Method for preparing straight-chain primary alcohols

Claim 2

In a process for preparing straight-chain, primary alcohols having 6 - 20 carbon atoms, the improvement comprising: reacting at a temperature of about 150° to 300°C straight-chain 1-chloroalkanes having 6 to 20 carbon atoms with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids based on said alkali salts of the alkanoic acids to form esters, saponifying said esters in an alkaline medium to form straight-chain, primary alcohols having 6 - 20 carbon atoms and separating said straight-chain, primary alcohols.

Claim 3

In a process for preparing straight-chain, primary alcohols having 6 - 20 carbon atoms, comprising: a. chlorinating straight-chain paraffins having 6 to 20 carbon atoms to form chlorinated paraffins; b. dehydrochlorinating and fractionally distilling said chlorinated paraffins; the improvement comprising: c. separating straight-chain 1-chloroalkanes having 6 to 20 carbon atoms as a sump product; d. reacting said straight-chain 1-chloroalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids having 4 to 22 carbon atoms and at a temperature of about 150° to 300°C to form esters; e. saponifying said esters in an alkaline medium to form said straight-chain, primary alcohols having 6-20 carbon atoms; and f. separating said straight-chain, primary alcohols.

Claim 4

In a process for preparing straight-chain, primary alcohols having 6 - 20 carbon atoms, comprising: a. chlorinating straight-chain paraffins having 6 to 20 carbon atoms to form chlorinated paraffins; b. dehydrochlorinating and fractionally distilling said chlorinated paraffins; the improvement comprising: c. separating straight-chain 1-chloroalkanes having 6 to 20 carbon atoms as a sump product; d. reacting said straight-chain 1-chloroalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids having 4 to 22 carbon atoms and at a temperature of about 150° to 300°C to form esters; e. saponifying said esters in an alkaline medium to form said straight-chain, primary alcohols having 6-20 carbon atoms; and f. separating said straight-chain, primary alcohols.

Claim 5

The process of claim 2, wherein said alkali salts of alkanoic acids have 4 to 10 carbon atoms.

Claim 6

The process of claim 3, wherein said reacting temperature is about 200° to 250°C.

Claim 7

The process of claim 2, wherein step (d) is carried out for a period of about 10 minutes to 5 hours.

Claim 8

The process of claim 5, wherein step (d) is carried out for a period of about 1 to 2 hours.

Claim 9

The process of claim 2, wherein said 1-chloroalkanes have a chlorine content of about 11 to 29 percent and are selected from the group consisting of lauryl chloride, 1-chloro-undecane, n-hexyl-chloride, 1-chloro-C20 alkane, 1-chloro-C22 alkane, mixtures of C-11 to C-14 1-chloroalkanes, 1-chloro-octane, 1-chloro-nonane, 1-chloro-decane, 1-chloro-tridecane, 1-chloropentedecane, 1-chloro-hexadecane, 1-chloro-heptadecane, 1-chloro-nonadecane and mixtures thereof.

Claim 10

In a process for preparing straight-chain, primary alcohols comprising dehydrochlorinating a solution consisting essentially of higher paraffinic hydrocarbons and not more than about 50 percent based on the total moles in solution of monochlorinated higher paraffinic hydrocarbon, said dehydrochlorinating comprising subjecting said solution to reflux fractional distillation at 100° - 500°C in the presence of a metallic iron catalyst; the improvement comprising: a. separating straight-chain 1-chloroalkanes having 6 to 20 carbon atoms as a sump product in said reflux fractional distillation; b. reacting said straight-chain 1-chloroalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids corresponding to the alkanoic structure of said alkali salts and at a temperature of about 150° to 300°C to form esters; c. saponifying said esters in an alkaline medium to form straight-chain, primary alcohols having 6-20 carbon atoms; and d. separating said straight-chain, primary alcohols.

Claim 11

In a process for preparing straight-chain, primary alcohols comprising dehydrochlorinating a solution consisting essentially of higher paraffinic hydrocarbons and not more than about 50 percent based on the total moles in solution of monochlorinated higher paraffinic hydrocarbon, said dehydrochlorinating comprising subjecting said solution to reflux fractional distillation at 100° - 500°C in the presence of a metallic iron catalyst; the improvement comprising: a. separating straight-chain 1-chloroalkanes having 6 to 20 carbon atoms as a sump product in said reflux fractional distillation; b. reacting said straight-chain 1-chloroalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids corresponding to the alkanoic structure of said alkali salts and at a temperature of about 150° to 300°C to form esters; c. saponifying said esters in an alkaline medium to form straight-chain, primary alcohols having 6-20 carbon atoms; and d. separating said straight-chain, primary alcohols.