US5120508A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Apparatus for removing oxides of nitrogen and sulfur from combustion gases
Assignee: Noell Inc
•
Filing: 1988-04-07
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Granted: 1992-06-09
•
Expires: 2008-04-07
Abstract
Abstract An apparatus is provided in accordance with practice of this invention for lowering the molar ratio of NO to NO 2 in flue gas by converting a portion of flue gas nitric oxide (NO) to nitrogen dioxide (NO 2 ), for removing the associated oxides of sulfur (SO x ) and nitrogen (NO x ) from the flue gas prior to discharge of the flue gas into the atmosphere.
Inventors
- 👤 Dale G. Jones
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:55
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; B01D53/54; B01D53/56; Y; Y02; Y02A; Y02A50/00; Y02A50/20
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
176 words
An apparatus for converting NO to NO 2 , comprising: a) means for providing a flow path for gas, wherein said gas flow path means includes a gas contacting section; b) means for introducing a gas stream containing NO and NO 2 at a first NO/NO 2 molar ratio into the gas contacting section; and c) means for mixing together a peroxyl initiator and an oxygen-containing gas and for introducing the mixture as an injection fluid into the gas contacting section for contacting the NO containing gas stream, the fluid mixing and introduction means comprising a preheater for the injection fluid capable of heating the injection fluid to a temperature in the range of 400° F. and 800° F., the peroxyl initiator and oxygen being present in the gas contacting section to convert NO to NO 2 to thereby provide a gas stream exiting the contacting section that contains NO and NO 2 at a second NO/NO 2 molar ratio wherein the second NO/NO 2 molar ratio is less than the first NO/NO 2 molar ratio.
Claim 2
Independent Claim
176 words
An apparatus for converting NO to NO 2 , comprising: a) means for providing a flow path for gas, wherein said gas flow path means includes a gas contacting section; b) means for introducing a gas stream containing NO and NO 2 at a first NO/NO 2 molar ratio into the gas contacting section; and c) means for mixing together a peroxyl initiator and an oxygen-containing gas and for introducing the mixture as an injection fluid into the gas contacting section for contacting the NO containing gas stream, the fluid mixing and introduction means comprising a preheater for the injection fluid capable of heating the injection fluid to a temperature in the range of 400° F. and 800° F., the peroxyl initiator and oxygen being present in the gas contacting section to convert NO to NO 2 to thereby provide a gas stream exiting the contacting section that contains NO and NO 2 at a second NO/NO 2 molar ratio wherein the second NO/NO 2 molar ratio is less than the first NO/NO 2 molar ratio.
Claim 3
Dependent Claim
50 words
The apparatus of claim 1 wherein the preheater for the injection fluid, preheats injection fluid which comprises propane, to a temperature in the range of ambient temperature and 800° F. and oxygen in the range of 5% and 20% by volume based on the total volume of the injection fluid.
Claim 4
Dependent Claim
35 words
The apparatus of claim 1 wherein the injection fluid mixing and introduction means comprises an array of distributor tubes with each distributor tube having a plurality of holes therein through which the injection fluid passes.
Claim 5
Dependent Claim
48 words
The apparatus of claim 3 wherein the distributor tube holes are aligned so that the direction of flow of the injection fluid from the distributor tubes is at an angle of from 10° to 20° from the plane of the array in the direction of flue gas flow.
Claim 6
Independent Claim
285 words
An apparatus for removing nitrogen oxides and sulfur oxides from a gas stream, the apparatus comprising: a) an NO to NO 2 conversion section comprising: i) a gas duct having an inlet and an outlet and a gas contacting section therebetween; ii) means for introducing a first gas stream containing NO, NO 2 and sulfur oxides into the gas duct inlet, said NO and NO 2 present in a first NO/NO 2 molar ratio; iii) means for mixing together a peroxyl initiator and oxygen and for introducing the mixture as an injection fluid into the gas duct contacting section for contacting the NO, NO 2 and sulfur oxides containing first gas stream, the fluid mixing and introduction means comprising a preheater for the injection fluid capable of heating the injection fluid to a temperature in the range of 400° F. and 800° F., the peroxyl initiator and oxygen being present in the gas duct to convert NO to NO 2 to thereby provide a second gas stream exiting the contacting section, the second gas stream containing NO and NO 2 at a second NO/NO 2 molar ratio wherein the second molar ratio is less than the first molar ratio; and b) an absorption section comprising: i) means for receiving the second gas stream as it exits the NO to NO 2 conversion section; ii) means for introducing a dry particulate sorbent into the second gas stream for sorbing oxides of sulfur and nitrogen therefrom to thereby provide a reacted sorbent; iii) means for removing reacted sorbent and any unreacted sorbent from the second gas stream to provide a clean waste gas stream; and iv) means for discharging the clean waste gas stream into the atmosphere.
Claim 7
Independent Claim
285 words
An apparatus for removing nitrogen oxides and sulfur oxides from a gas stream, the apparatus comprising: a) an NO to NO 2 conversion section comprising: i) a gas duct having an inlet and an outlet and a gas contacting section therebetween; ii) means for introducing a first gas stream containing NO, NO 2 and sulfur oxides into the gas duct inlet, said NO and NO 2 present in a first NO/NO 2 molar ratio; iii) means for mixing together a peroxyl initiator and oxygen and for introducing the mixture as an injection fluid into the gas duct contacting section for contacting the NO, NO 2 and sulfur oxides containing first gas stream, the fluid mixing and introduction means comprising a preheater for the injection fluid capable of heating the injection fluid to a temperature in the range of 400° F. and 800° F., the peroxyl initiator and oxygen being present in the gas duct to convert NO to NO 2 to thereby provide a second gas stream exiting the contacting section, the second gas stream containing NO and NO 2 at a second NO/NO 2 molar ratio wherein the second molar ratio is less than the first molar ratio; and b) an absorption section comprising: i) means for receiving the second gas stream as it exits the NO to NO 2 conversion section; ii) means for introducing a dry particulate sorbent into the second gas stream for sorbing oxides of sulfur and nitrogen therefrom to thereby provide a reacted sorbent; iii) means for removing reacted sorbent and any unreacted sorbent from the second gas stream to provide a clean waste gas stream; and iv) means for discharging the clean waste gas stream into the atmosphere.
