Hydroxylamines derived from hindered amines

Claim 1

A compound of formula D, G, I-K or M ##STR10## wherein R is hydrogen or methyl n is 1 or 2, R 1 is hydroxyl, R 6 is hydrogen, C 1 -C 12 alkyl, allyl, benzyl, glycidyl or C 2 -C 6 alkoxyalkyl; when n is 1 R 7 is hydrogen, C 1 -C 12 alkyl, C 3 -C 5 alkenyl, C 7 -C 9 aralkyl, C 5 -C 7 cycloalkyl, C 2 -C 4 hydroxyalkyl, C 2 -C 6 alkoxyalkyl, C 6 -C 10 aryl, glycidyl, a group of the formula --(CH 2 ) m --COO--Q or of the formula --(CH 2 ) m --O--CO--Q wherein m is 1 or 2, and Q is C 1 -C 4 alkyl or phenyl; or when n is 2, R 7 is C 2 -C 12 alkylene, C 6 -C 12 arylene, a group --CH 2 CH(OH)--CH 2 --O--X--O--CH 2 --CH(OH)--CH 2 -- wherein X is C 2 -C 10 alkylene, C 6 -C 15 arylene or C 6 -C 12 cycloalkylene, or a group --CH 2 CH(OZ 1 )CH 2 --(OCH 2 )CH 2 ) 2 -- wherein Z 1 is hydrogen, C 1 -C 18 alkyl, allyl, benzyl, C 2 -C 12 alkanoyl or benzoyl; when n is 1, T 4 is hydrogen, C 1 -C 18 alkyl, C 5 -C 7 cycloalkyl, C 2 -C 8 alkenyl unsubstituted or substituted by a cyano, carbonyl or carbamide group, or it is glycidyl, a group of the formula --CH 2 CH(OH)--Z or of the formula --CONH--Z and Z is hydrogen, methyl or phenyl; or when n is 2, T 4 is C 2 -C 12 alkylene, C 6 -C 12 arylene, xylylene, a --CH 2 CH(OH)--CH 2 group, or a group --CH 2 --CH(OH)--CH 2 --O--X--O--CH 2 --CH(OH)--CH 2 -- wherein X is C 2 -C 10 alkylene, C 6 -C 15 arylene or C 6 -C 12 cycloalkylene; or, provided that R 3 is not alkanoyl, alkenoyl or benzoyl, R 4 can also be divalent acyl radical of an aliphatic. cycloaliphatic or aromatic dicarboxylic acid or dicarbamic acid, or can be the group --CO--; or R 3 and R 4 together when p is 1 can be the cyclic acyl radical of an aliphatic or aromatic 1,2- or 1,3-dicarboxylic acid; T 5 is methyl, T 6 is methyl or ethyl, or T 5 and T 6 together are tetramethylene or pentamethylene; M and Y are independently methylene or carbonyl, but are not both carbonyl; T 10 and T 11 are independently alkylene of 2 to 12 carbon atoms, or T 11 is ##STR11## T 8 and T 9 are independently hydrogen, alkyl of 1 to 18 carbon atoms, or T 8 and T 9 together are alkylene of 4 to 6 carbon atoms, or 3-oxapentamethylene, k is 2 to 100, T 12 is ##STR12## where a, b and c are independently 2 or 3, and d is 0 or 1; and e is 3 or 4; E 1 and E 2 , being different, each are oxo or imino, E 3 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl, said phenyl or said naphthyl substituted by chloride or by alkyl of 1 to 4 carbon atoms, or phenylalkyl of 7 to 12 carbon atoms, or said phenylalkyl substituted by alkyl of 1 to 4 carbon atoms, and E 4 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl or phenylalkyl of 7 to 12 carbon atoms, or E 3 and E 4 together are polymethylene of 4 to 17 carbon atoms, or said polymethylene substituted by up to four alkyl groups of 1 to 4 carbon atoms.