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US4869825A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the removal of organic contaminants from solids

Assignee: Individual
•
Filing: 1988-04-15
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Granted: 1989-09-26
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Expires: 2008-04-15
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Abstract

Abstract A process for the decontamination of materials such as soil, sediments and sludges contaminated with organic contaminants such as PCB's. The process comprises leaching a mixture of solids, water and contaminant in a three step process with solvents to obtain contaminated solvent and water and a mixture of decontaminated solids and solvent. The contaminant is stripped from the contaminated leaching solvent with a stripping solvent to concentrate the contaminants.

Inventors

  • 👤 Werner Steiner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 22:38
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/26; B; B01; B01D; B01D11/00; B01D11/02; B01D11/028; B09; B09C; B09C1/00; B09C1/02; Y; Y10; Y10S; Y10S210/00; Y10S210/902; Y10S210/908; Y10S210/909

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 228 words
A process for the decontamination of solid materials contaminated with hydrophobic organic compounds, the process comprising the steps of: a. providing a mixture of solids with water and contaminant including hydrophobic organic compounds; b. leaching the solids with solvents to obtain contaminated solvent and water and a mixture of decontaminated solids and solvent by: i. removing water from the mixture of step (a) with a hydrophilic solvent to obtain a first liquid steam of water, hydrophilic solvent and contaminant and a first solid steam of solids, hydrophilic solvent and contamininant; ii. removing contaminant form the first solid steam with a comixture of the hydrophilic solvent and a hydrophobic solvent to obtain a second liquid steam of the two solvents and contaminant and a second solid steam of the solids, the two solvents and the remaining contaminant, and iii. removing hydrophobic solvent and remaining contaminant from the second solid steam with hydrophilic solvent to obtain a third liquid steam of the two solvents and the remaining contaminant and a decontaminated third solid steam of solids and hydrophilic solvent; c. stripping contaminant from at least two of the liquid steams with the hydrophobic solvent to obtain an output of decontaminated hydrophilic solvent and an output of hydrophobic solvent and concentrated contaminant; and d. stripping the hydrophilic solvent from the third solid steam to obtain decontaminated solids and decontaminated hydrophilic solvent.
Claim 2
Dependent Claim 228 words
A process for the decontamination of solid materials contaminated with hydrophobic organic compounds, the process comprising the steps of: a. providing a mixture of solids with water and contaminant including hydrophobic organic compounds; b. leaching the solids with solvents to obtain contaminated solvent and water and a mixture of decontaminated solids and solvent by: i. removing water from the mixture of step (a) with a hydrophilic solvent to obtain a first liquid steam of water, hydrophilic solvent and contaminant and a first solid steam of solids, hydrophilic solvent and contamininant; ii. removing contaminant form the first solid steam with a comixture of the hydrophilic solvent and a hydrophobic solvent to obtain a second liquid steam of the two solvents and contaminant and a second solid steam of the solids, the two solvents and the remaining contaminant, and iii. removing hydrophobic solvent and remaining contaminant from the second solid steam with hydrophilic solvent to obtain a third liquid steam of the two solvents and the remaining contaminant and a decontaminated third solid steam of solids and hydrophilic solvent; c. stripping contaminant from at least two of the liquid steams with the hydrophobic solvent to obtain an output of decontaminated hydrophilic solvent and an output of hydrophobic solvent and concentrated contaminant; and d. stripping the hydrophilic solvent from the third solid steam to obtain decontaminated solids and decontaminated hydrophilic solvent.
Claim 3
Dependent Claim 17 words
The process according to claim 1, wherein step (d) comprises stripping contaminant from all three liquid streams.
Claim 4
Dependent Claim 27 words
The process according to claim 1, wherein the third liquid stream is used to supply the comixture of solvents to remove contaminant from the first solid stream.
Claim 5
Dependent Claim 25 words
The process according to claim 1, further comprising: (e) recycling hydrophilic solvent from the stripping step (c) and step (d) into the leaching step (b).
Claim 6
Dependent Claim 39 words
The process according to claim 1, further comprising: (f) separating the contaminant from the hydrophobic solvent of step (c) to produce decontaminated hydrophobic solvent; and (g) recycling the decontaminated hydrophobic solvent of step (f) to the stripping step (c).
Claim 7
Dependent Claim 16 words
The process according to claim 1, wherein each portion of step (b) is a multistage process.
Claim 8
Dependent Claim 27 words
The process according to claim 1, wherein the hydrophilic solvent comprises a solvent, which has a boiling point lower than water and is completely miscible with water.
Claim 9
Dependent Claim 32 words
The process according to claim 1, wherein the step (c) of stripping comprises contacting the contaminated solvent in a liquid-liquid extractor with the hydrophobic solvent and an aqueous solution of potassium sulfate.
Claim 10
Dependent Claim 18 words
A process according to claim 1, wherein the mass ratio of solvent to solids is 0.5 to 15.
Claim 11
Dependent Claim 18 words
A process according to claim 1, wherein the mass ratio of solvent to solids is 0.5 to 5.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-25 1993-03-27 1993-09-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-25 1997-03-27 1997-09-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-25 2001-03-27 2001-09-26 $7700.00 Window Closed / Lapsed

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