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US4400505A Expired / Lapsed US ⏱️ 0.0 years remaining

Triazinyl-piperidines as light stabilizers for polymers

Assignee: Wyeth Holdings LLC
•
Filing: 1981-07-20
•
Granted: 1983-08-23
•
Expires: 2001-07-20
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Abstract

Abstract Compounds of the formula ##STR1## wherein at least one of the groups contains a 4-piperidinyl moiety are disclosed as light stabilizers for polymers.

Inventors

  • 👤 Frank F. Loffelman
  • 👤 Thomas E. Brady

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 10:28
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 332 words
A compound of the formula (I) ##STR14## wherein R represents C 3 -C 6 alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, ##STR15## wherein R 2 , R 3 , R 4 , R 5 , and R 6 are as defined below, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, piperidino, pyrrolidyl, a substituted C 1 -C 18 alkylamino, or a substituted C 1 -C 18 dialkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the groups ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached from a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or ##STR17## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; Y and Y 1 , which may be the same, or different, represent oxy, or ##STR18## wherein R 6 is as previously defined; X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxy, thio, or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that when Y and Y' are oxy, or R 6 is hydrogen, or C 1 -C 8 alkyl, at least one R 1 is, or contains ##STR21## and with the further proviso that R and R 1 are not allyloxy at the same time.
Claim 2
Dependent Claim 332 words
A compound of the formula (I) ##STR14## wherein R represents C 3 -C 6 alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, ##STR15## wherein R 2 , R 3 , R 4 , R 5 , and R 6 are as defined below, C 1 -C 18 alkylamino, C 1 -C 18 dialkylamino, morpholino, piperidino, pyrrolidyl, a substituted C 1 -C 18 alkylamino, or a substituted C 1 -C 18 dialkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the groups ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached from a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or ##STR17## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; Y and Y 1 , which may be the same, or different, represent oxy, or ##STR18## wherein R 6 is as previously defined; X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxy, thio, or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that when Y and Y' are oxy, or R 6 is hydrogen, or C 1 -C 8 alkyl, at least one R 1 is, or contains ##STR21## and with the further proviso that R and R 1 are not allyloxy at the same time.
Claim 3
Dependent Claim 13 words
The compound of claim 1 wherein Y and Y 1 are each ##STR22##
Claim 4
Dependent Claim 20 words
The compound of claim 1 wherein X is (CH 2 ) 6 and Y and Y 1 are each ##STR23##
Claim 5
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is diallylamino and R 1 is diallylamino.
Claim 6
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is diallylamino and R 1 is methoxy.
Claim 7
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is diallylamino and R 1 is t-octylamino.
Claim 8
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is alkyloxy and R 1 is t-octylamino.
Claim 9
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is allylamino and R 1 is t-octylamino.
Claim 10
Dependent Claim 16 words
The compound of claim 1 or 3 wherein R is allylamino and R 1 is allylamino.

References Cited (Backward Citations)

US4086204A Cited
US4263434A Cited
US4294963A Cited
US4315859A Cited
US4297492A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-22 1987-02-21 1987-08-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-22 1991-02-21 1991-08-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-22 1995-02-21 1995-08-23 $7700.00 Window Closed / Lapsed

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