Process for coating an object with a continuous coating of plastics film

Claim 1

A process for coating an object with a continuous coating of plastics film which consists of a pre-formed solid self-sealing tacky plastics film being brought into contact with an object, the film is stretched over the object and substantially all of the film made to adhere substantially permanently to the object, the film being made from a composition selected from the group consisting of: (a) A composition comprising (i) 90 to 99.95 wt.% of a copolymer of ethylene and a vinyl (or hydrocarbyl substituted vinyl) ester of a C 1 to C 30 monocarboxylic acid containing at least 89 wt.% of ethylene and either 0.05 to 10 wt.% of an amorphous hydrocarbon polymer having an average number molecular weight of not more than 3000 or 0.05 to 5 wt.% of liquid polyisobutylene or liquid polybutene or a combination of 0.05 to 10 wt.% of the hydrocarbon polymer and 0.05 to 5 wt.% of the polyisobutene or polybutene, provided the combined weight of hydrocarbon polymer and polyisobutene or polybutene is not more than 10 wt.%; (b) A composition comprising (i) 90 to 99.95 wt.% of a copolymer of ethylene and a vinyl (or hydrocarbyl substituted vinyl) ester of a C 1 to C 30 monocarboxylic acid (ii) either 0.05 to 10 wt.% of a hydrocarbon resin, or 0.05 to 5 wt.% of polybutene or polyisobutene or a combination of 0.05 to 10 wt.% of the hydrocarbon resin and 0.05 to 5 wt.% of polybutene or polyisobutene or a combination of 0.05 to 10 wt.% of the hydrocarbon resin and 0.05 to 5 wt.% of polybutene or polyisobutene provided the combined weight of the resin and polybutene or polyisobutene is not more than 10 wt.% and (iii) 0.01 to 3.0 wt.% based on the combined weight of (i) and (ii) of a partial carboxylic acid ester of a polyol; (c) A composition comprising (i) 95.0 to 99.9 wt.% of either a copolymer of ethylene and a vinyl (or hydrocarbyl substituted vinyl) ester of a C 1 to C 30 monocarboxylic acid, said copolymer containing 0.10 to 1.95 wt.% of the vinyl (or hydrocarbyl substituted vinyl) ester of 95.0 to 99.9 wt.% of a mixture of a thermoplastic polyolefin and a copolymer of ethylene and a vinyl (or hydrocarbyl substituted vinyl) ester of a C 1 to C 30 monocarboxylic acid, the proportion of polymerised vinyl (or hydrocarbyl substituted vinyl) ester in the mixture being from 0.10 to 1.95 wt.% and (ii) 0.01 to 5.0 wt.% of a partial ester of a carboxylic acid and a polyol; (d) A composition comprising (i) 85 to 99.8 wt.% of a thermoplastic polyolefin (ii) 0.1 to 10.0 wt.% of a partial ester of a carboxylic acid and a polyol and (iii) either 0.1 to 10 wt.% of a hydrogenated hydrocarbon resin or 0.1 to 10 wt.% of polybutene or polyisobutene, provided the combined weights of (ii) and (iii) is not more than 15 wt.%; and (e) A composition comprising 100 parts by weight of PVC, 10-20 parts by weight of plasticizer, 5-15 parts by weight of epoxidized soya bean oil and 0 to 5 parts by weight of a lubricant.