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US4480143A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocarbon synthesis

Assignee: CHANG CLARENCE D AND LANG WILLIAM H
•
Filing: 1981-01-28
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Granted: 1984-10-30
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Expires: 2001-01-28
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Abstract

Abstract A process for converting or synthesizing hydrocarbons from carbon sulfides such as CS2 by catalytic hydrogenation over catalysts such ZSM-5 type zeolites.

Inventors

  • 👤 Clarence D. Chang
  • 👤 William H. Lang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 07:23
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/32; C07C1/321; C07C1/322; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C07C2529/42; C07C2529/44; C07C2529/46; C07C2529/65; C07C2529/66; C07C2529/67; C07C2529/68; C07C2529/70; C07C2529/72; C07C2529/74; C07C2529/76

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 104 words
A process for converting as a reactant carbon sulfides selected from the group consisting of CS 2 and COS to a hydrocarbon or mixture of hydrocarbons ranging from C 1 to C 11 + wherein at least 25% thereof are C 5 to C 11 comprising contacting said carbon sulfides with a ZSM-5 type aluminosilicate zeolite catalyst having a constraint index of about 1 to 12 and having a silica to alumina ratio of at least 12 at about 400° to 1200° F. and a pressure of about 100 to 1000 psig in the presence of added hydrogen to produce a highly aromatic product.
Claim 2
Dependent Claim 104 words
A process for converting as a reactant carbon sulfides selected from the group consisting of CS 2 and COS to a hydrocarbon or mixture of hydrocarbons ranging from C 1 to C 11 + wherein at least 25% thereof are C 5 to C 11 comprising contacting said carbon sulfides with a ZSM-5 type aluminosilicate zeolite catalyst having a constraint index of about 1 to 12 and having a silica to alumina ratio of at least 12 at about 400° to 1200° F. and a pressure of about 100 to 1000 psig in the presence of added hydrogen to produce a highly aromatic product.
Claim 3
Dependent Claim 24 words
The process of claim 1 wherein the catalyst is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-35, ZSM-38 and their hydrogen forms.
Claim 4
Dependent Claim 23 words
The process of claim 2 wherein said catalyst is further comprised of a Group II or Group VIII metal from the Periodic Table.
Claim 5
Dependent Claim 23 words
The process of claim 3 wherein the metals are selected from the group consisting of Co, Co/Mn, Zn, ZnPd, Ni, NiW and Ni/Mo.

References Cited (Backward Citations)

US2041840A Cited
US4265735A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-30 1988-04-30 1988-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-30 1992-04-30 1992-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-30 1996-04-30 1996-10-30 $7700.00 Window Closed / Lapsed

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