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Trench isolation process using nitrogen preconditioning to reduce crystal defects

Assignee: Intel Corp
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Filing: 1995-09-29
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Granted: 1999-11-16
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Expires: 2015-09-29
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Abstract

Abstract A method of forming a trench isolation structure in a semiconductor substrate. After etching a trench into the semiconductor substrate, an oxide layer is formed within the trench. The surface of this oxide layer is subjected to a nitrogen plasma. Subsequently, another oxide layer is deposited over the nitrogen-rich surface of the first oxide layer. Deposition of this second oxide layer is accomplished by a chemical vapor deposition (CVD) process primarily using a reactant gas other than ozone.

Inventors

  • 👤 Peter K. Moon
  • 👤 David T. Krick
  • 👤 Kerry L. Spurgin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 21:31
CPC Classifications
H; H10; H10W; H10W10/00; H10W10/01; H10W10/011; H10W10/014; H10W10/0145; H10W10/10; H10W10/17; Y; Y10; Y10S; Y10S148/00; Y10S148/05

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 81 words
A method of forming an isolation structure in a semiconductor substrate comprising the steps of: a) etching a trench in the semiconductor substrate; b) forming a first oxide layer within the trench; c) subjecting a surface of the first oxide layer to a nitrogen plasma; and d) depositing a second oxide layer on the surface of the first oxide layer, the second oxide layer being deposited by a chemical vapor deposition (CVD) process primarily using a reactant gas other than ozone.
Claim 2
Independent Claim 81 words
A method of forming an isolation structure in a semiconductor substrate comprising the steps of: a) etching a trench in the semiconductor substrate; b) forming a first oxide layer within the trench; c) subjecting a surface of the first oxide layer to a nitrogen plasma; and d) depositing a second oxide layer on the surface of the first oxide layer, the second oxide layer being deposited by a chemical vapor deposition (CVD) process primarily using a reactant gas other than ozone.
Claim 3
Dependent Claim 28 words
The method of claim 1 further comprising the step of performing a chemical mechanical polishing etch-back step to isolate the first and second oxide layers within the trench.
Claim 4
Dependent Claim 23 words
The method of claim 1 wherein the first oxide layer is formed by a method including growing a thermal oxide within the trench.
Claim 5
Dependent Claim 18 words
The method of claim 1 wherein the second oxide layer is deposited by a plasma-enhanced CVD (PECVD) process.
Claim 6
Dependent Claim 16 words
The method of claim 4 wherein the second oxide layer is a substantially undoped oxide layer.
Claim 7
Dependent Claim 33 words
The method of claim 1 wherein the second oxide layer is a doped oxide selected from a group consisting of borosilicate glass (BSG), phosphosilicate glass (PSG), borophosphosilicate glass (BPSG), and any combination thereof.
Claim 8
Dependent Claim 15 words
The method of claim 4 wherein the PECVD process is performed using a TEOS chemistry.
Claim 9
Dependent Claim 19 words
The method of claim 1 wherein the second oxide layer is deposited by a low pressure CVD (LPCVD) process.
Claim 10
Dependent Claim 24 words
The method of claim 3 wherein the nitrogen plasma creates a nitrogen-rich surface of the first oxide layer that is approximately one monolayer thick.
Claim 11
Independent Claim 110 words
A method of forming an isolation structure in a semiconductor substrate comprising the steps of: a) etching a trench in the semiconductor substrate; b) growing a thermal oxide within the trench to form a first oxide layer; c) subjecting the first oxide layer to a nitrogen plasma to form a nitrogen-rich surface on the first oxide layer; d) depositing a second oxide layer over the nitrogen-rich surface of the first oxide layer, the second oxide layer being deposited by a chemical vapor deposition (CVD) process in the absence of ozone; and e) performing a chemical mechanical polishing etch-back step to isolate the first and second oxide layers within the trench.
Claim 12
Independent Claim 110 words
A method of forming an isolation structure in a semiconductor substrate comprising the steps of: a) etching a trench in the semiconductor substrate; b) growing a thermal oxide within the trench to form a first oxide layer; c) subjecting the first oxide layer to a nitrogen plasma to form a nitrogen-rich surface on the first oxide layer; d) depositing a second oxide layer over the nitrogen-rich surface of the first oxide layer, the second oxide layer being deposited by a chemical vapor deposition (CVD) process in the absence of ozone; and e) performing a chemical mechanical polishing etch-back step to isolate the first and second oxide layers within the trench.
Claim 13
Dependent Claim 19 words
The method of claim 10 wherein the nitrogen-rich surface of the first oxide layer is approximately one monolayer thick.
Claim 14
Dependent Claim 16 words
The method of claim 10 wherein the second oxide layer is a substantially undoped oxide layer.
Claim 15
Dependent Claim 33 words
The method of claim 10 wherein the second oxide layer is a doped oxide selected from a group consisting of borosilicate glass (BSG), phosphosilicate glass (PSG), borophosphosilicate glass (BPSG), and any combination thereof.
Claim 16
Dependent Claim 20 words
The method of claim 10 wherein the CVD process is a plasma-enhanced CVD (PECVD) process performed using a TEOS chemistry.
Claim 17
Dependent Claim 21 words
The method of claim 10 wherein the CVD process is a low pressure CVD (LPCVD) process performed using a TEOS chemistry.

References Cited (Backward Citations)

US5316965A Cited
US5492858A Cited
US5447884A Cited
US5643823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-11-15 2003-05-17 2003-11-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-11-15 2007-05-17 2007-11-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-11-15 2011-05-17 2011-11-16 $7700.00 Window Closed / Lapsed

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