Patent US4769443A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4769443A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric compounds containing piperidine radicals and their use as stabilizers for synthetic polymers

Assignee: Novartis Corp
•
Filing: 1987-08-03
•
Granted: 1988-09-06
•
Expires: 2007-08-03
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R 3 and R 4 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R 5 additionally can be a radical of formula VII ##STR3## and R 4 is C 2 -C 18 -diacyl or a radical of the formula ##STR4##

Inventors

  • 👤 Giuseppe Cantatore

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 14:08
CPC Classifications
C; C07; C07D; C07D401/00; C07D401/14; C07D471/00; C07D471/02; C07D471/10; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 315 words
A compound of the formula (I) ##STR23## in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 2 -C 12 -alkyl substituted by --OH, a C 1 -C 18 -alkoxy group or a C 2 -C 18 -dialkylamino group, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula ##STR24## where R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkynyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, or R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a heterocylic radical, such as pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl, morpholin-4-yl or 4-methylpiperazin-1-yl, R 3 and R 5 can be identical or different and are radicals of the formula (III), (IV), (V) or (VI) ##STR25## and R 5 additionally can be radical of formula VII ##STR26## wherein R 7 is hydrogen, C 1 -C 6 -alkyl or phenyl, X is a group --O--CH 2 ) n O-- or --N(R 8 )--C(O)--CH 2 ) n C(O)--N(R 8 )--, n is a number between 1 and 6, R 8 has the same meaning as R 1 or R 2 and Y is C 2 -C 12 -alkylene, C 3 -C 12 -alkylene substituted by one hydroxyl or containing an oxgen atom in the chain, C 4 -C 12 -alkenylene or C 8 -C 12 aralkylene, R 4 is C 2 -C 18 -diacyl or a radical of the formula (VIII) ##STR27## in which R 1 and R 2 are as defined above, a is a number between 0.2 and 1, and b is a number between zero and 0.8; the compounds of the formula (I) have a number average molecular weight Mn between 1,000 and 20,000.
Claim 2
Dependent Claim 315 words
A compound of the formula (I) ##STR23## in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 2 -C 12 -alkyl substituted by --OH, a C 1 -C 18 -alkoxy group or a C 2 -C 18 -dialkylamino group, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula ##STR24## where R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkynyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, or R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a heterocylic radical, such as pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl, morpholin-4-yl or 4-methylpiperazin-1-yl, R 3 and R 5 can be identical or different and are radicals of the formula (III), (IV), (V) or (VI) ##STR25## and R 5 additionally can be radical of formula VII ##STR26## wherein R 7 is hydrogen, C 1 -C 6 -alkyl or phenyl, X is a group --O--CH 2 ) n O-- or --N(R 8 )--C(O)--CH 2 ) n C(O)--N(R 8 )--, n is a number between 1 and 6, R 8 has the same meaning as R 1 or R 2 and Y is C 2 -C 12 -alkylene, C 3 -C 12 -alkylene substituted by one hydroxyl or containing an oxgen atom in the chain, C 4 -C 12 -alkenylene or C 8 -C 12 aralkylene, R 4 is C 2 -C 18 -diacyl or a radical of the formula (VIII) ##STR27## in which R 1 and R 2 are as defined above, a is a number between 0.2 and 1, and b is a number between zero and 0.8; the compounds of the formula (I) have a number average molecular weight Mn between 1,000 and 20,000.
Claim 3
Dependent Claim 191 words
A compound according to claim 1, of the formula (I), in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 12 -alkyl, C 2 -C 6 -alkyl substituted by C 1 -C 12 -alkoxy, C 3 -C 6 alkenyl, C 6 -C 10 -cycloalkyl or a radical of the formula (II) in which R 6 is hydrogen, methyl, allyl, benzyl or acetyl, or the radicals R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl or morpholin-4-yl radical, R 3 and R 5 are a radical of formula (III) and R 5 additionally can be a radical of formula (VII), R 7 is hydrogen, methyl, or ethyl, Y is C 2 -C 6 -alkylene, but-2-ene-1,4-diyl or xylylene, R 4 is C 2 -C 12 -diacyl or a radical of the formula (VIII) in which R 1 and R 2 are as defined above, a is a number between 0.3 and 1, and b is a number between zero and 0.7, and the number average molecular weight Mn is between 1,500 and 10,000.
Claim 4
Dependent Claim 85 words
A compound according to claim 1, of the formula (I), in which R 1 and R 2 can be identical or different and are C 1 -C 18 -alkyl, cyclohexyl, 2,2,6,6-tetramethyl-piperidin-4-yl or 1,2,2,6,6-pentamethyl-piperidin-4-yl, R 3 and R 5 are a radical of formula (III) and R 5 additionally can be a radical of formula (VIII), R 7 is hydrogen or methyl, Y is but-2-ene-1,4-diyl or xylylene, a is 1 and b is zero, and the number average molecular weight Mn is between 15,000 and 6,000.

References Cited (Backward Citations)

US4028334A Cited
US4086204A Cited
US4108829A Cited
US4263434A Cited
US4294963A Cited
US4250268A Cited
US4395508A Cited
US4356287A Cited
US4400505A Cited
US4412020A Cited
US4696961A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-06 1992-03-07 1992-09-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-06 1996-03-07 1996-09-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-06 2000-03-07 2000-09-06 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag