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US5453221A Expired / Lapsed US ⏱️ 0.0 years remaining

Bridged cyclopentadienylmagnesium compounds and use thereof for preparing metallocenes

Assignee: Chemtura Organometallics GmbH
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Filing: 1995-02-22
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Granted: 1995-09-26
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Expires: 2015-02-22
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Abstract

Abstract Disclosed are new bridged cyclopentadienylmagnesium compounds of the general formula Q(CpR a ) (Cp'R' a' )Mg, processes for the preparation thereof, and the use thereof for preparing bridged metallocenes.

Inventors

  • 👤 Richard Lisowsky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:13
CPC Classifications
C; C07; C07F; C07F17/00; C07F17/02; C07F3/00; C07F3/02; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/0825; C07F7/0827

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 141 words
A compound of the general formula (1) Q(CpR.sub.a)(Cp'R'.sub.a ')Mg (1) wherein Cp is a cyclopentadienyl or an indenyl radical; R and R' are the same or different and each is selected from the group consisting of alkyl, phosphine, amino, alkylamino, dialkylamino, alkoxy, alkoxy-alkyl, aryl-alkyl, and aryloxy-alkyl groups; 0≦a≦4 and 0≦a'≦4; Cp' is cyclopentadienyl or indenyl, or when a' is 1, Cp'R' can be NR" wherein R" is a C 1 -C 12 alkyl or a C 6 -C 10 aryl radical; and Q is a single-membered or multi-membered bridge between Cp and Cp' and represents (R.sup.1 --Z--R.sup.2).sub.b, wherein R 1 and R 2 are identical or different and each is a hydrogen atom, a C 1 -C 10 alkyl group or a C 6 -C 10 -aryl group; Z is carbon, silicon or germanium; and b is 1, 2 or 3.
Claim 2
Dependent Claim 141 words
A compound of the general formula (1) Q(CpR.sub.a)(Cp'R'.sub.a ')Mg (1) wherein Cp is a cyclopentadienyl or an indenyl radical; R and R' are the same or different and each is selected from the group consisting of alkyl, phosphine, amino, alkylamino, dialkylamino, alkoxy, alkoxy-alkyl, aryl-alkyl, and aryloxy-alkyl groups; 0≦a≦4 and 0≦a'≦4; Cp' is cyclopentadienyl or indenyl, or when a' is 1, Cp'R' can be NR" wherein R" is a C 1 -C 12 alkyl or a C 6 -C 10 aryl radical; and Q is a single-membered or multi-membered bridge between Cp and Cp' and represents (R.sup.1 --Z--R.sup.2).sub.b, wherein R 1 and R 2 are identical or different and each is a hydrogen atom, a C 1 -C 10 alkyl group or a C 6 -C 10 -aryl group; Z is carbon, silicon or germanium; and b is 1, 2 or 3.
Claim 3
Dependent Claim 11 words
A compound according to claim 1 wherein Cp'R' a' is NR".

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-09-25 1999-03-27 1999-09-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-09-25 2003-03-27 2003-09-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-09-25 2007-03-27 2007-09-26 $7700.00 Window Closed / Lapsed

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