' can be NR" wherein R" is a C 1 -C 12 alkyl or a C 6 -C 10 aryl radical; and Q is a single-membered or multi-membered bridge between Cp and Cp' and represents (R.sup.1 --Z--R.sup.2).sub.b, wherein R 1 and R 2 are identical or different and each is a hydrogen atom, a C 1 -C 10 alkyl group or a C 6 -C 10 -aryl group; Z is carbon, silicon or germanium; and b is 1, 2 or 3.
Claim 3
Dependent Claim
11 words
A compound according to claim 1 wherein Cp'R' a' is NR".
References Cited (Backward Citations)
DE480390C
Cited
US4447369A
Cited
EP0344887A2
Cited
AU622826B2
Cited
EP0416815A2
Cited
EP0420436A1
Cited
EP0520732A1
Cited
EP0530908A1
Cited
US5231205A
Cited
US5359105A
Cited
DE4402192A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-09-25 | 1999-03-27 | 1999-09-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-09-25 | 2003-03-27 | 2003-09-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-09-25 | 2007-03-27 | 2007-09-26 | $7700.00 | Window Closed / Lapsed |