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US5574162A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-migrating 1-hydrocarbyloxy hindered amine derivatives as polymer stabilizers

Assignee: Novartis Corp
•
Filing: 1995-05-31
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Granted: 1996-11-12
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Expires: 2015-05-31
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Abstract

Abstract 1-Hydrocarbyloxy substituted hindered amine compounds which also contain a reactive functional group such as hydroxy, amino, oxirane or carboxyl can be chemically attached to selected polymer substrates by condensation reactions to give polymers containing a chemically-bonded, non-migrating stabilizer having excellent stabilization efficacy for protecting said polymer substrate from the adverse effects of actinic light.

Inventors

  • 👤 James P. Galbo
  • 👤 Ramanathan Ravichandran
  • 👤 Peter J. Schirmann
  • 👤 Andrew Mar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 23:07
CPC Classifications
C; C07; C07D; C07D491/00; C07D491/02; C07D491/10; C07D211/00; C07D211/92; C07D211/94; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 241 words
A 1-hydrocarbyloxy substituted hindered amine compound having the formula V, ##STR18## where p is 2 to 10, L 1 is a p-valent radical of an alkane or alkene of 1 to 18 carbon atoms, a p-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, a p-valent radical of a saturated or unsaturated bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or a p-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N-O groups are not necessarily attached to the same carbon atom in L 1 , T 1 is --OH, --NHR 2 , --NCO, --O--glycidyl or Si(OR 1 ) 3 , G 1 and G 2 are independently alkyl of 1 to 4 carbon atoms, or G 1 and G 2 together are pentamethylene, where R 1 is hydrogen or alkyl of 1 to 12 carbon atoms, where R 2 is hydrogen, alkyl of 1 to 12 carbon atoms, or ##STR19## and where E is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, alkenyl of 2 to 18 carbon atoms, propargyl, cycloalkenyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, a radical of a saturated or unsaturated bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or aryl of 6 to 10 carbon atoms or said aryl substituted by alkyl.
Claim 2
Dependent Claim 241 words
A 1-hydrocarbyloxy substituted hindered amine compound having the formula V, ##STR18## where p is 2 to 10, L 1 is a p-valent radical of an alkane or alkene of 1 to 18 carbon atoms, a p-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, a p-valent radical of a saturated or unsaturated bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or a p-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N-O groups are not necessarily attached to the same carbon atom in L 1 , T 1 is --OH, --NHR 2 , --NCO, --O--glycidyl or Si(OR 1 ) 3 , G 1 and G 2 are independently alkyl of 1 to 4 carbon atoms, or G 1 and G 2 together are pentamethylene, where R 1 is hydrogen or alkyl of 1 to 12 carbon atoms, where R 2 is hydrogen, alkyl of 1 to 12 carbon atoms, or ##STR19## and where E is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, alkenyl of 2 to 18 carbon atoms, propargyl, cycloalkenyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, a radical of a saturated or unsaturated bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or aryl of 6 to 10 carbon atoms or said aryl substituted by alkyl.
Claim 3
Dependent Claim 15 words
A compound according to claim 1 where G 1 and G 2 are each methyl.
Claim 4
Dependent Claim 26 words
A compound according to claim 1 wherein E is alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 3 carbon atoms, propargyl or cyclohexyl.
Claim 5
Dependent Claim 15 words
A compound according to claim 3 wherein E is methyl, heptyl, octyl, nonyl or cyclohexyl.
Claim 6
Dependent Claim 18 words
A compound according to claim 1 wherein L 1 is an n-valent radical of n-octane, n-heptane or cyclohexane.
Claim 7
Dependent Claim 15 words
The compound according to claim 1 wherein T 1 is --OH or --NH 2 .

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-11-12 2000-05-13 2000-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-11-12 2004-05-13 2004-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-11-12 2008-05-13 2008-11-12 $7700.00 Window Closed / Lapsed

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