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US4769443A
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Polymeric compounds containing piperidine radicals and their use as stabilizers for synthetic polymers
Assignee: Novartis Corp
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Filing: 1987-08-03
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Granted: 1988-09-06
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Expires: 2007-08-03
Abstract
Abstract Novel light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers have been synthesized; these are of the formula: ##STR1## in which R 3 and R 4 can be identical or different and are radicals of formula (III), (IV), (V), (VI) ##STR2## and R 5 additionally can be a radical of formula VII ##STR3## and R 4 is C 2 -C 18 -diacyl or a radical of the formula ##STR4##
Inventors
- 👤 Giuseppe Cantatore
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:08
CPC Classifications
C; C07; C07D; C07D401/00; C07D401/14; C07D471/00; C07D471/02; C07D471/10; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
315 words
A compound of the formula (I) ##STR23## in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 2 -C 12 -alkyl substituted by --OH, a C 1 -C 18 -alkoxy group or a C 2 -C 18 -dialkylamino group, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula ##STR24## where R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkynyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, or R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a heterocylic radical, such as pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl, morpholin-4-yl or 4-methylpiperazin-1-yl, R 3 and R 5 can be identical or different and are radicals of the formula (III), (IV), (V) or (VI) ##STR25## and R 5 additionally can be radical of formula VII ##STR26## wherein R 7 is hydrogen, C 1 -C 6 -alkyl or phenyl, X is a group --O--CH 2 ) n O-- or --N(R 8 )--C(O)--CH 2 ) n C(O)--N(R 8 )--, n is a number between 1 and 6, R 8 has the same meaning as R 1 or R 2 and Y is C 2 -C 12 -alkylene, C 3 -C 12 -alkylene substituted by one hydroxyl or containing an oxgen atom in the chain, C 4 -C 12 -alkenylene or C 8 -C 12 aralkylene, R 4 is C 2 -C 18 -diacyl or a radical of the formula (VIII) ##STR27## in which R 1 and R 2 are as defined above, a is a number between 0.2 and 1, and b is a number between zero and 0.8; the compounds of the formula (I) have a number average molecular weight Mn between 1,000 and 20,000.
Claim 2
Dependent Claim
315 words
A compound of the formula (I) ##STR23## in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 2 -C 12 -alkyl substituted by --OH, a C 1 -C 18 -alkoxy group or a C 2 -C 18 -dialkylamino group, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula ##STR24## where R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkynyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, or R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a heterocylic radical, such as pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl, morpholin-4-yl or 4-methylpiperazin-1-yl, R 3 and R 5 can be identical or different and are radicals of the formula (III), (IV), (V) or (VI) ##STR25## and R 5 additionally can be radical of formula VII ##STR26## wherein R 7 is hydrogen, C 1 -C 6 -alkyl or phenyl, X is a group --O--CH 2 ) n O-- or --N(R 8 )--C(O)--CH 2 ) n C(O)--N(R 8 )--, n is a number between 1 and 6, R 8 has the same meaning as R 1 or R 2 and Y is C 2 -C 12 -alkylene, C 3 -C 12 -alkylene substituted by one hydroxyl or containing an oxgen atom in the chain, C 4 -C 12 -alkenylene or C 8 -C 12 aralkylene, R 4 is C 2 -C 18 -diacyl or a radical of the formula (VIII) ##STR27## in which R 1 and R 2 are as defined above, a is a number between 0.2 and 1, and b is a number between zero and 0.8; the compounds of the formula (I) have a number average molecular weight Mn between 1,000 and 20,000.
Claim 3
Dependent Claim
191 words
A compound according to claim 1, of the formula (I), in which R 1 and R 2 can be identical or different and are hydrogen, C 1 -C 12 -alkyl, C 2 -C 6 -alkyl substituted by C 1 -C 12 -alkoxy, C 3 -C 6 alkenyl, C 6 -C 10 -cycloalkyl or a radical of the formula (II) in which R 6 is hydrogen, methyl, allyl, benzyl or acetyl, or the radicals R 1 and R 2 , together with the nitrogen atom to which they are bonded, are a pyrrolidin-1-yl, piperidin-1-yl, hexahydroazepin-1-yl or morpholin-4-yl radical, R 3 and R 5 are a radical of formula (III) and R 5 additionally can be a radical of formula (VII), R 7 is hydrogen, methyl, or ethyl, Y is C 2 -C 6 -alkylene, but-2-ene-1,4-diyl or xylylene, R 4 is C 2 -C 12 -diacyl or a radical of the formula (VIII) in which R 1 and R 2 are as defined above, a is a number between 0.3 and 1, and b is a number between zero and 0.7, and the number average molecular weight Mn is between 1,500 and 10,000.
Claim 4
Dependent Claim
85 words
A compound according to claim 1, of the formula (I), in which R 1 and R 2 can be identical or different and are C 1 -C 18 -alkyl, cyclohexyl, 2,2,6,6-tetramethyl-piperidin-4-yl or 1,2,2,6,6-pentamethyl-piperidin-4-yl, R 3 and R 5 are a radical of formula (III) and R 5 additionally can be a radical of formula (VIII), R 7 is hydrogen or methyl, Y is but-2-ene-1,4-diyl or xylylene, a is 1 and b is zero, and the number average molecular weight Mn is between 15,000 and 6,000.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-09-06 | 1992-03-07 | 1992-09-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-09-06 | 1996-03-07 | 1996-09-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-09-06 | 2000-03-07 | 2000-09-06 | $7700.00 | Window Closed / Lapsed |