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Method for maintaining the resistance of a high resistive polysilicon layer for a semiconductor device

Assignee: SK Hynix Inc
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Filing: 1991-11-26
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Granted: 1993-05-18
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Expires: 2011-11-26
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Abstract

Abstract A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof and comprises sequentially depositing a silicon oxide layer and a silicon nitride layer, on a high resistance value polysilicon layer of a partially completed semiconductor structure to form a passivation layer thereover. The passivation layer including the silicon oxide layer and the silicon nitride layer is annealed with oxygen plasma in a chamber. The annealed passivation layer is then heated in the presence of a conditioning gas in the chamber to thereby maintaining the resistance of the high resistance value polysilicon layer.

Inventors

  • 👤 Hyung C. Hah
  • 👤 Jung T. Kim
  • 👤 Yong K. Baek
  • 👤 Hee K. Cheon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 10:17
CPC Classifications
H; H10; H10P; H10P95/00; H10P95/90; H10D; H10D1/00; H10D1/40; H10D1/47; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/6336; H10P32/00; H10P32/30; H10P32/302; H10B; H10B10/00; H10B10/15; Y; Y10; Y10S; Y10S148/00; Y10S148/003; Y10S148/118; Y10S148/122; Y10S438/00; Y10S438/958

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 144 words
A method for preventing the resistance of a high resistive polysilicon layer from decreasing due to the deposition of a passivation layer on the partially completed semiconductor structure which includes the high resistive polysilicon layer in a semiconductor device, the method comprising: depositing a passivation layer including a silicon oxide layer and a silicon nitride layer on a high resistive polysilicon layer of the partially completed semiconductor structure, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the passivation layer with oxygen plasma in a chamber; and heating the annealed passivation layer in the presence of nitrogen conditioning gas in the chamber such that it prevents the resistance of the high resistive polysilicon layer from being decreased by out-diffusing a plurality of the ions trapped into the boundary of the grains of the high resistive polysilicon during the deposition process of the passivation layer.
Claim 2
Independent Claim 144 words
A method for preventing the resistance of a high resistive polysilicon layer from decreasing due to the deposition of a passivation layer on the partially completed semiconductor structure which includes the high resistive polysilicon layer in a semiconductor device, the method comprising: depositing a passivation layer including a silicon oxide layer and a silicon nitride layer on a high resistive polysilicon layer of the partially completed semiconductor structure, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the passivation layer with oxygen plasma in a chamber; and heating the annealed passivation layer in the presence of nitrogen conditioning gas in the chamber such that it prevents the resistance of the high resistive polysilicon layer from being decreased by out-diffusing a plurality of the ions trapped into the boundary of the grains of the high resistive polysilicon during the deposition process of the passivation layer.
Claim 3
Dependent Claim 33 words
The method of claim 1 wherein the passivation layer is annealed at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the presence of oxygen plasma.
Claim 4
Dependent Claim 39 words
The method of claim 2 further including the simultaneously application of a radio frequency of 13.56 MHZ into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce the oxygen plasma.
Claim 5
Dependent Claim 36 words
The method of claim 1 wherein the annealed passivation layer is heated in the presence of the nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber.
Claim 6
Independent Claim 197 words
A method for preventing the resistance of a high resistive polysilicon layer from decreasing due to the deposition of the passivation layer on the partially completed semiconductor structure including the high resistive polysilicon layer in a semiconductor device, the method comprising: depositing a silicon oxide layer on a high resistive polysilicon layer of the partially completed semiconductor structure, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the silicon oxide layer with oxygen plasma in a chamber; heating the annealed silicon oxide layer in the presence of nitrogen conditioning gas in the chamber; depositing a silicon nitride layer on the resulting silicon oxide layer, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the silicon nitride layer with oxygen plasma in a chamber; and heating the annealed silicon nitride layer in the presence of nitrogen conditioning gas in the chamber, to thereby form a passivation layer including the silicon oxide layer and silicon nitride layer, such that it prevents the resistance of the high resistive polysilicon layer from being decreased by out-diffusing a plurality of the ions trapped into the boundary of the grains of the high resistive polysilicon during the deposition process of the passivation layer.
Claim 7
Independent Claim 197 words
A method for preventing the resistance of a high resistive polysilicon layer from decreasing due to the deposition of the passivation layer on the partially completed semiconductor structure including the high resistive polysilicon layer in a semiconductor device, the method comprising: depositing a silicon oxide layer on a high resistive polysilicon layer of the partially completed semiconductor structure, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the silicon oxide layer with oxygen plasma in a chamber; heating the annealed silicon oxide layer in the presence of nitrogen conditioning gas in the chamber; depositing a silicon nitride layer on the resulting silicon oxide layer, by utilizing a plasma-enhanced chemical vapor deposition process; annealing the silicon nitride layer with oxygen plasma in a chamber; and heating the annealed silicon nitride layer in the presence of nitrogen conditioning gas in the chamber, to thereby form a passivation layer including the silicon oxide layer and silicon nitride layer, such that it prevents the resistance of the high resistive polysilicon layer from being decreased by out-diffusing a plurality of the ions trapped into the boundary of the grains of the high resistive polysilicon during the deposition process of the passivation layer.
Claim 8
Dependent Claim 33 words
The method of claim 5 wherein the passivation layer is annealed at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the presence of oxygen plasma.
Claim 9
Dependent Claim 39 words
The method of claim 6 further including the simultaneous application of a radio frequency of 13.56 MHZ into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce the oxygen plasma.
Claim 10
Dependent Claim 36 words
The method of claim 5 wherein the annealed passivation layer is heated in the presence of the nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber.
Claim 11
