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US4018868A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal crushing of alkali compounds in the removal of sulfur dioxides from a flue gas

Assignee: ExxonMobil Oil Corp
•
Filing: 1975-03-19
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Granted: 1977-04-19
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Expires: 1995-03-19
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Abstract

Abstract Alkali metal and alkaline earth metal carbonate compounds (in a variety of forms), including sodium ores of nahcolite and calcium ores of limestone, can be thermally comminuted or crushed. Size reduction is accomplished by a thermal treatment process called thermal crushing. The solids are subjected to a high temperature environment which causes a rapid temperature rise within the solid particles. This rapid temperature rise apparently results in a rapid generation of gases within the particle that exceeds the rate at which the gases can escape, thus resulting in a pressure buildup inside the solid particles. This causes the particles to explode or disintegrate into many smaller particles or powder. The resulting generation of small particles or powder by thermal crushing of thermally crushable carbonate compounds improves their application for removing reactive gaseous impurities, such as sulfur dioxide, NO x , etc., from a flue gas. To remove such gaseous impurities, the small particles or powder produced by thermal crushing are introduced into a flue gas when the flue gas is at a temperature up to 1,500° F.

Inventors

  • 👤 John H. Knight

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:53
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 143 words
A method of reducing the sulfur dioxide content of a flue gas which comprises: a. introducing particulate nahcolite into a first zone heated to a temperature of from about 2,000° to about 4,000° F to produce thermally crushed nahcolite of a predominant particle size within the range of from about 0.1 to about 100 microns and a mean particle size of 1-20 microns; b. transporting said thermally crushed nahcolite to a second zone containing a flue gas having sulfur dioxide impurities, said flue gas being at a temperature up to 1,500° F; c. allowing said thermally crushed nahcolite and flue gas to remain in contact for a period of time sufficient to allow said thermally crushed nahcolite to combine with the sulfur dioxide impurities in said flue gas; and d. removing from said flue gas said thermally crushed nahcolite containing combined sulfur dioxide.
Claim 2
Independent Claim 143 words
A method of reducing the sulfur dioxide content of a flue gas which comprises: a. introducing particulate nahcolite into a first zone heated to a temperature of from about 2,000° to about 4,000° F to produce thermally crushed nahcolite of a predominant particle size within the range of from about 0.1 to about 100 microns and a mean particle size of 1-20 microns; b. transporting said thermally crushed nahcolite to a second zone containing a flue gas having sulfur dioxide impurities, said flue gas being at a temperature up to 1,500° F; c. allowing said thermally crushed nahcolite and flue gas to remain in contact for a period of time sufficient to allow said thermally crushed nahcolite to combine with the sulfur dioxide impurities in said flue gas; and d. removing from said flue gas said thermally crushed nahcolite containing combined sulfur dioxide.
Claim 3
Dependent Claim 24 words
The method of claim 1, wherein said flue gas and thermally crushed nahcolite are contacted for a period of up to about 10 seconds.
Claim 4
Dependent Claim 18 words
The method of claim 2, wherein the period of contact is from about 1 to about 6 seconds.
Claim 5
Dependent Claim 42 words
The method of claim 1, wherein the amount of thermally crushed nahcolite contacted with said flue gas is sufficient to provide a stoichiometric ratio of nahcolite to free and combined sulfur dioxide within the range of from about 0.9 to about 3.0.
Claim 6
Dependent Claim 22 words
The method of claim 1, wherein said thermally crushed nahcolite containing combined sulfur dioxide agglomerates prior to removal from the flue gas.
Claim 7
Dependent Claim 50 words
The method of claim 1, wherein said flue gas is produced by a boiler, furnace, or incinerator and the thermally crushed nahcolite is contacted with said flue gas in a boiler, furnace, or incinerator exit duct leading from said boiler, furnace, or incinerator to a stack open to the atmosphere.
Claim 8
Dependent Claim 40 words
The method of claim 6, wherein a particle extractor is located in said duct between a zone of contact between said thermally crushed nahcolite and flue gas and said stack to remove said thermally crushed nahcolite containing combined sulfur dioxide.
Claim 9
Dependent Claim 30 words
The method of claim 7, wherein the nahcolite is thermally crushed in a thermal crushing zone outside said duct and transported to said duct for contact with said flue gas.
Claim 10
Dependent Claim 20 words
The method of claim 7, wherein said nahcolite is thermally crushed in a thermal crushing zone located in said duct.

References Cited (Backward Citations)

US734240A Cited
US1679857A Cited
US2718453A Cited
US3520649A Cited
US3505008A Cited
US3880629A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-18 1980-10-18 1981-04-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-18 1984-10-18 1985-04-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-18 1988-10-18 1989-04-19 $7700.00 Window Closed / Lapsed

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