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US5385630A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for increasing sacrificial oxide etch rate to reduce field oxide loss

Assignee: Hewlett Packard Development Co LP
•
Filing: 1993-06-29
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Granted: 1995-01-31
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Expires: 2013-06-29
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Abstract

Abstract N 2 implantation is used to increase the etch rate of a sacrificial oxide (sometimes referred to as the first gate oxide) in integrated circuitry. This implantation allows etching selectivity by changing the relative etch rates of materials. In the specific implementation described, a field oxide is also provided and this implantation increases the etch rate of the sacrificial oxide relative to that of the field oxide. No heat treatment is applied to the implanted material prior to etching having the ability to repair the damage caused by the bombardment.

Inventors

  • 👤 Ara Philipossian
  • 👤 Hamid R. Soleimani
  • 👤 Brian S. Doyle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:12
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/282; H10P50/283

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 43 words
In the fabrication of integrated circuitry, the steps of: a) implanting a material on a substrate with nitrogen, to enhance the etchability of said material by an etchant by causing structural damage to said material; and b) exposing said material to said etchant.
Claim 2
Dependent Claim 43 words
In the fabrication of integrated circuitry, the steps of: a) implanting a material on a substrate with nitrogen, to enhance the etchability of said material by an etchant by causing structural damage to said material; and b) exposing said material to said etchant.
Claim 3
Dependent Claim 55 words
The fabrication process of claim 1 wherein said step of implanting causes damage to the atomic structure of said material, further including after said step of implanting but before said step of exposing, the step of maintaining the heat input to said material at less than that at which said damage will be meaningfully repaired.
Claim 4
Dependent Claim 16 words
The fabrication process of claim 1 wherein said implantation species particles are atomic or molecular particles.
Claim 5
Dependent Claim 34 words
The fabrication process of claim 1 wherein said material is silicon dioxide and said implantation is at a dose rate of at least 10 14 per square centimeter of surface of such silicon dioxide.
Claim 6
Dependent Claim 20 words
The fabrication process of claim 4 wherein said material is silicon dioxide formed by growth on a substrate of silicon.
Claim 7
Dependent Claim 21 words
The fabrication process of claim 1 wherein said step of exposing includes exposing said material to a diluent of hydrofluoric acid.
Claim 8
Dependent Claim 29 words
The fabrication process of claim 6 wherein said material is silicon dioxide grown on a substrate of silicon, and there is other silicon dioxide material deposited on said substrate.
Claim 9
Dependent Claim 20 words
The fabrication process of claim 6 wherein said diluent of hydrofluoric acid includes one or more constituents buffering said acid.
Claim 10
Dependent Claim 12 words
The fabrication process of claim 8 wherein said material is silicon dioxide.
Claim 11
Dependent Claim 29 words
In the fabrication of integrated circuitry, the step of tailoring nitrogen implantation of said material with a multitude of implantation conditions to customize the etch rate of said material.
Claim 12
Dependent Claim 29 words
In the fabrication of integrated circuitry, the step of tailoring nitrogen implantation of said material with a multitude of implantation conditions to customize the etch rate of said material.
Claim 13
Dependent Claim 12 words
The fabrication process of claim 10 wherein said material is silicon dioxide.
Claim 14
Dependent Claim 26 words
The fabrication process of claim 11 further including the step of exposing said material after said tailoring to a diluent of hydrofluoric acid as an etchant.
Claim 15
Dependent Claim 21 words
In the fabrication of integrated circuitry, increasing the etch rate of a silicon dioxide layer by implanting nitrogen in the same.
Claim 16
Dependent Claim 21 words
In the fabrication of integrated circuitry, increasing the etch rate of a silicon dioxide layer by implanting nitrogen in the same.
Claim 17
Dependent Claim 32 words
The fabrication process of integrated circuitry of claim 13 further including the step of exposing said silicon dioxide after said implantation to an etchant made up of a diluent of hydrofluoric acid.

References Cited (Backward Citations)

US4268347A Cited
JPS58131A Cited
JPS5898932A Cited
US4530734A Cited
JPS60240131A Cited
JPS61222137A Cited
US4978418A Cited
US4999083A Cited
JPH0360032A Cited
US5135605A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-01-30 1998-08-01 1999-01-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-01-30 2002-08-01 2003-01-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-01-30 2006-08-01 2007-01-31 $7700.00 Window Closed / Lapsed

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