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US5373522A Expired / Lapsed US ⏱️ 0.0 years remaining

Semiconductor devices with native aluminum oxide regions

Assignee: University of Illinois System
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Filing: 1993-09-07
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Granted: 1994-12-13
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Expires: 2013-09-07
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Abstract

Abstract A method of forming a native oxide from an aluminum-bearing Group III-V semiconductor material is provided. The method entails exposing the aluminum-bearing Group III-V semiconductor material to a water-containing environment and a temperature of at least about 375 DEG C. to convert at least a portion of said aluminum-bearing material to a native oxide characterized in that the thickness of said native oxide is substantially the same as or less than the thickness of that portion of said aluminum-bearing Group III-V semiconductor material thus converted. The native oxide thus formed has particular utility in electrical and optoelectrical devices, such as lasers.

Inventors

  • 👤 Nick Holonyak, Jr.
  • 👤 John M. Dallesasse

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:02
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6322; H01; H01S; H01S5/00; H01S5/20; H01S5/2054; H01S5/2059; H01S5/22; H01S5/2205; H01S5/2214; H01S5/2215; H01S5/40; H01S5/4025; H01S5/4031; H10P14/6304; H10P14/6306; H10P14/6312; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; H10P14/69391; Y; Y10; Y10S; Y10S148/00; Y10S148/065; Y10S148/116; Y10S148/117; Y10S148/118

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 162 words
A semiconductor laser which comprises: a semiconductor substrate layer; a first confining layer on said substrate layer; an active region on said first confining layer; a second confining layer on said active region, said second confining layer comprised of a first aluminum-bearing Group III-V semiconductor material; a current blocking layer on said second confining layer, said current blocking layer comprising a native oxide formed by the method of exposing at least part of the surface of said second confining layer to a water-containing environment and a temperature of at least about 375° C. for a time sufficient to convert at least a portion of said second confining layer to said native oxide, the thickness of said native oxide layer being substantially the same as or less than the thickness of that portion of said second confining layer thus converted; reflective facets at opposing edges of said active region; and means for applying an electric potential across said first and second confining layers.
Claim 2
Dependent Claim 162 words
A semiconductor laser which comprises: a semiconductor substrate layer; a first confining layer on said substrate layer; an active region on said first confining layer; a second confining layer on said active region, said second confining layer comprised of a first aluminum-bearing Group III-V semiconductor material; a current blocking layer on said second confining layer, said current blocking layer comprising a native oxide formed by the method of exposing at least part of the surface of said second confining layer to a water-containing environment and a temperature of at least about 375° C. for a time sufficient to convert at least a portion of said second confining layer to said native oxide, the thickness of said native oxide layer being substantially the same as or less than the thickness of that portion of said second confining layer thus converted; reflective facets at opposing edges of said active region; and means for applying an electric potential across said first and second confining layers.
Claim 3
Dependent Claim 68 words
The semiconductor laser of claim 1 wherein said substrate layer comprises an aluminum-free Group III-V semiconductor material, said first confining layer comprises a second aluminum-bearing Group III-V semiconductor material, said active region comprises at least two waveguide layers of a third aluminum-bearing Group III-V semiconductor material and a quantum well heterostructure disposed between said waveguide layers said quantum well heterostructure comprising a fourth aluminum-bearing Group III-V semiconductor material.
Claim 4
Dependent Claim 34 words
The semiconductor laser of claim 1 further comprising a contact layer disposed intermittently on the surface of said second confining layer at areas of said second confining layer not converted to said native oxide.
Claim 5
Dependent Claim 18 words
The semiconductor laser of claim 3 wherein said contact layer is intermittently disposed in a single stripe configuration.
Claim 6
Dependent Claim 18 words
The semiconductor laser of claim 3 wherein said contact layer is intermittently disposed in a multiple stripe configuration.
Claim 7
Dependent Claim 91 words
A semiconductor light emitting device, comprising: a semiconductor active region disposed between first and second confining regions of semiconductor material; an insulating region adjacent said second confining region, said insulating region comprising a native oxide formed from an aluminum-bearing III-V semiconductor material by exposing said aluminum-bearing III-V semiconductor material to a water containing environment and a temperature of at least about 375° C. to convert at least a portion of said III-V semiconductor material to said native oxide; and means for applying electric potential across said upper and lower confining regions.
Claim 8
Dependent Claim 91 words
A semiconductor light emitting device, comprising: a semiconductor active region disposed between first and second confining regions of semiconductor material; an insulating region adjacent said second confining region, said insulating region comprising a native oxide formed from an aluminum-bearing III-V semiconductor material by exposing said aluminum-bearing III-V semiconductor material to a water containing environment and a temperature of at least about 375° C. to convert at least a portion of said III-V semiconductor material to said native oxide; and means for applying electric potential across said upper and lower confining regions.
Claim 9
Dependent Claim 21 words
The semiconductor light-emitting device as defined by claim 6, wherein said first and second confining regions are of opposite semiconductor types.
Claim 10
Dependent Claim 19 words
The semiconductor light emitting device as defined by claim 6, wherein said aluminum-bearing III-V material is aluminum gallium arsenide.
Claim 11
Dependent Claim 19 words
The semiconductor light emitting device as defined by claim 7, wherein said aluminum-bearing III-V material is aluminum gallium arsenide.
Claim 12
Dependent Claim 99 words
A semiconductor laser device, comprising: a semiconductor active region disposed between first and second confining regions of semiconductor material; an insulating region adjacent said second confining region, said insulating region comprising a native oxide formed from an aluminum-bearing III-V semiconductor material by exposing said aluminum-bearing III-V semiconductor material to a water containing environment and a temperature of at least about 375° C. to convert at least a portion of said III-V semiconductor material to said native oxide; and reflective facets at opposing edges of said active region; means for applying electric potential across said upper and lower confining regions.
Claim 13
Dependent Claim 99 words
A semiconductor laser device, comprising: a semiconductor active region disposed between first and second confining regions of semiconductor material; an insulating region adjacent said second confining region, said insulating region comprising a native oxide formed from an aluminum-bearing III-V semiconductor material by exposing said aluminum-bearing III-V semiconductor material to a water containing environment and a temperature of at least about 375° C. to convert at least a portion of said III-V semiconductor material to said native oxide; and reflective facets at opposing edges of said active region; means for applying electric potential across said upper and lower confining regions.
Claim 14
Dependent Claim 21 words
The semiconductor light-emitting device as defined by claim 10, wherein said first and second confining regions are of opposite semiconductor types.
Claim 15
Dependent Claim 19 words
The semiconductor light emitting device as defined by claim 10, wherein said aluminum-bearing III-V material is aluminum gallium arsenide.
Claim 16
Dependent Claim 19 words
The semiconductor light emitting device as defined by claim 11, wherein said aluminum-bearing III-V material is aluminum gallium arsenide.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-12-12 1998-06-13 1998-12-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-12-12 2002-06-13 2002-12-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-12-12 2006-06-13 2006-12-13 $7700.00 Window Closed / Lapsed

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