US4618732A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Direct conversion of natural gas to methanol by controlled oxidation
Assignee: HER MAJESTY IN RIGHT OF CANADA ENERGY, Minister of
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Filing: 1985-05-20
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Granted: 1986-10-21
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Expires: 2005-05-20
Abstract
Abstract A process of directly converting natural gas to methanol employs controlled oxidation. The reaction takes place in an inert reactor, i.e. one having internal surfaces which do not affect the reaction, in the absence of a catalyst. The natural gas is intimately mixed with air or oxygen prior to introduction of the mixed gases into the reactor. Reaction takes place at an elevated temperature of 300 DEG to 500 DEG C. and at an elevated pressure of 10 to 100 atmospheres. The percentage of oxygen in the mixture of reactant gases is kept below 20% by volume and is preferably 2 to 10% by volume. Apparatus for carrying out the method is also provided.
Inventors
- 👤 Hyman D. Gesser
- 👤 Norman R. Hunter
- 👤 Lawrence Morton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:10
CPC Classifications
C; C07; C07C; C07C29/00; C07C29/48; C07C29/50
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
117 words
A process for converting natural gas containing methane to methanol, comprising: thoroughly and intimately mixing natural gas with gaseous air or oxygen to achieve substantially complete homogeneity of these gases; feeding the resulting gas mixture to an inert reactor under elevated pressure, said inert reactor having an internal surface surrounding a zone in which said gases react, said surface being made of a material selected from the group consisting of glass, non-reactive plastics, non-reactive waxes and non-reactive salts; and reacting said gases in said reaction zone at an elevated temperature in the absence in said reaction zone of any added material which measurably affects the rate of selectivity of the reaction or the yield of the product.
Claim 2
Dependent Claim
117 words
A process for converting natural gas containing methane to methanol, comprising: thoroughly and intimately mixing natural gas with gaseous air or oxygen to achieve substantially complete homogeneity of these gases; feeding the resulting gas mixture to an inert reactor under elevated pressure, said inert reactor having an internal surface surrounding a zone in which said gases react, said surface being made of a material selected from the group consisting of glass, non-reactive plastics, non-reactive waxes and non-reactive salts; and reacting said gases in said reaction zone at an elevated temperature in the absence in said reaction zone of any added material which measurably affects the rate of selectivity of the reaction or the yield of the product.
Claim 3
Dependent Claim
46 words
A process according to claim 1 wherein said thorough and intimate mixing is achieved by separately passing said gases at said elevated pressure into a mixing chamber containing a porous mass through porous diffuser plates and then feeding the resulting gas mixture to said inert reactor.
Claim 4
Dependent Claim
26 words
A process according to claim 2 wherein said gases are fed to said reactor via a needle valve to effect further intimate mixing of the gases.
Claim 5
Dependent Claim
13 words
A process according to claim 1 wherein said surface is made of glass.
Claim 6
Dependent Claim
13 words
A process according to claim 1 wherein said surface is made of polytetrafluoroethylene.
Claim 7
Dependent Claim
21 words
A process according to claim 1 wherein said reation is carried out at a temperature in the range of 300°-400° C.
Claim 8
Dependent Claim
23 words
A process according to claim 1 wherein said reaction is carried out at a pressure in the range of 10 to 100 atmospheres.
Claim 9
Dependent Claim
26 words
A process according to claim 1 wherein said gases are reacted in said reactor for a time period in the range of 2 to 1000 seconds.
Claim 10
Dependent Claim
37 words
A process according to claim 1 wherein respective amounts of said natural gas and air or oxygen are mixed together to give an oxygen content in the resulting mixed gas in the range of 2 to 20%.
Claim 11
Dependent Claim
42 words
A process according to claim 1 wherein methanol is removed from a reaction product resulting from reacting said gases, and any unreacted methane in said reaction product is further subjected to the mixing, feeding and reacting step as defined in claim 1.
Claim 12
Dependent Claim
34 words
A process according to claim 10 wherein said unreacted methane undergoes said further reacting step by recirculating it to the reactor used for the initial reaction of natural gas with gaseous air or oxygen.
Claim 13
Dependent Claim
25 words
A process according to claim 1 wherein said gases are each raised to said elevated pressure before said thorough and intimate mixing step takes place.
Claim 14
Dependent Claim
26 words
A process according to claim 1 wherein the natural gas and oxygen or air are introduced into the reactor in the absence of other gaseous materials.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-10-20 | 1990-04-21 | 1990-10-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-10-20 | 1994-04-21 | 1994-10-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-10-20 | 1998-04-21 | 1998-10-21 | $7700.00 | Window Closed / Lapsed |