Light stabilization of metallic lacquers

Claim 3

The method of claim 1 wherein said compound is a light stabiliser of the formula (II) ##STR21## in which n is a number from 1-4 inclusive; R is hydrogen or methyl; R 1 is hydrogen, oxyl, C 1 -C 18 alkyl, C 3 -C 8 alkenyl, C 1 -C 8 alkynyl, C 7 -C 12 aralkyl, C 1 -C 8 alkanoyl, C 3 -C 5 alkenoyl, glycidyl or a group --CH 2 --CH(OH)--Z wherein Z is hydrogen, methyl or phenyl; and R 2 when n is 1 is hydrogen, C 1 -C 18 alkyl optionally interrupted by one or more oxygen atoms, cyanoethyl, benzyl, glycidyl, a monovalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic carboxylic acid, or of carbamic acid or of a phosphorus-containing acid, or a monovalent silyl radical; R 2 when n is 2 is C 2 -C 12 alkylene, C 4 -C 12 alkenylene, xylylene, a bivalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic dicarboxylic acid, of dicarbamic acid or of a phosphorus-containing acid, or a bivalent silyl radical; R 2 when n is 3 is a trivalent radical of an aliphatic, cycloaliphatic or aromatic tricarboxylic acid, of an aromatic tricarbamic acid or of a phosphorus-containing acid, or a trivalent silyl radical; and R 2 when n is 4 is a tetravalent radical of an aliphatic, cycloaliphatic or aromatic tetracarboxylic acid.

Claim 4

The method of claim 2 wherein said light stabiliser of the formula (II) in which n is the number 1 or 2; R is hydrogen or methyl; R 1 is hydrogen, C 1 -C 12 alkyl, allyl, benzyl, acetyl or acryloyl; and R 2 when n is 1 is a radical of an aliphatic carboxylic acid having 2-18 C atoms, of a cycloaliphatic carboxylic acid having 5-12 C atoms or of an aromatic carboxylic acid having 7-15 C atoms; and R 2 when n is 2 is a radical of an aliphatic dicarboxylic acid having 2-36 C atoms, of a cycloaliphatic or aromatic dicarboxylic acid having 8-14 C atoms, or of an aliphatic, cycloaliphatic or aromatic dicarbamic acid having 8-14 C atoms.

Claim 5

The method of claim 1 wherein said compound is a light stabiliser of the formula (III) ##STR22## in which n is the number 1 or 2; R is hydrogen or methyl; R 1 is hydrogen, oxyl, C 1 -C 18 alkyl, C 3 -C 8 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 aralkyl, C 1 -C 8 alkanoyl or C 3 -C 5 alkenoyl; R 3 is hydrogen, C 1 -C 12 alkyl, C 5 -C 7 cycloalkyl, C 7 -C 8 aralkyl, C 2 -C 18 alkanoyl, C 3 -C 5 alkenoyl or benzoyl; and R 4 when n is 1 is hydrogen, C 1 -C 18 alkyl, C 5 -C 7 cycloalkyl, C 2 -C 8 alkenyl which is unsubstituted or substituted by a cyano, carbonyl or carbamide group, or it is glycidyl, a group of the formula --CH 2 --CH(OH)--Z or of the formula --CONH--Z wherein Z is hydrogen, methyl or phenyl; or R 4 when n is 2 is C 2 -C.sub. 12 alkylene, C 6 -C 12 arylene, xylilene, a --CH 2 --CH(OH)--CH 2 -- group or a group --CH 2 --CH(OH)--CH 2 --(X--O--CH 2 --CH(OH)--CH 2 -- wherein X is C 2 -C 10 alkylene, C 6 -C 15 arylene or C 6 -C 12 cycloalkylene; or, provided that R 3 is not alkanoyl, alkenoyl or benzoyl, R 4 can also be a bivalent radical of an aliphatic, cycloaliphatic or aromatic dicarboxylic acid or dicarbamic acid, or can also be the group --CO--; or R 3 and R 4 together when n is 1 can be the cyclic radical of an aliphatic or aromatic 1,2- or 1,3-dicarboxylic acid.

Claim 6

The method of claim 1 wherein said compound is a light stabiliser of the formula (IV) ##STR23## in which n is the number 1 or 2; R is hydrogen or methyl; R 1 is hydrogen, oxyl, C 1 -C 18 alkyl, C 3 -C 8 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 aralkyl, C 1 -C 8 alkanoyl or C 3 -C 5 alkenoyl; and R 5 when n is 1 is C 2 -C 8 alkylene or hydroxyalkylene or C 4 -C 22 acyloxyalkylene; and R 5 when n is 2 is the group (--CH 2 ) 2 C(CH 2 --) 2 .