Independent Claim 107 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: sequentially depositing a silicon oxide layer and a silicon nitride layer, on the high resistance value polysilicon layer of a partially completed semiconductor structure to form a passivation layer thereon; annealing the passivation layer including the silicon oxide layer and the silicon nitride layer with oxygen plasma in a chamber; and heating the annealed passivation layer in the presence of a conditioning gas in the chamber thereby maintaining the resistance of the high resistance value polysilicon layer.
Claim 12
Independent Claim 107 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: sequentially depositing a silicon oxide layer and a silicon nitride layer, on the high resistance value polysilicon layer of a partially completed semiconductor structure to form a passivation layer thereon; annealing the passivation layer including the silicon oxide layer and the silicon nitride layer with oxygen plasma in a chamber; and heating the annealed passivation layer in the presence of a conditioning gas in the chamber thereby maintaining the resistance of the high resistance value polysilicon layer.
Claim 13
Dependent Claim 24 words
The method of claim 9 wherein the silicon oxide layer and the silicon nitride layer are deposited utilizing a plasma-enhanced chemical vapor deposition process.
Claim 14
Dependent Claim 33 words
The method of claim 9 wherein the passivation layer is annealed at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the presence of oxygen plasma.
Claim 15
Dependent Claim 33 words
The method of claim 11 further including applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma.
Claim 16
Dependent Claim 36 words
The method of claim 9 wherein the annealed passivation layer is heated in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber.
Claim 17
Independent Claim 162 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer and a silicon nitride layer, on the high resistance polysilicon layer by a plasma-enhanced chemical vapor deposition process to form a passivation layer on the semiconductor structure; annealing the passivation layer including the silicon oxide layer and the silicon nitride layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma; and heating the annealed passivation layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber thereby maintaining the resistance of the high resistant polysilicon layer.
Claim 18
Independent Claim 162 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer and a silicon nitride layer, on the high resistance polysilicon layer by a plasma-enhanced chemical vapor deposition process to form a passivation layer on the semiconductor structure; annealing the passivation layer including the silicon oxide layer and the silicon nitride layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma; and heating the annealed passivation layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber thereby maintaining the resistance of the high resistant polysilicon layer.
Claim 19
Independent Claim 116 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer on the high resistant polysilicon layer; annealing the silicon oxide layer with oxygen plasma; heat treating the annealed silicon oxide layer with nitrogen conditioning gas in a chamber; depositing a silicon nitride layer on the annealed silicon oxide layer; annealing the silicon nitride layer by treatment with oxygen plasma; and heat treating the annealed silicon nitride layer with nitrogen conditioning gas in the chamber to form a resulting passivation layer thereby maintaining the high resistance of the high resistant polysilicon layer.
Claim 20
Independent Claim 116 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer on the high resistant polysilicon layer; annealing the silicon oxide layer with oxygen plasma; heat treating the annealed silicon oxide layer with nitrogen conditioning gas in a chamber; depositing a silicon nitride layer on the annealed silicon oxide layer; annealing the silicon nitride layer by treatment with oxygen plasma; and heat treating the annealed silicon nitride layer with nitrogen conditioning gas in the chamber to form a resulting passivation layer thereby maintaining the high resistance of the high resistant polysilicon layer.
Claim 21
Dependent Claim 25 words
The method of claim 15 wherein the silicon oxide layer and the silicon nitride layer are each deposited utilizing a plasma-enhanced chemical vapor deposition process.
Claim 22
Dependent Claim 39 words
The method of claim 15 wherein the silicon oxide layer and the silicon nitride layer are annealed at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the presence of oxygen plasma.
Claim 23
Dependent Claim 42 words
The method of claim 17 wherein the oxygen plasma is formed in the chamber and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma.
Claim 24
Dependent Claim 44 words
The method of claim 15 wherein the annealed silicon oxide layer and the annealed silicon nitride layer are each heated in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber.
Claim 25
Independent Claim 250 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer on the high resistant polysilicon layer to a predetermined thickness by a plasma-enhanced chemical vapor deposition process; annealing the silicon oxide layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma: heating the annealed silicon oxide layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber; depositing a silicon nitride layer on the annealed silicon oxide layer by a plasma-enhanced chemical vapor deposition process; annealing the silicon nitride layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in the chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma thereby forming a resulting passivation layer; and heating the annealed silicon nitride layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber thereby maintaining the high resistance of the high resistant polysilicon layer.
Claim 26
Independent Claim 250 words
A method for depositing a passivation layer on a semiconductor structure having a high resistance value polysilicon layer formed thereon while maintaining the high resistance value thereof, the method comprising: depositing a silicon oxide layer on the high resistant polysilicon layer to a predetermined thickness by a plasma-enhanced chemical vapor deposition process; annealing the silicon oxide layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in a chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma: heating the annealed silicon oxide layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber; depositing a silicon nitride layer on the annealed silicon oxide layer by a plasma-enhanced chemical vapor deposition process; annealing the silicon nitride layer at a temperature of 300-400 degrees Celsius for a period of 1-2 minutes in the chamber in the and simultaneously applying 13.56 MHZ radio frequency into the chamber and supplying 500-1,000 SCCM of oxygen and 300-500 Watts of power to the chamber to produce oxygen plasma thereby forming a resulting passivation layer; and heating the annealed silicon nitride layer in the presence of a nitrogen conditioning gas at a temperature of 350-450 degrees Celsius for a period of 30-60 minutes in the chamber thereby maintaining the high resistance of the high resistant polysilicon layer.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-17 1996-11-16 1997-05-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-17 2000-11-16 2001-05-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-17 2004-11-16 2005-05-18 $7700.00 Window Closed / Lapsed

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