Negative resist material

Claim 2

A negative resist material, consisting of poly(silsesquioxane) of weight average molecular weight 2000 or more represented by the general formula (1): (CH.sub.2 ═CHCH.sub.2 SiO.sub.3/2).sub.m (ClCH.sub.2 SiO.sub.3/2).sub.n ( 1) where m and n denote the molar percentages of each component of the polymer, wherein both are positive numbers and m+n=100.

Claim 3

A material as set forth in claim 1 wherein the weight average molecular weight is 2500 or more.

Claim 4

A material as set forth in claim 2 wherein the weight average molecular weight is 3000 to 100,000.

Claim 5

A material as set forth in claim 1 wherein m is not more than 30.

Claim 6

A process for manufacturing a silicone resin used as resist material, wherein an oligomer is first obtained by hydrolyzing the trifunctional silane monomers represented by formulas (2) and (3) below for a time and temperature sufficient to produce said oligomer: CH.sub.2 ═CHCH.sub.2 SiX.sub.3 ( 2) ClCH.sub.2 SiY.sub.3 ( 3) X, Y being chlorine, bromine, methoxy, ethoxy or acetoxy that is susceptible to hydrolysis, said oligomer thus obtained is then further polymerized in the presence of an amine basic catalyst in an amount sufficient to further polymerize the oligomers to higher molecular weight polymers having a weight average molecular weight of 2000 or more, said catalytic polymerization reaction being carried out in ketonic solvent for a time and temperature sufficient to give a compound represented by formula (1) below: (CH.sub.2 ═CHCH.sub.2 SiO.sub.3/2).sub.m ·(ClCH.sub.2 SiO.sub.3/2).sub.n ( 1) m and n being molar percentages in which m and n are positive numbers and wherein m+n=100.

Claim 7

A process for manufacturing a silicone resin used as resist material, wherein an oligomer is first obtained by hydrolyzing the trifunctional silane monomers represented by formulas (2) and (3) below for a time and temperature sufficient to produce said oligomer: CH.sub.2 ═CHCH.sub.2 SiX.sub.3 ( 2) ClCH.sub.2 SiY.sub.3 ( 3) X, Y being chlorine, bromine, methoxy, ethoxy or acetoxy that is susceptible to hydrolysis, said oligomer thus obtained is then further polymerized in the presence of an amine basic catalyst in an amount sufficient to further polymerize the oligomers to higher molecular weight polymers having a weight average molecular weight of 2000 or more, said catalytic polymerization reaction being carried out in ketonic solvent for a time and temperature sufficient to give a compound represented by formula (1) below: (CH.sub.2 ═CHCH.sub.2 SiO.sub.3/2).sub.m ·(ClCH.sub.2 SiO.sub.3/2).sub.n ( 1) m and n being molar percentages in which m and n are positive numbers and wherein m+n=100.

Claim 8

A process as set forth in claim 5, wherein the solvent in the polymerization is acetone, methyl isobutyl ketone, methyl ethyl ketone, dioxane or tetrahydrofuran.

Claim 9

A process as set forth in claim 5, wherein the basic catalyst used in the polymerization is triethylamine, tri-n-butylamine, pyridine, lutidine or --collidine.

Claim 10

A process as set forth in claim 5, wherein m is not more than 30.

Claim 11

A negative resist material according to claim 1 wherein m varies from 20 to 80 and n varies from 80 to 20.

Claim 12

A process according to claim 5 wherein m varies from 20 to 80 and n varies from 80 to 20.

Claim 13

A process according to claim 5 wherein the hydrolysis is carried out in the presence of an acid.

Claim 14

A process according to claim 5 wherein the hydrolysis is carried out in the presence of triethylamine.