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US4977218A Expired / Lapsed US ⏱️ 0.0 years remaining

Carboxylated rubber particles as tougheners for fiber reinforced composites

Assignee: BP Corp North America Inc
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Filing: 1988-09-26
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Granted: 1990-12-11
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Expires: 2008-09-26
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Abstract

Abstract Preformed carboxylated rubber particles are effective for toughening fiber reinforced composite structures based on thermoset resins such as epoxy resin formulations. The composites are effectively toughened by adding the carboxylated rubber particles to the matrix resin prior to curing the composite.

Inventors

  • 👤 Hugh C. Gardner
  • 👤 Richard H. Newman-Evans

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:04
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/12; C08L; C08L13/00; C08L63/00; C08J2313/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 56 words
Particles having a smallest dimension in the range of from 1 to about 75 microns comprising a cross-linked carboxylated rubber selected from the group consisting of carboxylated diene rubbers and carboxylated acrylic rubbers, said carboxylated rubber having from 0.1 to 5 wt% carboxyl functionality and a Tg above 15° C., said particles being formed by spray-drying.
Claim 2
Dependent Claim 56 words
Particles having a smallest dimension in the range of from 1 to about 75 microns comprising a cross-linked carboxylated rubber selected from the group consisting of carboxylated diene rubbers and carboxylated acrylic rubbers, said carboxylated rubber having from 0.1 to 5 wt% carboxyl functionality and a Tg above 15° C., said particles being formed by spray-drying.
Claim 3
Dependent Claim 30 words
The rubber particles of claim 1 wherein said particles are formed of a carboxylated rubber selected from the group consisting of carboxylated styrene-butadiene-acrylonitrile terpolymers, carboxylated acrylic rubbers and mixtures thereof.
Claim 4
Dependent Claim 19 words
The particles of claim 1 wherein said carboxylated rubber has from about 0.5 to about 3 wt% carboxyl functionality.
Claim 5
Dependent Claim 21 words
The particles of claim 1 wherein said carboxylated rubber is a carboxylated styrene-butadiene-acrylonitrile terpolymer having a Tg of about 26° C.
Claim 6
Dependent Claim 20 words
The particles of claim 1 wherein saidcarboxylated rubber is a carboxylated acrylic rubber having a Tg of about 20° C.
Claim 7
Dependent Claim 63 words
Particles having a smallest dimension in the range of from 1 to about 75 microns comprising a carboxylated rubber selected from the group consisting of carboxylated styrene-butadiene-acrylonitrile terpolymers having a Tg of about 26° C. and carboxylated acrylic rubbers having a Tg of about 20° C., said carboxylated rubber having from 0.1 to 5 wt% carboxyl functionality, said particles being formed by spray-drying.
Claim 8
Dependent Claim 63 words
Particles having a smallest dimension in the range of from 1 to about 75 microns comprising a carboxylated rubber selected from the group consisting of carboxylated styrene-butadiene-acrylonitrile terpolymers having a Tg of about 26° C. and carboxylated acrylic rubbers having a Tg of about 20° C., said carboxylated rubber having from 0.1 to 5 wt% carboxyl functionality, said particles being formed by spray-drying.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-12-10 1994-06-11 1994-12-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-12-10 1998-06-11 1998-12-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-12-10 2002-06-11 2002-12-11 $7700.00 Window Closed / Lapsed

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