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US5021577A Expired / Lapsed US ⏱️ 0.0 years remaining

Polysubstituted n-hydrocarbyloxy hindered amine light stabilizers

Assignee: BASF Corp
•
Filing: 1990-02-14
•
Granted: 1991-06-04
•
Expires: 2010-02-14
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Abstract

Abstract Polysubstituted N-hydrocarbyloxy hindered amines are effective light stabilizers in protecting organic substrates against the deleterious effects of actinic light.

Inventors

  • 👤 James P. Galbo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:04
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C07; C07D; C07D211/00; C07D211/92; C07D211/94

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 234 words
A polysubstituted N-hydrocarbyloxy compound of the formula ##STR8## where n is 2 to 10, R 1 and R 2 are independently alkyl of 1 to 4 carbon atoms, or R 1 and R 2 together are pentamethylene, L is an n-valent radical of an alkane or alkene of 1 to 18 carbon atoms, an n-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, an n-valent radical of a bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or an n-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N--O groups are not necessarily attached to the same carbon atom in L, T is an organic moiety selected from the group consisting of E--COO--, E 1 --OCO--, E--CONR 3 -- ##STR9## E 1 NHCOCONH--, ##STR10## E 1 OCO(CH 2 ) m NH--, E 1 OCO(CH 2 )pCOO--, ##STR11## where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms, E 1 is methyl or ethyl, R 3 is hydrogen, alkyl of 1 to 8 carbon atoms or ##STR12## where L 1 is a monovalent radical of the definition of L, m is 2 to 4, p is 0 to 10, G is hydrogen or alkyl of 1 to 18 carbon atoms, and X is hydrogen or --CH 2 CH 2 COOC 12 H 25 .
Claim 2
Dependent Claim 234 words
A polysubstituted N-hydrocarbyloxy compound of the formula ##STR8## where n is 2 to 10, R 1 and R 2 are independently alkyl of 1 to 4 carbon atoms, or R 1 and R 2 together are pentamethylene, L is an n-valent radical of an alkane or alkene of 1 to 18 carbon atoms, an n-valent radical of a cycloalkane or cycloalkene of 5 to 12 carbon atoms, an n-valent radical of a bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms or an n-valent radical of an aryl, alkyl substituted aryl or aralkyl hydrocarbon of 6 to 15 carbon atoms, with the proviso that the N--O groups are not necessarily attached to the same carbon atom in L, T is an organic moiety selected from the group consisting of E--COO--, E 1 --OCO--, E--CONR 3 -- ##STR9## E 1 NHCOCONH--, ##STR10## E 1 OCO(CH 2 ) m NH--, E 1 OCO(CH 2 )pCOO--, ##STR11## where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms, E 1 is methyl or ethyl, R 3 is hydrogen, alkyl of 1 to 8 carbon atoms or ##STR12## where L 1 is a monovalent radical of the definition of L, m is 2 to 4, p is 0 to 10, G is hydrogen or alkyl of 1 to 18 carbon atoms, and X is hydrogen or --CH 2 CH 2 COOC 12 H 25 .
Claim 3
Dependent Claim 12 words
A compound according to claim 1 wherein n is 2 to 4.
Claim 4
Dependent Claim 15 words
A compound according to claim 1 wherein R 1 and R 2 are each methyl.
Claim 5
Dependent Claim 17 words
A compound according to claim 1 wherein L is an n-valent radical of n-octane, n-heptane or cyclohexane.
Claim 6
Dependent Claim 23 words
A compound according to claim 1 wherein T is E--COO-- where E is phenyl, vinyl or alkyl of 1 to 17 carbon atoms.
Claim 7
Dependent Claim 10 words
A compound according to claim 5 wherein E is heptadecyl.
Claim 8
Dependent Claim 21 words
A compound according to claim 1 wherein T is E--CONR 3 -- where R 3 is hydrogen and E is vinyl.
Claim 9
Dependent Claim 14 words
A compound according to claim 1 wherein T is ##STR13## where G is dodecyl.
Claim 10
Dependent Claim 9 words
The compound according to claim 1 which is 1,4-bis(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)-2-cyclohexene.
Claim 11
Dependent Claim 9 words
The compound according to claim 1 which is 1,8-bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-yl-oxy)octane.
Claim 12
Dependent Claim 9 words
The compound according to claim 1 which is bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)octane.
Claim 13
Dependent Claim 9 words
The compound according to claim 1 which is bis-(4-benzoyloxy-2,2,6,6-tetramethylpiperidin-1-yloxy)methane.

References Cited (Backward Citations)

US4191829A Cited
US4426472A Cited
US4762872A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-06-03 1994-12-03 1995-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-06-03 1998-12-03 1999-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-06-03 2002-12-03 2003-06-04 $7700.00 Window Closed / Lapsed

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