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US5489641A Expired / Lapsed US ⏱️ 0.0 years remaining

Freeze resistant die-attach compositions

Assignee: QUANUM MATERIALS Inc
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Filing: 1993-02-26
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Granted: 1996-02-06
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Expires: 2013-02-26
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Abstract

Abstract In accordance with the present invention, there is provided a novel composition for attaching a semiconductor device to a substrate. The invention composition comprises liquid monomer vehicle comprising at least two monomers wherein at least one monomer is a polycyanate ester monomer, electrically conductive filler, and a curing catalyst. Compositions of the invention remain homogeneous at room temperature for at least eight hours.

Inventors

  • 👤 Stephen M. Dershem

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 02:53
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/22; C; C08; C08G; C08G73/00; C08G73/06; C08G73/0622; C08G73/0638; C08G73/065; C08G73/0655; C08K; C08K3/00; C08K3/02; C08K3/08

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 66 words
A composition for attaching a semiconductor device to a substrate comprising: 8 to 20 wt. percent monomer vehicle comprising at least two monomers, wherein at least one monomer is a polycyanate ester monomer, and wherein said monomer vehicle is free of solvent; 80 to 92 wt. percent electrically conductive filler; and 50 to 1500 ppm metal catalyst; wherein said monomer vehicle is liquid under ambient conditions.
Claim 2
Dependent Claim 66 words
A composition for attaching a semiconductor device to a substrate comprising: 8 to 20 wt. percent monomer vehicle comprising at least two monomers, wherein at least one monomer is a polycyanate ester monomer, and wherein said monomer vehicle is free of solvent; 80 to 92 wt. percent electrically conductive filler; and 50 to 1500 ppm metal catalyst; wherein said monomer vehicle is liquid under ambient conditions.
Claim 3
Dependent Claim 47 words
A composition according to claim 1 wherein said liquid monomer vehicle is selected from: vehicles consisting essentially of liquid monomers, vehicles consisting essentially of solid monomer(s) miscible and/or soluble in liquid monomer(s), or vehicles consisting essentially of solid monomers which, when combined, provide a liquid monomer mixture.
Claim 4
Dependent Claim 16 words
A composition according to claim 2 wherein said liquid monomer vehicle consists essentially of liquid monomers.
Claim 5
Dependent Claim 22 words
A composition according to claim 2 wherein said liquid monomer vehicle consists essentially of solid monomer(s) miscible and/or soluble in liquid monomer(s).
Claim 6
Dependent Claim 24 words
A composition according to claim 2 wherein said liquid monomer vehicle consists essentially of solid monomers which, when combined, provide a liquid monomer mixture.
Claim 7
Dependent Claim 44 words
A composition for attaching a semiconductor device to a substrate comprising: 13 to 20 wt. percent monomer vehicle comprising 1,1bis(4-cyanatophenyl)ethane(I) and 2,2-bis(4-cyanatophenyl)propane(II), wherein said monomer vehicle is free of solvent; 80 to 87 wt. percent silver filler; and 50 to 500 ppm cobalt acetylacetonate.
Claim 8
Dependent Claim 44 words
A composition for attaching a semiconductor device to a substrate comprising: 13 to 20 wt. percent monomer vehicle comprising 1,1bis(4-cyanatophenyl)ethane(I) and 2,2-bis(4-cyanatophenyl)propane(II), wherein said monomer vehicle is free of solvent; 80 to 87 wt. percent silver filler; and 50 to 500 ppm cobalt acetylacetonate.
Claim 9
Dependent Claim 39 words
A composition according to claim 6 wherein said monomers comprise from about 80 to about 95 wt. percent (I) and from about 5 to about 20 wt. percent (II), with the combined percentages representing total wt. percent monomer vehicle.
Claim 10
Dependent Claim 34 words
A composition according to claim 1 wherein additional monomer is selected from the group consisting of vinyl ethers, divinyl ethers, propargyl allyl ethers, monomaleimides, bismaleimides and mixtures of any two or more such monomers.
Claim 11
Dependent Claim 19 words
A composition according to claim 4 wherein said liquid monomer vehicle consists essentially of 1,1-bis(4-cyanatophenyl)ethane and cyclohexanedimethanol monovinyl ether.
Claim 12
Dependent Claim 17 words
A composition according to claim 5 wherein said liquid monomer vehicle consists essentially of 1,1-bis(4-cyanatophenyl)ethane and 1,1-bis(propargyloxyphenyl)ethane.
Claim 13
Dependent Claim 26 words
A composition according to claim 5 wherein said liquid monomer vehicle comprises at least one monomer selected from 2,2,4-trimethylhexamethylene-1,6-bismaleimide, 1,1-bis(4-propargyloxyphenyl)ethane, 3-(2,2-dimethyltrimethylene acetal)-1-maleimidobenzene or 2,2-bis[4-(4-maleimidophenoxy)-phenyl]propane and 1,1-bis(4-cyanatophenyl)ethane.
Claim 14
Dependent Claim 16 words
A composition according to claim 5 wherein said liquid monomer vehicle comprises 2,2-bis(4-cyanatophenyl) propane and 1,1-bis(4-cyanatophenyl)ethane.
Claim 15
Dependent Claim 17 words
A composition according to claim 1 wherein additional monomer is selected from diallyl ethers or dipropargyl ethers.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-02-05 1999-08-07 2000-02-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-02-05 2003-08-07 2004-02-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-02-05 2007-08-07 2008-02-06 $7700.00 Window Closed / Lapsed

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