Permanently stabilized polyurethanes

Claim 2

A permanently stabilized polyurethane, containing 2,2,6,6-tetraalkyl-piperidine structures chemically attached to the polyurethane molecule by a urethane or urea group.

Claim 3

A process for the preparation of a permanently stabilized polyurethane which comprises incorporating a derivative of 2,2,6,6-tetraalkyl-piperidine having an active hydrogen-containing group in a reaction mixture used for the preparation of the polyurethane.

Claim 4

A process for the preparation of a permanently stabilized polyurethane which comprises incorporating a derivative of 2,2,6,6-tetraalkyl-piperidine having an active hydrogen-containing group in a reaction mixture used for the preparation of the polyurethane.

Claim 5

The process according to claim 2, wherein the reaction mixture comprises a polyhydroxyl compound, a polyisocyanate and a chain-lengthening agent.

Claim 6

The process according to claim 2, wherein the derivative of 2,2,6,6-tetraalkyl-piperidine is represented by the following general formula: ##STR21## wherein R denotes hydrogen, a straight chain or branched chain alkyl group having from 1 to 20 C-atoms, an alkenyl group having from 3 to 5 C-atoms, an aralkyl group having from 7 to 12 C-atoms, CH 2 --CH 2 --CN, CH 2 --CH 2 --COO-alkyl ##STR22## R 1 and R 2 , which are identical or different, each denote a straight chain or branched chain alkyl group having from 1 to 6 C-atoms or, together with the ring carbon atoms to which they are attached, a cycloalkyl ring having from 5 to 7 C-atoms, R 3 denotes hydrogen, a straight chain or branched chain alkyl group having from 1 to 20 C-atoms, a cycloalkyl group having from 5 to 12 C-atoms, an aralkyl group having from 7 to 12 C-atoms, an ω-cyanoalkyl group or a β-alkoxycarbonylalkyl group having from 1 to 3 C-atoms in the alkoxy part, R 4 denotes hydrogen, CO--NH--NH 2 or, when R 3 ═H, a straight chain or branched chain alkyl group having from 1 to 20 C-atoms, a cycloalkyl group having from 5 to 12 C-atoms, an aralkyl group having from 7 to 12 C-atoms, an ω-cyanoalkyl group or a β-alkoxycarbonylalkyl group; or when R 3 is not H, an ω-aminoalkyl, an ω-N-alkylaminoalkyl, an ω-hydroxyalkyl or an ω-carboxylic acid hydrazidoalkyl group, and when R 3 and R 4 do not carry an active hydrogen-containing group, R may also denote an ω-aminoalkyl, β-hydroxyalkyl or β-carboxylic acid hydrazidoalkyl group.

Claim 7

The process according to claim 4, wherein the derivative of 2,2,6,6-tetraalkyl-piperidine is represented by the following general formula: ##STR23## wherein R, R 1 and R 2 have the meaning indicated in claim 4, R 5 denotes hydrogen or CN, and R 6 denotes hydrogen, β-hydroxyalkyl, β-or γ-amino-alkyl, CH 2 --CH 2 --CO--NH--NH 2 or CH 2 --CH(CH 3 )--CO--NH--NH 2 , and in cases where the groups R 5 and R 6 do not carry an active hydrogen-containing group, R may denote an ω-aminoalkyl, β-hydroxyalkyl or β-carboxylic acid hydrazidoalkyl group.

Claim 8

The process according to claim 4, wherein the derivative of 2,2,6,6-tetraalkyl-piperidine corresponds to the general formula: ##STR24## wherein R, R 1 and R 2 have the meaning indicated in claim 4.

Claim 9

The process according to claim 2, wherein an isocyanate prepolymer, obtained by reaction of a substantially linear polyester or polyether having OH end groups with an excess quantity of a diisocyanate, is reacted in a highly polar amide solvent with a chain-lengthening agent and from 0.05 to 5%, by weight, based on the sum of reactants, of the 2,2,6,6-tetraaklyl-piperidine derivative.

Claim 10

The process according to claim 7, wherein the derivative of 2,2,6,6-tetraalkyl-piperidine is represented by the following formula: ##STR25## wherein R 8 denotes hydrogen or methyl.

Claim 11

Fibers and foils comprising a stabilized polyurethane according to claim 1.