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US5254653A Expired / Lapsed US ⏱️ 0.0 years remaining

Terpolymer rubber of styrene, isoprene and butadiene

Assignee: Goodyear Tire and Rubber Co
•
Filing: 1992-05-18
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Granted: 1993-10-19
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Expires: 2012-05-18
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Abstract

Abstract A styrene, isoprene, butadiene terpolymer rubber with a characterization according to its glass transition temperatures and unit structure and a pneumatic tire with a tread composed of such terpolymer rubber specifically in combination with selected other rubber.

Inventors

  • 👤 Adel F. Halasa
  • 👤 Jean Bergh
  • 👤 Fernand A. J. Fourgon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 16:10
CPC Classifications
C; C08; C08L; C08L9/00; C08L9/06; B; B60; B60C; B60C1/00; B60C1/0016; C08F; C08F236/00; C08F236/02; C08F236/04; C08F236/10; C08L9/08; C08L7/00

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 215 words
A linear styrene, isoprene, butadiene terpolymer rubber (SIBR) which is comprised of (1) about 6 to about 40 weight percent bound styrene; (2) about 20 to about 65 weight percent bound isoprene; and (3) about 10 to about 50 weight percent bound butadiene and is characterized by having a single glass transition temperature (Tg) which is in the range of about -10° C. to -75° C. a heterogeneity index in the range of about 1.5 to about 2.4 and a ML4(100) viscosity in the range of about 70 to about 100, and further characterized in that at least 98 percent of its styrene is contained in sequential styrene units of 5 or less, and at least 75 percent of its styrene is contained in sequential styrene units of 2 or less and the bound butadiene structure contains about 8 to about 40 percent 1,2-vinyl units with the remainder being essentially composed of 1,4-configured units, the said bound isoprene structure contains about 8 to about 50 percent 3,4-vinyl units with the remainder being essentially 1,4-configured units with less than about 2 percent 1,2-configured units and the sum of the said percent 1,2-vinyl units of the bound butadiene and the percent 3,4 units of the bound isoprene is in the range of about 20 to about 90.
Claim 2
Dependent Claim 215 words
A linear styrene, isoprene, butadiene terpolymer rubber (SIBR) which is comprised of (1) about 6 to about 40 weight percent bound styrene; (2) about 20 to about 65 weight percent bound isoprene; and (3) about 10 to about 50 weight percent bound butadiene and is characterized by having a single glass transition temperature (Tg) which is in the range of about -10° C. to -75° C. a heterogeneity index in the range of about 1.5 to about 2.4 and a ML4(100) viscosity in the range of about 70 to about 100, and further characterized in that at least 98 percent of its styrene is contained in sequential styrene units of 5 or less, and at least 75 percent of its styrene is contained in sequential styrene units of 2 or less and the bound butadiene structure contains about 8 to about 40 percent 1,2-vinyl units with the remainder being essentially composed of 1,4-configured units, the said bound isoprene structure contains about 8 to about 50 percent 3,4-vinyl units with the remainder being essentially 1,4-configured units with less than about 2 percent 1,2-configured units and the sum of the said percent 1,2-vinyl units of the bound butadiene and the percent 3,4 units of the bound isoprene is in the range of about 20 to about 90.
Claim 3
Dependent Claim 119 words
The SIBR of claim 1 which is composed of (1) about 8 to about 25 weight percent bound styrene; (2) about 20 to about 50 weight percent bound isoprene; (3) about 10 to about 25 weight percent bound butadiene and is characterized by having a single Tg which is in the range of about -20° C. to about -40° C. and where the bound butadiene structure contains about 20 to about 35 percent 1,2-vinyl units, the bound isoprene structure contains about 20 to about 35 percent 3,4-vinyl units and the sum of the said percent 1,2-vinyl unit of the bound butadiene and the 3,4 units of the bound isoprene is in the range of about 40 to about 70.
Claim 4
Dependent Claim 119 words
The SIBR of claim 1 which is composed of (1) about 15 to about 25 weight percent bound styrene; (2) about 40 to about 60 weight percent bound isoprene; (3) about 20 to about 40 weight percent bound butadiene and is characterized by having a single Tg which is in the range of about -20° C. to about -40° C. and where the bound butadiene structure contains about 8 to about 40 percent 1,2-vinyl units, the bound isoprene structure contains about 8 to about 50 percent 3,4-vinyl units and the sum of the said percent 1,2-vinyl units of the bound butadiene and the 3,4 units of the bound isoprene is in the range of about 20 to about 90.
Claim 5
Dependent Claim 119 words
The SIBR of claim 1 which is composed of (1) about 6 to about 15 weight percent bound styrene; (2) about 25 to about 65 weight percent bound isoprene; (3) about 20 to about 40 weight percent bound butadiene and is characterized by having a single Tg which is in the range of about -60° C. to about -75° C. and where the bound butadiene structure contains about 10 to about 18 percent 1,2-vinyl units, the bound isoprene structure contains about 8 to about 12 percent 3,4-vinyl units and the sum of the said percent 1,2-vinyl units of the bound butadiene and the 3,4 units of the bound isoprene is in the range of about 20 to about 30.
Claim 6
Dependent Claim 118 words
The SIBR of claim 1 which is composed of (1) about 6 to about 20 weight percent bound styrene; (2) about 30 to about 40 weight percent bound isoprene; (3) about 40 to about 50 weight percent bound butadiene and is characterized by having a single Tg which is in the range about -40° C. to about -60° C. and where the bound butadiene structure contains about 10 to about 25 percent 1,2-vinyl units, the bound isoprene structure contains about 12 to about 18 percent 3,4-vinyl units and the sum of the said percent 1,2-vinyl units of the bound butadiene and the 3,4 units of the bound isoprene is in the range of about 22 to about 43.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-10-18 1997-04-19 1997-10-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-10-18 2001-04-19 2001-10-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-10-18 2005-04-19 2005-10-19 $7700.00 Window Closed / Lapsed

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