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Photoresist compositions of controlled dissolution rate in alkaline developers

Assignee: International Business Machines Corp
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Filing: 1985-12-17
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Granted: 1990-12-25
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Expires: 2005-12-17
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Abstract

Abstract A photoresist composition is disclosed which is a mixture of a photoactive compound and an alkali soluble resin binder comprises of an unsaturated dicarboxylic acid esterified polymeric material, such as a phenolic resin containing a plurality of acid esterifiable groups esterified with an unsaturated dicarboxylic acid anhydride having the formula ##STR1## wherein R 1 and R 2 are independently selected from hydrogen and alkyl groups containing 1 to 3 carbon atoms, R 3 and R 4 are alkylene groups containing 1 to 3 carbon atoms and x and y are either 0 or 1.

Inventors

  • 👤 Kaolin N. Chiong
  • 👤 Bea-Jane L. Yang
  • 👤 Jer-Ming Yang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:02
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/023; G03F7/0233; G03F7/008; G03F7/012; G03F7/0125

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 50 words
A photoresist composition comprised of an admixture of a photoactive compound and an alkali soluble resin binder which is comprised of an unsaturated dicarboxylic acid esterified polymeric material, wherein the photoactive compound is present in a concentration from about 2 to about 25 percent by weight of the resin binder.
Claim 2
Dependent Claim 50 words
A photoresist composition comprised of an admixture of a photoactive compound and an alkali soluble resin binder which is comprised of an unsaturated dicarboxylic acid esterified polymeric material, wherein the photoactive compound is present in a concentration from about 2 to about 25 percent by weight of the resin binder.
Claim 3
Dependent Claim 65 words
The photoresist composition of claim 1 wherein the polymeric material is esterified with an unsaturated dicarboxylic acid anhydride having the formula ##STR8## wherein R 1 and R 2 are independently selected from hydrogen and alkyl groups containing 1 to 3 carbon atoms, R 3 and R 4 are alkylene groups containing 1 to 3 carbon atoms and x and y are either 0 to 1.
Claim 4
Dependent Claim 30 words
The photoresist composition of claim 1 wherein the polymeric material is a hydroxy group containing resin selected from the group consisting of a novolak-type cresol formaldehyde resins and (poly p-hydroxystyrene).
Claim 5
Dependent Claim 13 words
The photoresist composition of claim 1 wherein the composition has positive working functionality.
Claim 6
Dependent Claim 20 words
The photoresist composition of claim 4 wherein the photoactive compound is a 4- or 5-substituted naphthoquinone (1,2) diazide-sulfonic acid ester.
Claim 7
Dependent Claim 32 words
The photoresist composition of claim 4 wherein the diazonaphthoquinone sulfonic acid ester is selected from the group consisting of 5-substituted napthoquinone-1,2-diazide sulfonic acid esters of 2,3,4-trihydroxy benzophenone and 4,8-bis(hydroxymethyl)tricyclo[5.2.1.0 2 ,6 ]decane.
Claim 8
Dependent Claim 13 words
The photoresist composition of claim 1 wherein the composition has negative working functionality.
Claim 9
Dependent Claim 15 words
The photoresist composition of claim 6 wherein the photo active compound is an aryl azide.

References Cited (Backward Citations)

US3802885A Cited
US3869292A Cited
US4108666A Cited
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US4115128A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-12-24 1994-06-25 1994-12-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-12-24 1998-06-25 1998-12-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-12-24 2002-06-25 2002-12-25 $7700.00 Window Closed / Lapsed

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