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US4889788A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive composition, photosensitive copying material prepared from this composition with thermal hardening symmetric triazine alkyl(aryl)-ether

Assignee: Hoechst AG
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Filing: 1988-07-27
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Granted: 1989-12-26
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Expires: 2008-07-27
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Abstract

Abstract The invention describes a photosensitive composition, a copying material prepared from this composition, and a process for the production of negative relief copies, in which a photosensitive composition or a photosensitive material, respectively, is used, that comprises a support and a photosensitive composition coated onto the suppoort and comprising a photosensitive 1,2-quinonediazide or a photosensitive mixture, a binder that is soluble in aqueous-alkaline solutions and an s-triazine of the general formula I ##STR1## wherein R denotes akyl, allyl, alkoxy, alkoxycarbonyl, alkoxycarbonylakkenyl, each having from 1 to 4 carbon atoms in the alkyl or alkenyl group, aryloxy, halogen or a nitro group and n stands for 1 to 3. The material is exposed imagewise under a negative original, thereafter heated and, after cooling, exposed without an original or optionally under a positive original, then developed by means of an aqueous-alkaline developer and optionally baked. The copying material has a relatively large treatment range during the heating step and can be used for the production of negative and positive printing forms and in the photocomposing process.

Inventors

  • 👤 Paul Stahlhofen
  • 👤 Hans W. Frass

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:57
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/72; G03F; G03F7/00; G03F7/004; G03F7/0045; G03F7/022; G03F7/0226

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 153 words
A photosensitive composition comprising in admixture: a polymeric binder which is insoluble in water and soluble in aqueous-alkaline solutions present in an amount sufficient to form a uniform film; one of a photosensitive 1,2-quinonediazide and a photosensitive mixture comprising a compound which splits off acid upon exposure to light and a compound containing at least one acid-cleavable C-O-C group; and a symmetric triazone-alkyl(aryl)-ether as a substance which promotes thermal hardening comprising a compound of the general formula I ##STR4## wherein R denotes alkyl, allyl, alkoxy, alkoxycarbonyl, alkoxycarbonylalkenyl, each having from 1 to 4 carbon atoms in the alkyl or alkenyl group, aryloxy, halogen or a nitro group and n is 1 to 3. wherein the photosensitive compound or mixture is present in an amount sufficient to render exposed areas soluble in developer and the thermal-hardening substance is present in an amount sufficient to cause hardening of exposed areas under the action of heat.
Claim 2
Dependent Claim 153 words
A photosensitive composition comprising in admixture: a polymeric binder which is insoluble in water and soluble in aqueous-alkaline solutions present in an amount sufficient to form a uniform film; one of a photosensitive 1,2-quinonediazide and a photosensitive mixture comprising a compound which splits off acid upon exposure to light and a compound containing at least one acid-cleavable C-O-C group; and a symmetric triazone-alkyl(aryl)-ether as a substance which promotes thermal hardening comprising a compound of the general formula I ##STR4## wherein R denotes alkyl, allyl, alkoxy, alkoxycarbonyl, alkoxycarbonylalkenyl, each having from 1 to 4 carbon atoms in the alkyl or alkenyl group, aryloxy, halogen or a nitro group and n is 1 to 3. wherein the photosensitive compound or mixture is present in an amount sufficient to render exposed areas soluble in developer and the thermal-hardening substance is present in an amount sufficient to cause hardening of exposed areas under the action of heat.
Claim 3
Dependent Claim 37 words
A photosensitive composition as claimed in claim 1, wherein a compound of the general formula I is present, wherein R denotes methyl, isobutyl, ethoxy, ethoxycarbonyl, methoxycarbonylethenyl, bromine or a nitro group and n is 1 or 3.
Claim 4
Dependent Claim 38 words
A photosensitive composition as claimed in claim 1, which contains from about 0.5 to 30% by weight, based on the weight of the non-volatile constituents of the photosensitive composition, of a compound corresponding to the general formula I.
Claim 5
Dependent Claim 25 words
A photosensitive composition as claimed in claim 1, wherein the substance promoting thermal hardening is selected from the group consisting of 2,4,6-tris-(4-methylphenoxy)-s-triazine, 2,4,6-tris-(4-ethoxycarbonyl-phenoxy)-s-triazine and 2,4,6-tris-(2,4,6-tribromophenoxy)-s-triazine.
Claim 6
Dependent Claim 22 words
A photosensitive copying material comprising a support and a photosensitive layer on the support comprising a composition as claimed in claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-25 1993-06-26 1993-12-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-25 1997-06-26 1997-12-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-25 2001-06-26 2001-12-26 $7700.00 Window Closed / Lapsed

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