US4543345A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silicon carbide whisker reinforced ceramic composites and method for making same
Assignee: United States Department of Energy
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Filing: 1984-02-09
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Granted: 1985-09-24
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Expires: 2004-02-09
Abstract
Abstract The present invention is directed to the fabrication of ceramic composites which possess improved mechanical properties especially increased fracture toughness. In the formation of these ceramic composites, the single crystal SiC whiskers are mixed with fine ceramic powders of a ceramic material such as Al2O3, mullite, or B4C. The mixtures which contain a homogeneous dispersion of the SiC whiskers are hot pressed at pressures in a range of about 28 to 70 MPa and temperatures in the range of about 1600 DEG to 1950 DEG C. with pressing times varying from about 0.75 to 2.5 hours. The resulting ceramic composites show an increase in fracture toughness of up to about 9 MPa.m1/2 which represents as much as a two-fold increase over that of the matrix material.
Inventors
- 👤 George C. Wei
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 13:59
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/56; C04B35/563; C04B35/622; C04B35/64; C04B35/645; C04B35/71; C04B35/78; C04B35/80
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
77 words
A ceramic composite characterized by increased toughness and resistance to fracture, comprising a composite defined by a matrix of ceramic material having homogeneously dispersed therein about 5 to 60 vol. % of silicon carbide whiskers, with said silicon carbide whiskers having a monocrystalline structure and in a size range of about 0.6 μm in diameter and a length of 10 to 80 μm, said composite being of a density greater than about 99% of the theoretical density.
Claim 2
Dependent Claim
77 words
A ceramic composite characterized by increased toughness and resistance to fracture, comprising a composite defined by a matrix of ceramic material having homogeneously dispersed therein about 5 to 60 vol. % of silicon carbide whiskers, with said silicon carbide whiskers having a monocrystalline structure and in a size range of about 0.6 μm in diameter and a length of 10 to 80 μm, said composite being of a density greater than about 99% of the theoretical density.
Claim 3
Dependent Claim
19 words
The ceramic composite claimed in claim 1, wherein the silicon carbide whiskers are essentially unidirectionally oriented in the matrix.
Claim 4
Dependent Claim
70 words
The ceramic composite claimed in claim 2, wherein the matrix is Al 2 O 3 , the concentration of silicon carbide whiskers in the matrix is about 20 vol. %, wherein fracture toughness of the composite is in the range of about 8 to 9 MPa.m 1/2 at room temperature, and wherein fracture strength of the composite is in the range of about 590 to 899 MPa at room temperature.
Claim 5
Dependent Claim
59 words
The ceramic composite claimed in claim 2 wherein the matrix is 3Al 2 O 3 .2SiO 2 , the concentration of silicon carbide whiskers in the composite is about 20 vol. % wherein fracture toughness of the composition is 4.6 MPa.m 1/2 at room temperature, and wherein fracture strength of the composite is about 438 MPa at room temperature.
Claim 6
Dependent Claim
19 words
The ceramic composite claimed in claim 1, wherein the silicon carbide whiskers are essentially omnidirectionally oriented in the matrix.
Claim 7
Dependent Claim
35 words
The ceramic composite claimed in claim 1, wherein the ceramic matrix material is selected from the group consisting of Al 2 O 3 , 3Al 2 O 3 .2SiO 2 , and B 4 C.
Claim 8
Independent Claim
115 words
A method for preparing a ceramic composite having increased toughness and resistance to fracture, comprising the steps of forming a homogeneous mixture of particulate ceramic material with about 5 to 60 vol. % of silicon carbide whiskers having a monocrystalline structure and in a size range of about 0.6 μm diameter and a length of about 10 to 80 μm, and hot pressing the mixture at a pressure in the range of about 28 to 70 MPa and temperature in the range of about 1600° to 1900° C. for a duration of 0.75 to 2.5 hours to provide a composite with a density greater than about 99% of the theoretical density of the ceramic material.
Claim 9
Independent Claim
115 words
A method for preparing a ceramic composite having increased toughness and resistance to fracture, comprising the steps of forming a homogeneous mixture of particulate ceramic material with about 5 to 60 vol. % of silicon carbide whiskers having a monocrystalline structure and in a size range of about 0.6 μm diameter and a length of about 10 to 80 μm, and hot pressing the mixture at a pressure in the range of about 28 to 70 MPa and temperature in the range of about 1600° to 1900° C. for a duration of 0.75 to 2.5 hours to provide a composite with a density greater than about 99% of the theoretical density of the ceramic material.
Claim 10
Dependent Claim
26 words
A method for preparing a ceramic composite as claimed in claim 7, wherein the ceramic material is of a particle size less than about 44 m.
Claim 11
Dependent Claim
39 words
A method for preparing a ceramic composite as claimed in claim 8, wherein the ceramic material is selected from the group consisting of Al 2 O 3 , 3Al 2 O 3 .2SiO 2 , and B 4 C.
Claim 12
Dependent Claim
40 words
A method for preparing a ceramic composite as claimed in claim 9, wherein the silicon carbide whiskers are preferentially aligned along an axis of the composite by unidirectionally hot pressing the mixture along an axis perpendicular to the first-mentioned axis.
Claim 13
Dependent Claim
29 words
The method for preparing a ceramic composite as claimed in claim 9 wherein the silicon carbide whiskers are omnidirectionally aligned within the composite by isostatically hot pressing the mixture.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-23 | 1989-03-25 | 1989-09-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-23 | 1993-03-25 | 1993-09-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-23 | 1997-03-25 | 1997-09-24 | $7700.00 | Window Closed / Lapsed |