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US5155066A Expired / Lapsed US ⏱️ 0.0 years remaining

Rapid-curing adhesive formulation for semiconductor devices

Assignee: National Starch and Chemical Investment Holding Corp
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Filing: 1991-12-06
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Granted: 1992-10-13
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Expires: 2011-12-06
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Abstract

Abstract A rapid curing adhesive formulation that contains 10-40 wt. % of a cyanate ester vehicle having a cyanate ester, alkylphenol and a metal curing catalyst and 60-90 wt. % of thermally and/or electrically conductive filler. The adhesive formulation has a maximum curing time of 5 minutes, preferably 2 minutes, at 200 DEG C. and is adapted for use in high speed processes for production of bonded semiconductor assemblies.

Inventors

  • 👤 My N. Nguyen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 23:37
CPC Classifications
H; H10; H10W; H10W40/00; H10W40/20; H10W40/25; H10W40/251; H10W20/00; H10W20/40; H10W72/00; H10W72/071; H10W72/073; H10W72/07331; H10W72/07337; H10W72/07338; H10W72/30; H10W72/351; H10W72/353; H10W72/354; Y; Y10; Y10S; Y10S148/00; Y10S148/021

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 178 words
A process for continuous production of bonded semiconductor assemblies comprising: preparing an adhesive formulation comprising 10 to 40 wt.% cyanate ester vehicle and 60 to 90 wt.% filler from a group consisting of thermally conductive filler, electrically conductive filler and thermally and electrically conductive filler, said cyanate ester vehicle comprising liquid cyanate ester having about 2 to 6 pph alkylphenol, about 50 to 500 ppm metal catalyst, and a viscosity of about 1 to 5 poise at 25° C., said filler comprising particulate material less than 70 microns, said adhesive formulation having the property of being capable of being cured in a maximum curing time of five minute at 200° C.; intermittently dispensing said adhesive as a film on portions of said substrate to provide intermittent film portions on said substrate; continuously placing semiconductor devices on said intermittent film portions to provide a bonding surface for each semiconductor device on said substrate and to produce a plurality of unbonded semiconductor assemblies; and continuously curing said adhesive of said unbonded semiconductor assemblies to effect bonding of said semiconductor assemblies.
Claim 2
Dependent Claim 178 words
A process for continuous production of bonded semiconductor assemblies comprising: preparing an adhesive formulation comprising 10 to 40 wt.% cyanate ester vehicle and 60 to 90 wt.% filler from a group consisting of thermally conductive filler, electrically conductive filler and thermally and electrically conductive filler, said cyanate ester vehicle comprising liquid cyanate ester having about 2 to 6 pph alkylphenol, about 50 to 500 ppm metal catalyst, and a viscosity of about 1 to 5 poise at 25° C., said filler comprising particulate material less than 70 microns, said adhesive formulation having the property of being capable of being cured in a maximum curing time of five minute at 200° C.; intermittently dispensing said adhesive as a film on portions of said substrate to provide intermittent film portions on said substrate; continuously placing semiconductor devices on said intermittent film portions to provide a bonding surface for each semiconductor device on said substrate and to produce a plurality of unbonded semiconductor assemblies; and continuously curing said adhesive of said unbonded semiconductor assemblies to effect bonding of said semiconductor assemblies.
Claim 3
Dependent Claim 16 words
A process according to claim 1 wherein said filler comprises particulate material less than 20 microns.
Claim 4
Dependent Claim 41 words
A process according to claim 1 wherein said alkylphenol comprises nonylphenol, said metal curing catalyst comprises a metal carboxylate or acetylacetonate, and said filler comprises at least one material from the group consisting of silver, nickel, silicon, alumina and aluminum nitride.
Claim 5
Dependent Claim 65 words
A process according to claim 1 wherein said adhesive formulation has a viscosity of about 100 to 1000 poise at 25° C. and a maximum curing time of 2.0 minutes, said filler has a maximum particle size of 20 microns and comprises one of the group consisting of silicon, silver, and nickel, and the metal curing catalyst comprises one of zinc, cobaltic and cobaltous acetylacetonate.
Claim 6
Dependent Claim 29 words
A process according to claim 1 wherein said adhesive formulation is dispensed in amounts not greater than two mg. as a thin film of less than 5 microns thickness.
Claim 7
Dependent Claim 21 words
A process according to claim 5 wherein said adhesive formulation is applied as a thin film of less than two microns.
Claim 8
Dependent Claim 14 words
A process according to claim 1 wherein the substrate is a metallic lead frame.
Claim 9
Dependent Claim 26 words
A process according to claim 1 wherein said filler comprises silver in an amount of 70 to 90 wt.% of total weight of the adhesive formulation.
Claim 10
Dependent Claim 13 words
A process according to claim 8 wherein the silver filler comprises silver flake.
Claim 11
Dependent Claim 15 words
A process according to claim 1 wherein said filler comprises alumina or aluminum nitride powder.
Claim 12
Dependent Claim 15 words
A process according to claim 1 wherein said substrate comprises a ceramic or metal substrate.
Claim 13
Dependent Claim 30 words
A process according to claim 1 further comprising the step of applying pressure on the semiconductor device in the uncured assembly so that the adhesive spreads under the semiconductor device.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-13 1996-04-13 1996-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-13 2000-04-13 2000-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-13 2004-04-13 2004-10-13 $7700.00 Window Closed / Lapsed

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