Silicon nitride based composite with improved fracture toughness

Claim 1

A method for continuous or interrupted machine cutting of cast iron stock comprising the step of milling, turning, or boring with a shaped tool of a densified abrasion and fracture resistant composite material comprising: about 5-60% by volume of one or more first dispersoid materials selected from the group consisting of whiskers of carbides, nitrides, and carbonitrides of titanium, hafnium, tantalum, niobium, and tungsten, and solid solutions thereof; and optionally, one or more other dispersoid materials selected from the group consisting of particles and polycrystalline fibers of carbides, nitrides, and carbonitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, and silicon carbide, titanium diboride, hafnium diboride, and alumina, and mixtures and solid solutions thereof; wherein the combined dispersoid materials comprise about 5-70% by volume of the densified composite material; the remainder of the densified composite material being a two-phase matrix comprising a first phase of silicon nitride grains and a second, continuous intergranular phase formed from one or more suitable densification aids; wherein the dispersoid materials are substantially uniformly distributed in the two-phase matrix, and the densified composite material has a density greater than about 98% or theoretical and a fracture toughness greater than or equal to 3.5 MPa.m 1/2 .

Claim 2

A method for continuous or interrupted machine cutting of cast iron stock comprising the step of milling, turning, or boring with a shaped tool of a densified abrasion and fracture resistant composite material comprising: about 5-60% by volume of one or more first dispersoid materials selected from the group consisting of whiskers of carbides, nitrides, and carbonitrides of titanium, hafnium, tantalum, niobium, and tungsten, and solid solutions thereof; and optionally, one or more other dispersoid materials selected from the group consisting of particles and polycrystalline fibers of carbides, nitrides, and carbonitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, and silicon carbide, titanium diboride, hafnium diboride, and alumina, and mixtures and solid solutions thereof; wherein the combined dispersoid materials comprise about 5-70% by volume of the densified composite material; the remainder of the densified composite material being a two-phase matrix comprising a first phase of silicon nitride grains and a second, continuous intergranular phase formed from one or more suitable densification aids; wherein the dispersoid materials are substantially uniformly distributed in the two-phase matrix, and the densified composite material has a density greater than about 98% or theoretical and a fracture toughness greater than or equal to 3.5 MPa.m 1/2 .

Claim 3

A method for continuous or interrupted machine cutting of high nickel alloy stock comprising at least 50% nickel comprising the step of milling, turning, or boring with a shaped tool of a densified abrasion and fracture resistant composite material comprising: about 5-60% by volume of one or more first dispersoid materials selected from the group consisting of whiskers of carbides, nitrides, and carbonitrides of titanium, hafnium, tantalum, niobium, and tungsten, and solid solutions, thereof; and optionally, one or more other dispersoid materials selected from the group consisting of particles and polycrystalline fibers of carbides, nitrides, and carbonitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, and silicon carbide, titanium diboride, hafnium diboride, and alumina, and mixtures and solid solutions thereof; wherein the combined dispersoid materials comprise about 5-70% by volume of the densified composite material; the remainder of the densified composite material being a two-phase matrix comprising a first phase of silicon nitride grains and a second, continuous intergranular phase formed from one or more suitable densification aids; wherein the dispersoid materials are substantially uniformly distributed in the two-phase matrix, and the densified composite material has a density greater than about 98% or theoretical and a fracture toughness greater than or equal to 3.5 MPa.m 1/2 .

Claim 4

A method for continuous or interrupted machine cutting of high nickel alloy stock comprising at least 50% nickel comprising the step of milling, turning, or boring with a shaped tool of a densified abrasion and fracture resistant composite material comprising: about 5-60% by volume of one or more first dispersoid materials selected from the group consisting of whiskers of carbides, nitrides, and carbonitrides of titanium, hafnium, tantalum, niobium, and tungsten, and solid solutions, thereof; and optionally, one or more other dispersoid materials selected from the group consisting of particles and polycrystalline fibers of carbides, nitrides, and carbonitrides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten, and silicon carbide, titanium diboride, hafnium diboride, and alumina, and mixtures and solid solutions thereof; wherein the combined dispersoid materials comprise about 5-70% by volume of the densified composite material; the remainder of the densified composite material being a two-phase matrix comprising a first phase of silicon nitride grains and a second, continuous intergranular phase formed from one or more suitable densification aids; wherein the dispersoid materials are substantially uniformly distributed in the two-phase matrix, and the densified composite material has a density greater than about 98% or theoretical and a fracture toughness greater than or equal to 3.5 MPa.m 1/2 .