Method for decomposition of halogenated organic compounds

Claim 3

The method claimed in claim 1 wherein (i) said decomposition reagent is formed from an alkali metal hydroxide selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, or mixtures thereof, and a reactant having the formula set forth in claim 1 wherein R 1 and R 2 are hydrogen and x is 2, and (ii) said halogenated organic compound is selected from the group consisting of hexachlorocyclohexane, hexachlorobenzene, trichlorobenzene, tetrachlorobenzene, dichlorophenol, pentachlorophenol, dichlorodiphenyltrichloroethane, decachlorooctahydro-1,3,4-metheno-2H-cyclobuta-[c,d]-pentalen-2- one and polychlorinated biphenyl.

Claim 4

The method claimed in claim 1 wherein said decomposition reagent is formed from sodium hydroxide and polyethylene glycol.

Claim 5

The method claimed in claim 3 wherein the halogenated organic compound comprises polychlorinated biphenyl.

Claim 6

The method claimed in claim 1 wherein the step of providing the decomposition reagent is carried out using an aqueous solution of the alkali metal hydroxide.

Claim 7

The method claimed in claim 5 wherein the halogenated organic compound is dissolved in a water-immiscible liquid, whereby the mixture remaining after the reaction of the decomposition reagent with the halogenated organic compound separates into two liquid phases comprising an aqueous phase and a water-immiscible phase substantially free of said halogenated organic compound, and the water-immiscible phase is separated from the aqueous phase.

Claim 9

The method claimed in claim 7 wherein the alkali metal hydroxide is reacted with the reactant at a mole ratio of about 1.1 moles of alkali metal hydroxide per mole of reactant.

Claim 10

In the method for decomposing a halogenated organic compound by the steps of providing a decomposition reagent formed by reacting an alkali metal, a reactant having the general formula ##STR3## wherein R is hydrogen or lower alkyl, R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, unsubstituted or substituted lower alkyl, unsubstituted or substituted cycloalkyl having from 5 to 8 carbon atoms, and unsubstituted or substituted aryl, n has a value from about 2 to about 400 and x has a value of at least 2, and oxygen; and reacting the halogenated organic compound with the decomposition reagent in the presence of oxygen to effect substantially complete dehalogenation of said halogenated organic compound and form an oxygenated derivative of said compound, the improvement which comprises introducing into the decomposition reaction mixture an alkali metal containing compound which is soluble therein to enhance the reactivity of said decomposition reagent.

Claim 11

In the method for decomposing a halogenated organic compound by the steps of providing a decomposition reagent formed by reacting an alkali metal, a reactant having the general formula ##STR3## wherein R is hydrogen or lower alkyl, R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, unsubstituted or substituted lower alkyl, unsubstituted or substituted cycloalkyl having from 5 to 8 carbon atoms, and unsubstituted or substituted aryl, n has a value from about 2 to about 400 and x has a value of at least 2, and oxygen; and reacting the halogenated organic compound with the decomposition reagent in the presence of oxygen to effect substantially complete dehalogenation of said halogenated organic compound and form an oxygenated derivative of said compound, the improvement which comprises introducing into the decomposition reaction mixture an alkali metal containing compound which is soluble therein to enhance the reactivity of said decomposition reagent.

Claim 12

The method claimed in claim 9 wherein said alkali metal-containing compound is an alkali metal hydroxide and said halogenated organic compound is selected from the group consisting of hexachlorocyclohexane, hexachlorobenzene, trichlorobenzene, tetrachlorobenzene, pentachlorophenol, dichlorodiphenyltrichloroethane, decachlorooctahydro-1,3,4-metheno-2H-cyclobutra-[c,d]-pentalen-2- one and polychlorinated biphenyl.

Claim 13

The method claimed in claim 10 wherein said decomposition reagent is formed from sodium, polyethylene glycol and oxygen and the alkali metal hydroxide is sodium hydroxide.

Claim 14

The method claimed in claim 11 wherein the halogenated organic compound comprises polychlorinated biphenyl.

Claim 15

The method claimed in claim 10 wherein the alkali metal hydroxide is introduced in the form of an aqueous solution thereof.

Claim 16

The method claimed in claim 13 wherein the halogenated organic compound is dissolved in a water-immiscible liquid, whereby the mixture remaining after the reaction of the halogenated organic compound with the decomposition reagent separates into two liquid phases comprising an aqueous phase and a water-immiscible phase substantially free of said organic halogenated compound, and the water-immiscible phase is separated from the aqueous phase.

Claim 17

The method claimed in claim 1, wherein said decomposition reagent is formed from potassium hydroxide and polyethylene glycol.

Claim 18

The method claimed in claim 15, wherein the halogenated organic compound comprises 2, 4, 5-trichlorophenoxyacetic acid.

Claim 19

The method claimed in claim 15, wherein the halogenated organic compound comprises polychlorinated biphenyl.

Claim 20

The method claimed in claim 9, wherein said alkali metal-containing compound is an alkali metal hydroxide.