US4356287A
Expired / Lapsed
US
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Novel polymeric light stabilizers for polymers
Assignee: Wyeth Holdings LLC
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Filing: 1981-07-20
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Granted: 1982-10-26
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Expires: 2001-07-20
Abstract
Abstract Polymers of the following monomer ##STR1## wherein R and/or R 1 contains a polymerizable double bond are disclosed as light stabilizers for polymers.
Inventors
- 👤 Frank F. Loffelman
- 👤 Thomas E. Brady
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 10:07
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36; C08F20/52; C08F20/54; C08F20/60; C08F26/00; C08F26/06; C08L; C08L101/00
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
245 words
A polymer prepared by the polymerization of a monomer, represented by formula (I) ##STR10## wherein R represents C 3 -C 6 alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR11## wherein R 2 , R 3 , R 4 , R 5 , and R 6 are as defined below, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, piperidino, pyrrolidyl, a substituted C 1 -C 18 alkylamino, or a substituted C 1 -C 18 dialkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the groups ##STR12## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or ##STR13## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; X is oxy, or ##STR14## wherein R 6 is as previously defined.
Claim 2
Dependent Claim
245 words
A polymer prepared by the polymerization of a monomer, represented by formula (I) ##STR10## wherein R represents C 3 -C 6 alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR11## wherein R 2 , R 3 , R 4 , R 5 , and R 6 are as defined below, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, piperidino, pyrrolidyl, a substituted C 1 -C 18 alkylamino, or a substituted C 1 -C 18 dialkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the groups ##STR12## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or ##STR13## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; X is oxy, or ##STR14## wherein R 6 is as previously defined.
Claim 3
Dependent Claim
10 words
The polymer of claim 1 wherein R 1 is ##STR15##
Claim 4
Dependent Claim
10 words
The polymer of claim 1 wherein R 1 is ##STR16##
Claim 5
Dependent Claim
11 words
The monomer of claim 1 wherein R is (CH.sub.2 ═CH--CH.sub.2).sub.2 N--
Claim 6
Dependent Claim
11 words
The monomer of claim 1 wherein R is CH.sub.2 ═CH--CH.sub.2 O--
Claim 7
Dependent Claim
20 words
The polymer of claims 1, 4 or 5 wherein R 1 is selected from t-octylamino, methoxy, dialkylamino, alkoxy, and ##STR17##
Claim 8
Dependent Claim
32 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a polymer of claim 1.
Claim 9
Dependent Claim
26 words
The method of claim 7 wherein the stabilizer is incorporated in a concentration of from about 0.2% to 2% based on the weight of the polymer.
Claim 10
Dependent Claim
11 words
The method of claim 7 wherein the polymer is a polyolefin.
Claim 11
Dependent Claim
10 words
The method of claim 9 wherein the polyolefin is polypropylene.
Claim 12
Dependent Claim
18 words
The method of claim 7 wherein the stabilizer polymer is that of claims 2, 3, 4 or 5.
Claim 13
Dependent Claim
13 words
The composition produced by the method of claims 7, 8, 9 or 10.
References Cited (Backward Citations)
US4108829A
Cited
US4210612A
Cited
US4292237A
Cited
US4294963A
Cited
US4276401A
Cited
US4288593A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1985-10-25 | 1986-04-26 | 1986-10-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-25 | 1990-04-26 | 1990-10-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-25 | 1994-04-26 | 1994-10-26 | $7700.00 | Window Closed / Lapsed |