US4544785A
Expired / Lapsed
US
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Methane conversion
Assignee: Atlantic Richfield Co
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Filing: 1984-04-16
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Granted: 1985-10-01
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Expires: 2004-04-16
Abstract
Abstract A method is disclosed for converting methane to higher hydrocarbon product by contacting methane with a solid which comprises a reducible metal oxide which when contacted with methane at a temperature within the range of about 500° to 1000° C. is reduced and produces higher hydrocarbon products and a promoting amount of at least one chalcogen component. The preferred chalcogen components are selected from a group consisting of sulfur, selenium, tellurium, and compounds thereof.
Inventors
- 👤 Howard P. Withers
- 👤 John A. Sofranko
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 11:03
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/76; C07C2/82; C07C2/84; C07C2523/00; C07C2523/14; C07C2523/16; C07C2523/18; C07C2523/32; C07C2523/34; C07C2527/00; C07C2527/02; C07C2527/057; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/943
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
76 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature selected within the range of 500° to 1000° C. with a contact solid comprising at least one reducible oxide of at least metal which oxides when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises incorporating at least one chalcogen component into said contact solid.
Claim 2
Dependent Claim
76 words
In an improved method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a temperature selected within the range of 500° to 1000° C. with a contact solid comprising at least one reducible oxide of at least metal which oxides when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises incorporating at least one chalcogen component into said contact solid.
Claim 3
Independent Claim
170 words
A method for converting methane to higher hydrocarbons which comprises: (a) contacting at a temperature selected within the range of about 500° to 1000° C. a gas comprising methane and a contact solid comprising: (1) at least one reducible oxide of at least one metal selected from the group consisting of Mn, Sn, In, Ge, Pb, Sb and Bi and (2) at least one promoter selected from the group consisting of the chalcogens and compounds thereof, said contacting producing an effluent comprising higher hydrocarbons and water and solids comprising reduced metal oxides; (b) recovering higher hydrocarbons; (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide; (d) at least periodically contacting solids selected from the group consisting of solids comprising reduced metal oxides and said regenerated solids with a chalcogen source to incorporate additional chalcogen promoter into said selected solids; and (e) contacting a gas comprising methane with solids produced in step (d) as recited in step (a).
Claim 4
Independent Claim
170 words
A method for converting methane to higher hydrocarbons which comprises: (a) contacting at a temperature selected within the range of about 500° to 1000° C. a gas comprising methane and a contact solid comprising: (1) at least one reducible oxide of at least one metal selected from the group consisting of Mn, Sn, In, Ge, Pb, Sb and Bi and (2) at least one promoter selected from the group consisting of the chalcogens and compounds thereof, said contacting producing an effluent comprising higher hydrocarbons and water and solids comprising reduced metal oxides; (b) recovering higher hydrocarbons; (c) at least periodically contacting solids comprising reduced metal oxides with an oxygen-containing gas to regenerate solids comprising a reducible metal oxide; (d) at least periodically contacting solids selected from the group consisting of solids comprising reduced metal oxides and said regenerated solids with a chalcogen source to incorporate additional chalcogen promoter into said selected solids; and (e) contacting a gas comprising methane with solids produced in step (d) as recited in step (a).
Claim 5
Dependent Claim
22 words
The method of claim 2 wherein said oxygen-containing gas and said chalcogen source are simultaneously contacted with solids comprising reduced metal oxides.
Claim 6
Dependent Claim
23 words
The method of claim 2 wherein said gas comprising methane and said chalcogen source are simultaneously contacted with solids comprising reducible metal oxides.
Claim 7
Dependent Claim
88 words
In an improved method for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises at least periodically contacting a member of the group consisting of said reducible metal oxides, said reduced metal oxides and mixtures thereof with a chalcogen source.
Claim 8
Dependent Claim
88 words
In an improved method for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature within the range of about 500° to 1000° C. with at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water, the improvement which comprises at least periodically contacting a member of the group consisting of said reducible metal oxides, said reduced metal oxides and mixtures thereof with a chalcogen source.
Claim 9
Dependent Claim
116 words
In an improved method for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature selected with the range of about 500° to 1000° C. with a solid comprising: (a) at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water; and (b) at least one member of the group consisting of alkali metals, alkaline earth metals and compounds thereof; the improvement which comprises at least periodically contacting a member of the group consisting of solids comprising said reducible metal oxides solids comprising said reduced metal oxides and mixtures thereof with a chalcogen source.
Claim 10
Dependent Claim
116 words
In an improved method for converting methane to higher hydrocarbon products comprising contacting a gas comprising methane at a temperature selected with the range of about 500° to 1000° C. with a solid comprising: (a) at least one reducible oxide of at least one metal which oxide(s) when contacted with methane at said temperature are reduced and produce higher hydrocarbon products and water; and (b) at least one member of the group consisting of alkali metals, alkaline earth metals and compounds thereof; the improvement which comprises at least periodically contacting a member of the group consisting of solids comprising said reducible metal oxides solids comprising said reduced metal oxides and mixtures thereof with a chalcogen source.
Claim 11
Dependent Claim
23 words
The method of claim 6 wherein component (b) of the solid is selected from the group consisting of alkali metals and compounds thereof.
Claim 12
Dependent Claim
22 words
The method of claim 6 wherein component (b) of the solid is selected from the group consisting of sodium and compounds thereof.
Claim 13
Dependent Claim
22 words
The method of claim 6 wherein component (b) of the solid is selected from the group consisting of lithium and compounds thereof.
Claim 14
Dependent Claim
22 words
The method of claim 6 wherein component (b) of the solid is selected from the group consisting of potassium and compounds thereof.
Claim 15
Dependent Claim
15 words
The method of claim 1 wherein said chalcogen component comprises sulfur and/or a compound thereof.
Claim 16
Dependent Claim
15 words
The method of claim 1 wherein said chalcogen component comprises selenium and/or a compound thereof.
Claim 17
Dependent Claim
15 words
The method of claim 1 wherein said chalcogen component comprises tellurium and/or a compound thereof.
Claim 18
Dependent Claim
15 words
The method of claim 5 wherein said chalcogen component comprises sulfur and/or a compound thereof.
Claim 19
Dependent Claim
15 words
The method of claim 5 wherein said chalcogen source comprises selenium and/or a compound thereof.
Claim 20
Dependent Claim
15 words
The method of claim 5 wherein said chalcogen source comprises tellurium and/or a compound thereof.
Claim 21
Dependent Claim
15 words
The method of claim 7 wherein said chalcogen source comprises sulfur and/or a compound thereof.
Claim 22
Dependent Claim
15 words
The method of claim 7 wherein said chalcogen source comprises selenium and/or a compound thereof.
Claim 23
Dependent Claim
15 words
The method of claim 7 wherein said chalcogen source comprises tellurium and/or a compound thereof.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-09-30 | 1989-04-01 | 1989-10-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-09-30 | 1993-04-01 | 1993-10-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-09-30 | 1997-04-01 | 1997-10-01 | $7700.00 | Window Closed / Lapsed |