Claim 8
Dependent Claim
51 words
The apparatus of claim 5 wherein the preheater for the injection fluid preheats the injection fluid which comprises propane, to a temperature in the range of ambient temperature and 800° F. and oxygen in the range of 5% and 20% by volume based on the total volume of the injection fluid.
Claim 9
Dependent Claim
29 words
The apparatus of claim 5 wherein the preheater comprises an array of distributor tubes with each distributor tube having a plurality of holes therein through the injection fluid passes.
Claim 10
Dependent Claim
48 words
The apparatus of claim 7 wherein the distributor tube holes are aligned so that the direction of flow of the injection fluid from the distributor tubes is at an angle of from 10° to 20° from the plane of the array in the direction of fluid gas flow.
Claim 11
Dependent Claim
38 words
The apparatus of claim 5 wherein the reacted and unreacted sorbent removal means comprises a baghouse and the particulate sorbent introduction means comprises a plurality of tubes extending into the flue gas flow path upstream from the baghouse.
Claim 12
Dependent Claim
58 words
The apparatus of claim 5 wherein the absorption section comprises a baghouse and the particulate sorbent introduction means comprises a spray dryer located in flow connection with and upstream from the baghouse, said particulate sorbent being introduced into the flue gas stream in the spray dryer, the flue gas and entrained particulate sorbent being discharged into the baghouse.
Claim 13
Dependent Claim
49 words
The apparatus of claim 5 wherein the reacted and unreacted sorbent removal means comprises a baghouse and the absorption section additionally comprises means in flow connection with and downstream from the baghouse for contacting the gas stream exiting the baghouse with a metal oxide sorbent for NO x .
Claim 14
Dependent Claim
55 words
The apparatus of claim 5 wherein the reacted and unreacted sorbent removal means comprises a baghouse comprising filtration surfaces and wherein the apparatus additionally comprises means for recycling sorbent removed from the second gas stream back into the second gas stream at any point in flow connection with and upstream from the baghouse filtration surfaces.
Claim 15
Dependent Claim
28 words
The apparatus of claim 12 wherein the baghouse comprises an inlet duct comprising a plurality of nozzles designed to introduce the gas stream into the baghouse filtration surfaces.
Claim 16
Independent Claim
165 words
An apparatus for converting NO to NO 2 comprising: a) means for providing a flow path for gas, said means including a gas contacting section; b) means for flowing a gas stream containing NO and NO 2 at a first NO/NO 2 molar ratio through the contacting section; c) heating means comprising a gas injection grid and distributor tubes for introducing an injection fluid which comprises a peroxyl initiator mixed together with an oxygen-containing gas into the contacting section in a sufficient quantity and at a sufficient velocity to thereby provide that such injection fluid is not heated to more than 800° F. prior to introduction of the injection fluid into the contacting section, the NO/NO 2 containing gas stream contacting the injection fluid as said NO/NO 2 containing gas stream flows through the contacting section, wherein the injection fluid contains a sufficient quantity of peroxyl initiator and oxygen to provide that NO, upon contact with the injection fluid, is converted to NO 2 .
Claim 17
Independent Claim
165 words
An apparatus for converting NO to NO 2 comprising: a) means for providing a flow path for gas, said means including a gas contacting section; b) means for flowing a gas stream containing NO and NO 2 at a first NO/NO 2 molar ratio through the contacting section; c) heating means comprising a gas injection grid and distributor tubes for introducing an injection fluid which comprises a peroxyl initiator mixed together with an oxygen-containing gas into the contacting section in a sufficient quantity and at a sufficient velocity to thereby provide that such injection fluid is not heated to more than 800° F. prior to introduction of the injection fluid into the contacting section, the NO/NO 2 containing gas stream contacting the injection fluid as said NO/NO 2 containing gas stream flows through the contacting section, wherein the injection fluid contains a sufficient quantity of peroxyl initiator and oxygen to provide that NO, upon contact with the injection fluid, is converted to NO 2 .
Claim 18
Dependent Claim
28 words
The apparatus of claim 14 wherein the gas injection grid and distributor tubes comprise a plurality of gas nozzles extending in an array across the gas contacting section.
Claim 19
Dependent Claim
33 words
The apparatus of claim 14 wherein the injection fluid mixing and introduction means comprises a preheater for the injection fluid capable of heating said injection fluid to between ambient temperature and 800° F.
Claim 20
Dependent Claim
78 words
The apparatus of claim 14 wherein the gas flow means is capable of providing the NO/NO 2 containing gas stream with a velocity in the range of from 30 feet per second to 70 feet per second while the injection fluid mixing and introduction means includes a plurality of nozzles wherein each such nozzle is capable of providing the injection fluid with a velocity of at least 10 times the velocity of the NO/NO 2 containing gas stream.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-06-09 | 1995-12-09 | 1996-06-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-06-09 | 1999-12-09 | 2000-06-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-06-09 | 2003-12-09 | 2004-06-09 | $7700.00 | Window Closed / Lapsed |