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US5102965A Expired / Lapsed US ⏱️ 0.0 years remaining

Base resistant fluoroelastomers with improved processibility and curability

Assignee: EIDP Inc
•
Filing: 1991-07-25
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Granted: 1992-04-07
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Expires: 2011-07-25
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Abstract

Abstract Base-resistant peroxide-curable fluoroelastomers with improved processibility comprising a polymeric chain having tetrafluroethylene as one comonomer copolymerized with monomer units selected from the group (a) propylene, (b) propylene and vinylidene fluoride and (c) a C 2-3 hydrocarbon olefin and one or more perfluoro(alkyl vinyl ethers); said polymer chains having terminal iodo-groups.

Inventors

  • 👤 Dana P. Carlson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:53
CPC Classifications
C; C08; C08F; C08F214/00; C08F214/18; C08F214/26; C08F214/265; C08F210/00; C08F210/04; C08F210/06; C08K; C08K7/00; C08K7/02; C08K7/04; C08K7/14

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 97 words
A process for preparing a base-resistant peroxide-curable fluoroelastomer with improved processibility comprising copolymerizing (a) tetrafluoroethylene with propylene, (b) tetrafluoroethylene, propylene, and vinylidene fluoride or (c) tetrafluoroethylene ethylene and one or more perfluoro(alkyl vinyl ethers), said copolymerization being carried out in the presence of a compound of the formula RI 2 , wherein R is a saturated perfluorocarbon or chloroperfluorocarbon alkylene group of 3 or more carbon atoms, with at least 3 carbon atoms separating the iodo groups, said polymerization further being carried out at monomer pressures above about 1.7 MPa and at temperatures of about 25°-100° C.
Claim 2
Dependent Claim 97 words
A process for preparing a base-resistant peroxide-curable fluoroelastomer with improved processibility comprising copolymerizing (a) tetrafluoroethylene with propylene, (b) tetrafluoroethylene, propylene, and vinylidene fluoride or (c) tetrafluoroethylene ethylene and one or more perfluoro(alkyl vinyl ethers), said copolymerization being carried out in the presence of a compound of the formula RI 2 , wherein R is a saturated perfluorocarbon or chloroperfluorocarbon alkylene group of 3 or more carbon atoms, with at least 3 carbon atoms separating the iodo groups, said polymerization further being carried out at monomer pressures above about 1.7 MPa and at temperatures of about 25°-100° C.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein the fluoroelastomer comprises copolymerized units of tetrafluoroethylene and propylene in the mole ratios 45-70/55-30.
Claim 4
Dependent Claim 20 words
The process of claim 1 wherein the fluoroelastomer comprises copolymerized units of tetrafluoroethylene and propylene in the mole ratios 45-60/55-40.
Claim 5
Dependent Claim 23 words
The process of claim 1 wherein the fluoroelastomer comprises copolymerized units of tetrafluoroethylene, propylene and vinylidene fluoride in the mole ratios 5-65/5-40/5-40, respectively.
Claim 6
Dependent Claim 23 words
The process of claim 1 wherein the fluoroelastomer comprises copolymerized units of tetrafluoroethylene, propylene and vinylidene fluoride in the mole ratios 30-60/20-35/10-35, respectively.
Claim 7
Dependent Claim 48 words
The process of claim 1 wherein the fluoroelastomer comprises copolymerized units of tetrafluoroethylene, ethylene and one or more perfluoro(alkyl vinyl ethers) having the formula CF 2 =CFO(CF 2 ) n CF 3 , where n is 0-5 or perfluoro(alkoxyalkyl vinyl ethers), present in mole ratios of 32-60/10-40/20-40, respectively.
Claim 8
Dependent Claim 14 words
The process of claim 6 wherein the perfluor(alkyl vinyl ether) is perfluoro(methyl vinyl ether).

References Cited (Backward Citations)

US3467635A Cited
US3859259A Cited
US4035565A Cited
US4158678A Cited
US4148982A Cited
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US4694045A Cited
US4948853A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-04-07 1995-10-07 1996-04-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-04-07 1999-10-07 2000-04-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-04-07 2003-10-07 2004-04-07 $7700.00 Window Closed / Lapsed

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