US4412020A
Expired / Lapsed
US
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Novel light stabilizers for polymers
Assignee: Wyeth Holdings LLC
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Filing: 1981-07-20
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Granted: 1983-10-25
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Expires: 2001-07-20
Abstract
Abstract Oligomers of the formula: ##STR1## wherein at least one of the substituents contains a piperidyl group are disclosed as light stabilizers for polymers. Also disclosed is a method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation, by incorporating therein an ultraviolet stabilizingly effective amount of such oligomer.
Inventors
- 👤 Frank F. Loffelman
- 👤 Joseph A. Hoffman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 17:31
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
280 words
An oligomer of the formula: ##STR16## wherein R represents C 1 -C 8 alkyl; R 1 represents C 1 -C 8 alkoxy, C 1 -C 8 alkyl, halo, C 1 -C 8 alkylthio, amino, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, pyrrolidyl, piperidino the groups ##STR17## wherein R 2 , R 3 , R 4 , R 5 and R 6 are as defined below, a substituted C 1 -C 18 alkylamino or C 1 -C 18 dialkylamino, wherein the substitutents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1-8 carbon atoms, and the groups ##STR18## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; and R 6 represents hydrogen, C 1 -C 8 alkyl or ##STR19## Y and Y 1 , which may be the same or different, represent oxy or ##STR20## wherein R 6 is as previously defined; X and X 1 represent C 2 -C 18 alkylene, wherein the alkylene chain may be interrupted by one or more oxy, thio, or ##STR21## radicals, C 5 -C 10 cycloalkylene, ##STR22## C 6 -C 12 arylene, or C 8 -C 14 aralkylene, and n is an integer greater than 1; with the proviso that when Y and Y 1 are oxy, or R 6 is hydrogen or C 1 -C 16 alkyl, at least one R 1 is ##STR23##
Claim 2
Dependent Claim
280 words
An oligomer of the formula: ##STR16## wherein R represents C 1 -C 8 alkyl; R 1 represents C 1 -C 8 alkoxy, C 1 -C 8 alkyl, halo, C 1 -C 8 alkylthio, amino, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, pyrrolidyl, piperidino the groups ##STR17## wherein R 2 , R 3 , R 4 , R 5 and R 6 are as defined below, a substituted C 1 -C 18 alkylamino or C 1 -C 18 dialkylamino, wherein the substitutents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1-8 carbon atoms, and the groups ##STR18## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; and R 6 represents hydrogen, C 1 -C 8 alkyl or ##STR19## Y and Y 1 , which may be the same or different, represent oxy or ##STR20## wherein R 6 is as previously defined; X and X 1 represent C 2 -C 18 alkylene, wherein the alkylene chain may be interrupted by one or more oxy, thio, or ##STR21## radicals, C 5 -C 10 cycloalkylene, ##STR22## C 6 -C 12 arylene, or C 8 -C 14 aralkylene, and n is an integer greater than 1; with the proviso that when Y and Y 1 are oxy, or R 6 is hydrogen or C 1 -C 16 alkyl, at least one R 1 is ##STR23##
Claim 3
Dependent Claim
13 words
The oligomer of claim 1 wherein Y and Y 1 are each ##STR24##
Claim 4
Dependent Claim
13 words
The oligomer of claim 1 wherein Y and Y 1 are each ##STR25##
Claim 5
Dependent Claim
11 words
The oligomer of claim 1 wherein R is --CH 3 .
Claim 6
Dependent Claim
17 words
The oligomer of claim 1 wherein R 1 is selected from CH 3 O--, t-octylamino, and (2,2,6,6-tetramethyl-4-piperidinyl)imino.
Claim 7
Dependent Claim
13 words
The oligomer of claim 1 wherein X is C 2 -C 18 alkylene.
Claim 8
Dependent Claim
11 words
The oligomer of claim 1 wherein --Y--X--Y 1 -- is ##STR26##
Claim 9
Dependent Claim
10 words
The oligomer of claim 1 wherein X 1 is ##STR27##
Claim 10
Dependent Claim
32 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of an oligomer of claim 1.
Claim 11
Dependent Claim
28 words
The method of claim 9 wherein the oligomer is incorporated in a concentration of from about 0.2 to 2% by weight based on the weight of the polymer.
Claim 12
Dependent Claim
11 words
The method of claim 7 wherein the polymer is a polyolefin.
Claim 13
Dependent Claim
10 words
The method of claim 11 wherein the polyolefin is polypropylene.
Claim 14
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 2.
Claim 15
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 3.
Claim 16
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 4.
Claim 17
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 5.
Claim 18
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 6.
Claim 19
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 7.
Claim 20
Dependent Claim
13 words
The method of claim 9 wherein the oligomer is that of claim 8.
Claim 21
Dependent Claim
20 words
The compositions produced by the method of claims 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, or 19.
References Cited (Backward Citations)
US4234728A
Cited
US4294963A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-24 | 1987-04-25 | 1987-10-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-24 | 1991-04-25 | 1991-10-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-24 | 1995-04-25 | 1995-10-25 | $7700.00 | Window Closed / Lapsed |