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US5322757A Expired / Lapsed US ⏱️ 0.0 years remaining

Positive photoresists comprising a novolak resin made from 2,3-dimethyl phenol,2,3,5-trimethylphenol and aldehyde with no meta-cresol present

Assignee: Olin Microelectronic Chemicals Inc
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Filing: 1993-03-24
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Granted: 1994-06-21
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Expires: 2013-03-24
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Abstract

Abstract Improved photoresist compositions having high resolution and high thermal resistance, produced from certain novolak polymers and diazoquinone photosensitizers. The useful novolak polymers are formed from phenolic mixtures including 2,3,5-trimethyl phenol and/or 2,3-dimethyl phenol, and optional amounts of 2,6-dimethyl phenol, o-cresol and p-cresol.

Inventors

  • 👤 Charles E. Ebersole

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:02
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/023; G03F7/0233; G03F7/0236

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 85 words
A positive resist composition comprising an admixture of, on a solids basis, about 60% to about 95% by weight of novolak resin and about 5% to about 40% by weight of diazoquinone sensitizer; said novolak resin formed by the reaction of a phenolic mixture with aldehyde and wherein said phenolic mixture contains, based on the total weight of phenolic compounds present therein, from about 2% to about 60% by weight 2,3,5-trimethylphenol and about 2% to about 95% by weight of 2,3-dimethylphenol and contains no meta-cresol.
Claim 2
Dependent Claim 85 words
A positive resist composition comprising an admixture of, on a solids basis, about 60% to about 95% by weight of novolak resin and about 5% to about 40% by weight of diazoquinone sensitizer; said novolak resin formed by the reaction of a phenolic mixture with aldehyde and wherein said phenolic mixture contains, based on the total weight of phenolic compounds present therein, from about 2% to about 60% by weight 2,3,5-trimethylphenol and about 2% to about 95% by weight of 2,3-dimethylphenol and contains no meta-cresol.
Claim 3
Dependent Claim 32 words
The positive resist composition of claim 1 wherein said phenolic mixture contains, based on the total weight of phenolic compounds present therein, from about 20% to about 60% by weight of 2,3,5-trimethylphenol.
Claim 4
Dependent Claim 30 words
The positive resist composition of claim 1 wherein said phenolic mixture further contains, based on the total weight of phenolic compounds present therein, up to 15% by weight of 2,6-dimethylphenol.
Claim 5
Dependent Claim 30 words
The positive resist composition of claim 1 wherein said phenolic mixture further contains, based on the total weight of phenolic compounds present therein, up to 60% by weight of p-cresol.
Claim 6
Dependent Claim 30 words
The resist composition of claim 1 wherein said phenolic mixture further contains, based on the total weight of phenolic compounds contained therein, up to about 60% by weight of o-cresol.
Claim 7
Dependent Claim 20 words
The positive resist composition of claim 1 wherein said novolak resin has a molecular weight between about 1,000 to 6,000.
Claim 8
Dependent Claim 19 words
The positive resist composition of claim 1 wherein said novolak resin has a softening point above about 140° C.
Claim 9
Dependent Claim 23 words
The positive resist composition of claim 1 wherein the molar ratio of aldehyde to phenolic mixture is from about 1:1 to about 1.15:1.
Claim 10
Dependent Claim 12 words
The positive resist composition of claim 1 wherein said diazoquinone comprises 2,1,5-diazonaphtoquinone.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-20 1997-12-20 1998-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-20 2001-12-20 2002-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-20 2005-12-20 2006-06-21 $7700.00 Window Closed / Lapsed

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