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US4752634A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat resistant hot melt precoat and adhesive compositions

Assignee: Hercules LLC
•
Filing: 1986-04-17
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Granted: 1988-06-21
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Expires: 2006-04-17
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Abstract

Abstract Disclosed are hot melt compositions having good resistance to flow at temperatures up to 100° C. The compositions are homogenous blends, which consist essentially of (1) an ethylene--mono-unsaturated ester copolymer having a melt index from 2 to about 20, or an ethylene terpolymer having a melt index of from about 6 to about 20; (2) a heat resistant polymer having a crystalline melting point greater than 109° C.; (3) a tackifier resin having a Ring and Ball (R&B) softening point of from about 85° C. to about 110° C.; and (4) a hydrocarbon wax. When the tackifier resin has a R&B softening point of 100° C. to about 110° C., a naphthenic oil must also be added. The compositions may also contain a finely divided inorganic filler when used as an adhesive to produce pile fabrics or for backcoating the primary backing of a tufted carpet. The compositions are useful in the manufacture of carpets.

Inventors

  • 👤 Raymond W. Goss

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:04
CPC Classifications
C; C09; C09D; C09D123/00; C09D123/02; C09D123/10; C09D123/04; C09D123/08; C09D123/18; C09D123/20

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 236 words
A composition having a Brookfield viscosity of from about 10,000 to about 200,000 centipoise at from about 140° C. to about 180° C., comprising by weight: (1) from 10 parts to about 40 parts of an ethylene polymer selected from the group consisting of (i) an ethylene copolymer having a melt index from 2 to about 50, and, by weight of the copolymer, an ethylene content of from about 67% to about 82% and a mono-unsaturated ester content of from about 33% to about 18%, and (ii) an ethylene terpolymer having a melt index of from about 6 to about 20, and, by weight of the terpolymer, from about 74% to about 76% ethylene, from about 23% to about 26% vinyl ester, and from about 1% to about 3% of a termonomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, acrylamide, beta dimethylaminoethyl methacrylate, beta hydroxyethyl acrylate, diallyl maleate, diallyl phthalate, diallyl ether and ethylene glycol dimethacrylate; (2) from 10 parts to about 30 parts of a heat-resistant polymer having a crystalline melting point greater than 109° C. selected from the group consisting of polybutylene and propylene-butylene copolymer (3) from about 30 parts to about 50 parts of a tackifier resin having a Ring and Ball softening point of from about 85° C. up to about 110° C.; and (4) from about 1 part to about 5 parts of a hydrocarbon wax.
Claim 2
Dependent Claim 236 words
A composition having a Brookfield viscosity of from about 10,000 to about 200,000 centipoise at from about 140° C. to about 180° C., comprising by weight: (1) from 10 parts to about 40 parts of an ethylene polymer selected from the group consisting of (i) an ethylene copolymer having a melt index from 2 to about 50, and, by weight of the copolymer, an ethylene content of from about 67% to about 82% and a mono-unsaturated ester content of from about 33% to about 18%, and (ii) an ethylene terpolymer having a melt index of from about 6 to about 20, and, by weight of the terpolymer, from about 74% to about 76% ethylene, from about 23% to about 26% vinyl ester, and from about 1% to about 3% of a termonomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, acrylamide, beta dimethylaminoethyl methacrylate, beta hydroxyethyl acrylate, diallyl maleate, diallyl phthalate, diallyl ether and ethylene glycol dimethacrylate; (2) from 10 parts to about 30 parts of a heat-resistant polymer having a crystalline melting point greater than 109° C. selected from the group consisting of polybutylene and propylene-butylene copolymer (3) from about 30 parts to about 50 parts of a tackifier resin having a Ring and Ball softening point of from about 85° C. up to about 110° C.; and (4) from about 1 part to about 5 parts of a hydrocarbon wax.
Claim 3
Dependent Claim 23 words
The composition of claim 1 wherein component (1) is an ethylene-mono-unsaturated ester copolymer having a melt index of about 25 to about 30.
Claim 4
Dependent Claim 43 words
The composition of claim 1 wherein the component (1) is a member selected from the group consisting of a vinyl ester of C 1-4 carboxylic acid, a C 1-5 alkyl ester of acrylic acid, and a C 1-5 alkyl ester of methacrylic acid.
Claim 5
Dependent Claim 12 words
The composition of claim 1 wherein component (1) is an ethylene terpolymer.
Claim 6
Dependent Claim 11 words
The composition of claim 1 wherein component (2) is a polybutylene.
Claim 7
Dependent Claim 12 words
The composition of claim 1 wherein component (2) is a propylene-butylene copolymer.
Claim 8
Dependent Claim 55 words
The composition of claim 1 wherein component (3) is a member selected from the group consisting of rosin, an ester of rosin and an aliphatic hydrocarbon resin prepared by polymerizing (i) a non-terpenic C 4-9 unsaturated hydrocarbon monomers or (ii) an unsaturated hydrocarbon monomer obtained from a petroleum refining stream; terpene resin; and mixtures thereof.
Claim 9
Dependent Claim 31 words
A composition of claim 1 having a Brookfield viscosity of from about 20,000 to about 200,000 centipoise and containing from about 6 parts to about 12 parts of a softening agent.
Claim 10
Dependent Claim 73 words
The composition of claim 1 wherein component (1) is present in an amount of from about 10 parts to about 20 parts; component (2) is present in an amount of from about 14 parts to about 30 parts; component (3) is present in an amount of from about 32 parts to about 47 parts; and component (4) is present in an amount of from about 3 parts to about 4.2 parts by weight.
Claim 11
Dependent Claim 22 words
The composition of claim 9 containing a naphthene oil present in an amount of from about 7.5 parts to about 9 parts.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-06-21 1991-12-21 1992-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-06-21 1995-12-21 1996-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-06-21 1999-12-21 2000-06-21 $7700.00 Window Closed / Lapsed

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