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US4767518A Expired / Lapsed US ⏱️ 0.0 years remaining

Cermet electrode

Assignee: Siemens Energy Inc
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Filing: 1986-06-11
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Granted: 1988-08-30
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Expires: 2006-06-11
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Abstract

Abstract Disclosed is a cermet electrode consisting of metal particles of nickel, cobalt, iron, or alloys or mixtures thereof immobilized by zirconia stabilized in cubic form which contains discrete deposits of about 0.1 to about 5% by weight of praseodymium, dysprosium, terbium, or a mixture thereof. The solid oxide electrode can be made by covering a substrate with particles of nickel, cobalt, iron, or mixtures thereof, growing a stabilized zirconia solid oxide skeleton around the particles thereby immobilizing them, contacting the skeleton with a compound of praseodymium, dysprosium, terbium, or a mixture thereof, and heating the skeleton to a temperature of at least 500° C. The electrode can also be made by preparing a slurry of nickel, cobalt, iron, or mixture and a compound of praseodymium, dysprosium, terbium, or a mixture thereof, depositing the slurry on a substrate, heating the slurry to dryness, and growing a stabilized zirconia skeleton around the metal particles.

Inventors

  • 👤 Nicholas J. Maskalick

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 10:56
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/86; H01M4/90; H01M4/9041; H01M4/905; H01M4/9066; C; C25; C25B; C25B11/00; C25B11/04; C25B11/042; C25B11/047; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 81 words
A cermet electrode comprising: (A) metal particles selected from the group consisting of nickel, cobalt, iron, and mixtures thereof; (B) zirconia stabilized with yttria in cubic form immobilizing said metal particles; and (C) discrete deposits of an oxide selected from the group consisting of praseodymium oxide, dysprosium oxide, terbium oxide, and mixtures thereof, where the amount of praseodymium, dysprosium, and terbium in said discrete deposits is from about 0.1% to about 5% by weight of the weight of said cermet electrode.
Claim 2
Dependent Claim 81 words
A cermet electrode comprising: (A) metal particles selected from the group consisting of nickel, cobalt, iron, and mixtures thereof; (B) zirconia stabilized with yttria in cubic form immobilizing said metal particles; and (C) discrete deposits of an oxide selected from the group consisting of praseodymium oxide, dysprosium oxide, terbium oxide, and mixtures thereof, where the amount of praseodymium, dysprosium, and terbium in said discrete deposits is from about 0.1% to about 5% by weight of the weight of said cermet electrode.
Claim 3
Dependent Claim 13 words
A cermet electrode according to claim 1 wherein said metal particles are nickel.
Claim 4
Dependent Claim 13 words
A cermet electrode according to claim 1 wherein said oxide is praseodymium oxide.
Claim 5
Dependent Claim 29 words
A ceramic oxide cell comprising a ceramic oxide electrolyte having a ceramic oxide air electrode on one side and a cermet electrode according to claim 1 on the other.
Claim 6
Dependent Claim 34 words
A ceramic oxide cell according to claim 4 in the shape of a tube with an air electrode on the inside of said tube and said cermet electrode on the outside of said tube.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-30 1992-02-29 1992-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-30 1996-02-29 1996-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-30 2000-02-29 2000-08-30 $7700.00 Window Closed / Lapsed

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