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US4464351A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the thermal destruction of solid metable halogenated waste with resultant production of hydrogen halide therefrom

Assignee: Orica Ltd
•
Filing: 1981-12-07
•
Granted: 1984-08-07
•
Expires: 2001-12-07
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Abstract

Abstract A process for the thermal destruction of heavy halogenated wastes in a hydrogen/oxygen flame which process comprises passing a mixture of heavy halogenated wastes in the vapor phase and a carrier gas of hydrogen or hydrogen-rich hydrocarbon through burning means provided with gaseous oxygen. Destruction efficiencies of better than 99.999% can be achieved with typical industrial wastes comprising hexachlorobenzene, polychlorinated biphenyls and related compounds.

Inventors

  • 👤 Vladimir Vasak
  • 👤 Joze Sencar
  • 👤 King K. Mok

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 22:41
CPC Classifications
A; A62; A62D; A62D3/00; A62D3/30; A62D3/38; C; C01; C01B; C01B7/00; C01B7/01; F; F23; F23G; F23G7/00; A62D2101/00; A62D2101/20; A62D2101/22; A62D2203/00; A62D2203/10; F23C; F23C2900/00; F23C2900/9901

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 104 words
A process of thermal destruction of solid meltable heavy halogenated waste characterized in that a pre-heated mixture of heavy halogenated waste vapour and a carrier gas comprising at least 80% v/v hydrogen is burnt in a hydrogen/oxygen flame wherein the gaseous oxygen fed to the flame has an oxygen content of at least 40% w/w, and wherein the pre-heated mixture is formed by heating the heavy halogenated waste until molten and passing it concurrently with a quantity of carrier gas containing sufficient hydrogen for complete conversion of the heavy halogenated waste to hydrogen halide into a vaporization chamber maintained at or above 300° C.
Claim 2
Dependent Claim 104 words
A process of thermal destruction of solid meltable heavy halogenated waste characterized in that a pre-heated mixture of heavy halogenated waste vapour and a carrier gas comprising at least 80% v/v hydrogen is burnt in a hydrogen/oxygen flame wherein the gaseous oxygen fed to the flame has an oxygen content of at least 40% w/w, and wherein the pre-heated mixture is formed by heating the heavy halogenated waste until molten and passing it concurrently with a quantity of carrier gas containing sufficient hydrogen for complete conversion of the heavy halogenated waste to hydrogen halide into a vaporization chamber maintained at or above 300° C.
Claim 3
Dependent Claim 15 words
A process according to claim 1 wherein the heavy halogenated wastes comprise chlorinated aromatic wastes.
Claim 4
Dependent Claim 13 words
A process according to claim 2 wherein the chlorinated aromatic wastes comprise hexachlorobenzene.
Claim 5
Dependent Claim 26 words
A process according to claim 2 or claim 3 wherein the chlorinated aromatic wastes comprise a compound from the group consisting of polychlorinated biphenyls and octachlorostyrene.
Claim 6
Dependent Claim 15 words
A process according to claim 1 wherein the heavy halogenated wastes comprise chlorinated aliphatic wastes.
Claim 7
Dependent Claim 25 words
A process according to claim 5 wherein the chlorinated aliphatic wastes comprise a compound selected from the group consisting of hexachloroethane, perchloroethylene, hexachlorobutadiene and octachlorobutene.
Claim 8
Dependent Claim 12 words
A process according to claim 1 wherein the carrier gas is hydrogen.
Claim 9
Dependent Claim 37 words
A process according to claim 1 wherein the heavy halogenated wastes are converted to vapour by heating to a temperature above 106° C. and passing carrier gas through or over the surface of the heated halogenated wastes.
Claim 10
Dependent Claim 19 words
A process according to claim 1 wherein the carrier gas is preheated before contact with the heavy halogenated wastes.
Claim 11
Dependent Claim 42 words
A process according to claim 1 wherein the burning means comprises a central tube for passage of the said mixture of vapour of the heavy halogenated wastes and carrier gas surrounded by a substantially concentric tube for the passage of gaseous oxygen.
Claim 12
Dependent Claim 23 words
A process according to claim 1 wherein the halogen from the heavy halogenated wastes is recovered in a form comprising a hydrogen halide.
Claim 13
Dependent Claim 13 words
A process according to claim 11 wherein the hydrogen halide is hydrogen chloride.
Claim 14
Dependent Claim 18 words
A process according to claim 1 wherein at least 99.997% w/w of the heavy halogenated wastes is destroyed.
Claim 15
Dependent Claim 18 words
A process according to claim 13 wherein at least 99.999% w/w of the heavy halogenated wastes is destroyed.
Claim 16
Dependent Claim 18 words
A process according to claim 1 wherein the gaseous oxygen has an oxygen content of at least 90%.

References Cited (Backward Citations)

US3305309A Cited
US3445192A Cited
US3933989A Cited
US3845190A Cited
US3980758A Cited
GB1430146A Cited
US4140066A Cited
GB2033063A Cited
US4246255A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-07 1988-02-06 1988-08-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-07 1992-02-06 1992-08-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-07 1996-02-06 1996-08-07 $7700.00 Window Closed / Lapsed

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