Claim 7

The method of claim 1 wherein said compound is a light stabiliser of the formula (V) ##STR24## in which n is the number 1 or 2; R is hydrogen or methyl; R 1 is hydrogen, oxyl, C 1 -C 18 alkyl, C 3 -C 8 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 aralkyl, C 1 -C 8 alkanoyl or C 3 -C 5 alkenoyl; R 6 is hydrogen, C 1 -C 12 alkyl, allyl, benzyl, glycidyl or C 2 -C 6 alkoxyalkyl; and R 7 when n is 1 is hydrogen, C 1 -C 12 alkyl, C 3 -C 5 alkenyl, C 7 -C 9 aralkyl, C 5 -C 7 cycloalkyl, C 2 -C 4 hydroxyalkyl, C 2 -C 6 alkoxyalkyl, C 6 -C 10 aryl, glycidyl, a group of the formula --(CH 2 ) m --COO--Q or of the formula --(CH 2 ) m --O--CO--Q wherein m is 1 or 2, and Q is C 1 -C 4 alkyl or phenyl; or R 7 when n is 2 is C 2 -C 12 alkylene or C 6 -C 12 arylene, a group --CH 2 --CH(OH)--CH 2 --O--X--O--CH 2 --CH(OH)--CH 2 -- wherein X is C 2 -C 10 alkylene, C 6 -C 15 arylene or C 6 -C 12 cycloalkylene, or a group --CH 2 CH(OZ') CH 2 --(OCH 2 --CH(OZ')CH 2 ) 2 -- wherein Z' is hydrogen, C 1 -C 18 alkyl, allyl, benzyl, C 2 -C 12 alkanoyl or benzoyl.

Claim 8

The method of claim 1 wherein said compound is a light stabiliser of the formula (VI) ##STR25## in which n is the number 1 or 2; and R 8 is a group of the formula ##STR26## in which R is as defined under the formula (I), R 1 is as defined under (a), Y is --O-- or --NR 11 --, A is C 2 -C 6 alkylene; and m is the number 0 or 1; R 9 is the groups R 8 , NR 11 R 12 , --OR 13 , --NHCH 2 OR 13 or --N(CH 2 OR 13 ) 2 ; R 10 when n is 1 is the groups R 8 or R 9 ; and R 10 when n is 2 is the group --Y--Q--Y-- wherein Q is C 2 -C 6 alkylene optionally interrupted by --N(R 14 )--; R 11 is C 1 -C 12 alkyl, cyclohexyl, benzyl or C 1 -C 4 hydroxyalkyl, or a group of the formula ##STR27## R 12 is C 1 -C 12 alkyl, cyclohexyl, benzyl, C 1 -C 4 hydroxyalkyl; R 13 is hydrogen, C 1 -C 12 alkyl or phenyl; and R 14 is hydrogen or the group --CH 2 OR 13 ; or R 11 and R 12 together are C 4 -C 5 alkylene or oxaalkylene, or R 11 and R 12 are each a group of the formula ##STR28##

Claim 9

The method of claim 1 wherein said compound is a light stabiliser of the formula (VII) ##STR29## in which n is the number 1 or 2; R is hydrogen or methyl; and R 14 when n is 1 is C 4 -C 18 alkyl, C 7 -C 12 aralkyl, the group --CO--R 15 , or C 1 -C 4 alkyl which is substituted by --CN, --COOR 16 , --OH, --OCOR 17 or ##STR30## wherein R 15 is C 1 -C 12 alkyl, C 2 -C 4 alkenyl or phenyl, R 16 is C 1 -C 18 alkyl, R 17 is C 1 -C 18 alkyl, C 2 -C 10 alkenyl, cyclohexyl, benzyl or C 6 -C 10 aryl; or R 14 when n is 2 is C 4 -C 12 alkylene, 2-butenylene-1,4, xylylene, the group --(CH 2 ) 2 --OOC--R 18 --COO--(CH 2 ) 2 -- or the group --CH 2 --OOC--R 19 --COO--CH 2 -- wherein R 18 is C 2 -C 10 alkylene, phenylene or cyclohexylene, and R 19 is C 2 -C 10 alkylene, xylylene or cyclohexylene.

Claim 10

The method of claim 1 wherein said compound is a light stabiliser of the formula (VIII) ##STR31## in which Q is --N(R 3 )-- or --O--; E is C 1 -C 3 alkylene, the group --CH 2 --CH(R 4 )--O-- wherein R 4 is hydrogen, methyl or phenyl, the group --(CH 2 ) 3 --NH-- or a single bond; R is hydrogen or methyl; R 1 is hydrogen, C 1 -C 18 alkyl, C 3 -C 8 alkenyl, C 3 -C 8 alkynyl, C 7 -C 12 aralkyl, C 1 -C 8 alkanoyl, C 3 -C 5 alkenoyl or glycidyl; R 2 is hydrogen or C 1 -C 18 alkyl; R 3 is hydrogen, C 1 -C 18 alkyl, C 5 -C 7 cycloalkyl, C 7 -C 12 aralkyl, cyanoethyl, C 6 -C 10 aryl, the group --CH 2 --CH(R 4 )--OH wherein R 4 has the meaning defined above, a group of the formula ##STR32## or a group of the formula ##STR33## wherein G can be C 2 -C 6 alkylene or C 6 -C 12 arylene; or R 3 is a group --E--CO--NH--CH 2 --OR 2 .

Claim 11

The method according to claim 1, wherein additional light stabilizers are incorporated in said resins, the amount of additional stabilizer being so chosen that the sum of all the light stabilizers is 0.02 to 5 percent by weight, relative to the solvent-free binder (lacquer resin).

Claim 12

The method according to claim 10, wherein antioxidants, plasticisers, levelling agents, curing accelerators, thickeners, dispersing agents or agents improving adhesion are added as further additives.

Claim 13

The method of claim 1, wherein metallic lacquers based on binder systems containing alkyd resin are stabilised.

Claim 14

The method of claim 1, wherein metallic lacquers based on hot-crosslinkable polyacrylate resins containing styrene incorporated by polymerisation are stabilised.

Claim 15

The method according to claim 1, wherein said compound is (di-2,2,6,6-tetramethylpiperidin-4-yl)-sebacate.