US5021577A
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Polysubstituted n-hydrocarbyloxy hindered amine light stabilizers
Assignee: BASF Corp
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Filing: 1990-02-14
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Granted: 1991-06-04
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Expires: 2010-02-14
Abstract
Abstract Polysubstituted N-hydrocarbyloxy hindered amines are effective light stabilizers in protecting organic substrates against the deleterious effects of actinic light.
Inventors
- 👤 James P. Galbo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 16:04
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C07; C07D; C07D211/00; C07D211/92; C07D211/94
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
234 words
A polysubstituted N-hydrocarbyloxy compound of the formula ##STR8## where n is 2 to 10, R 1 and R 2 are independently alkyl of 1 to 4 carbon atoms, or R 1 and R 2 together are pentamethylene, L is an n-valent radical of an alkane or alkene of 1 to 18 carbon atoms, an n-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, an n-valent radical of a bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or an n-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N--O groups are not necessarily attached to the same carbon atom in L, T is an organic moiety selected from the group consisting of E--COO--, E 1 --OCO--, E--CONR 3 -- ##STR9## E 1 NHCOCONH--, ##STR10## E 1 OCO(CH 2 ) m NH--, E 1 OCO(CH 2 )pCOO--, ##STR11## where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms, E 1 is methyl or ethyl, R 3 is hydrogen, alkyl of 1 to 8 carbon atoms or ##STR12## where L 1 is a monovalent radical of the definition of L, m is 2 to 4, p is 0 to 10, G is hydrogen or alkyl of 1 to 18 carbon atoms, and X is hydrogen or --CH 2 CH 2 COOC 12 H 25 .
Claim 2
Dependent Claim
234 words
A polysubstituted N-hydrocarbyloxy compound of the formula ##STR8## where n is 2 to 10, R 1 and R 2 are independently alkyl of 1 to 4 carbon atoms, or R 1 and R 2 together are pentamethylene, L is an n-valent radical of an alkane or alkene of 1 to 18 carbon atoms, an n-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, an n-valent radical of a bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or an n-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N--O groups are not necessarily attached to the same carbon atom in L, T is an organic moiety selected from the group consisting of E--COO--, E 1 --OCO--, E--CONR 3 -- ##STR9## E 1 NHCOCONH--, ##STR10## E 1 OCO(CH 2 ) m NH--, E 1 OCO(CH 2 )pCOO--, ##STR11## where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms, E 1 is methyl or ethyl, R 3 is hydrogen, alkyl of 1 to 8 carbon atoms or ##STR12## where L 1 is a monovalent radical of the definition of L, m is 2 to 4, p is 0 to 10, G is hydrogen or alkyl of 1 to 18 carbon atoms, and X is hydrogen or --CH 2 CH 2 COOC 12 H 25 .
Claim 3
Dependent Claim
12 words
A compound according to claim 1 wherein n is 2 to 4.
Claim 4
Dependent Claim
15 words
A compound according to claim 1 wherein R 1 and R 2 are each methyl.
Claim 5
Dependent Claim
17 words
A compound according to claim 1 wherein L is an n-valent radical of n-octane, n-heptane or cyclohexane.
Claim 6
Dependent Claim
23 words
A compound according to claim 1 wherein T is E--COO-- where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms.
Claim 7
Dependent Claim
10 words
A compound according to claim 5 wherein E is heptadecyl.
Claim 8
Dependent Claim
21 words
A compound according to claim 1 wherein T is E--CONR 3 -- where R 3 is hydrogen and E is vinyl.
Claim 9
Dependent Claim
14 words
A compound according to claim 1 wherein T is ##STR13## where G is dodecyl.
Claim 10
Dependent Claim
9 words
The compound according to claim 1 which is 1,4-bis(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)-2-cyclohexene.
Claim 11
Dependent Claim
9 words
The compound according to claim 1 which is 1,8-bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-yl-oxy)octane.
Claim 12
Dependent Claim
9 words
The compound according to claim 1 which is bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)octane.
Claim 13
Dependent Claim
9 words
The compound according to claim 1 which is bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)methane.
References Cited (Backward Citations)
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