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US4864074A
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Process for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates
Assignee: Mobil Oil AS
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Filing: 1988-05-03
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Granted: 1989-09-05
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Expires: 2008-05-03
Abstract
Abstract There is provided a process for converting methane to higher molecular weight hydrocarbons. In a first step, methane is contacted with elemental sulfur. In one embodiment, carbon disulfide and hydrogen sulfide are produced from this reaction of methane and sulfur, and this product is, in turn, reacted to form CH 3 SH. In another embodiment, CH 3 SH is formed directly in a one-step reaction of methane and sulfur. This CH 3 SH is then contacted with a sufficient catalyst, such as a zeolite, especially ZSM-5, under conditions sufficient to produce hydrocarbons having two or more carbon atoms.
Inventors
- 👤 Scott Han
- 👤 Robert E. Palermo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 19:20
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/32; C07C1/321; C07C1/322; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/93; Y10S585/934; Y10S585/943
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
78 words
A process for converting methane to higher molecular weight hydrocarbons, said process comprising the steps of: (i) contacting methane with sulfur under conditions sufficient to generate carbon disulfide; (ii) contacting said carbon disulfide of step (i) with hydrogen sulfide under conditions sufficient to generate CH 3 SH; and (iii) contacting said CH 3 SH of step (ii) with a catalyst under conditions sufficient to produce hydrogen sulfide and a mixture of hydrocarbons having at least two carbon atoms.
Claim 2
Dependent Claim
78 words
A process for converting methane to higher molecular weight hydrocarbons, said process comprising the steps of: (i) contacting methane with sulfur under conditions sufficient to generate carbon disulfide; (ii) contacting said carbon disulfide of step (i) with hydrogen sulfide under conditions sufficient to generate CH 3 SH; and (iii) contacting said CH 3 SH of step (ii) with a catalyst under conditions sufficient to produce hydrogen sulfide and a mixture of hydrocarbons having at least two carbon atoms.
Claim 3
Dependent Claim
45 words
A process according to claim 1 wherein the reaction mixture of step (i) comprises a sufficient amount of sulfur to convert all of the methane in the reaction mixture, whereby essentially all of the hydrogen in the methane reactant is converted to H 2 S.
Claim 4
Dependent Claim
29 words
A process according to claim 2, wherein carbon disulfide is produced in step (i) in accordance with the stoichiometry set forth in the following reaction: CH.sub.4 +4S→CS.sub.2 +2H.sub.2 S.
Claim 5
Dependent Claim
30 words
A process according to claim 3, wherein CH 3 SH is produced in step (ii) in accordance with the stoichiometry set forth in the following reaction: CS.sub.2 +2H.sub.2 S→CH.sub.3 SH+3S.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-09-04 | 1993-03-06 | 1993-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-04 | 1997-03-06 | 1997-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-04 | 2001-03-06 | 2001-09-05 | $7700.00 | Window Closed / Lapsed |