US4471086A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hot-melt adhesives for meat packaging and other low temperature applications
Assignee: HB Fuller Co
•
Filing: 1983-11-09
•
Granted: 1984-09-11
•
Expires: 2003-11-09
Abstract
Abstract The hot-melt adhesives of the present invention comprise a blend of at least one polyethylene, a tackifying resin, a high density, low viscosity polyethylene wax having a molecular weight of about 1000, and a Fischer-Tropsch hydrocarbon wax. This hot-melt adhesive has a novel combination of properties such as low viscosity and fast setting which meet the requirements necessary for use in rapid bonding or closing in low temperature applications.
Inventors
- 👤 Bruce W. Foster
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 15:29
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/06; C09J151/00; C09J151/06; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
231 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 65 to 45 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 18 to about 28 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 18 to about 28 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1 to 1:3.
Claim 2
Dependent Claim
231 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 65 to 45 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 18 to about 28 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 18 to about 28 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1 to 1:3.
Claim 3
Dependent Claim
44 words
A hot-melt adhesive composition according to claim 1 wherein said polyethylene is a modified polyethylene having a viscosity of 3800 cp. at 190° C., a density of 0.908 g./cc., a Ring and Ball softening point of 106° C. and a saponification number of 5.
Claim 4
Dependent Claim
45 words
A hot-melt adhesive composition according to claim 2 wherein said tackifier resin is a hydrocarbon tackifier resin having a density of 1.028 g./cc. at 21° C., a melt viscosity of 2150 cp. at 177° C., and a Ring and Ball softening point of 130° C.
Claim 5
Dependent Claim
231 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 60 to 50 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 to about 25 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 to about 25 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1 to 1:3.
Claim 6
Dependent Claim
231 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 60 to 50 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 to about 25 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 to about 25 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1 to 1:3.
Claim 7
Dependent Claim
44 words
A hot-melt adhesive composition according to claim 4 wherein said polyethylene is a modified polyethylene having a viscosity of 3800 cp. at 190° C., a density of 0.908 g./cc., a Ring and Ball softening point of 106° C. and a saponification number of 5.
Claim 8
Dependent Claim
45 words
A hot-melt adhesive composition according to claim 5 wherein said tackifier resin is a hydrocarbon tackifier resin having a density of 1.028 g./cc. at 21° C., a melt viscosity of 2150 cp. at 177° C., and a Ring and Ball softening point of 130° C.
Claim 9
Dependent Claim
221 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprisng a blend of (a) about 60 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1.
Claim 10
Dependent Claim
221 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprisng a blend of (a) about 60 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:1.
Claim 11
Dependent Claim
44 words
A hot-melt adhesive composition according to claim 7 wherein said polyethylene is a modified polyethylene having a viscosity of 3800 cp. at 190° C., a density of 0.908 g./cc., a Ring and Ball softening point of 106° C. and a saponification number of 5.
Claim 12
Dependent Claim
45 words
A hot-melt adhesive composition according to claim 8 wherein said tackifier resin is a hydrocarbon tackifier resin having a density of 1.028 g./cc. at 21° C., a melt viscosity of 2150 cp. at 177° C., and a Ring and Ball softening point of 130° C.
Claim 13
Dependent Claim
221 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 60 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:3.
Claim 14
Dependent Claim
221 words
A hot-melt adhesive composition having a viscosity of less than 1200 cp. at 177° C. and a cleavage set time of about 6 seconds or less which provides bonds having good low temperature properties comprising a blend of (a) about 60 percent by weight of at least one polyethylene having a melt viscosity of 500 to 20,000 centipoise at 190° C. and a density of greater than 0.90 to about 0.945 g./cc., (b) about 20 percent by weight of at least one tackifier resin selected from the group consisting of hydrocarbon resin and polyterpene resins having a Ring and Ball softening point of about 125° C. to about 135° C., and (c) about 20 percent by weight of a blend of (1) a high density, low viscosity polyethylene wax having a molecular weight of about 800 to 1200 and a Ring and Ball softening point in the range of 110° C. to 120° C. and (2) a Fischer-Tropsch wax having a DSC melting point in the range of 85° C. to 120° C., a molecular weight of about 600 to 800, a penetration hardness of about 1.5 at 23° C. and a melt viscosity of about 10 to 4 cp. at 149° C., wherein said wax blend contains a ratio of high density polyethylene wax to Fischer-Tropsch wax of about 1:3.
Claim 15
Dependent Claim
44 words
A hot-melt adhesive composition according to claim 10 wherein said polyethylene is a modified polyethylene having a viscosity of 3800 cp. at 190° C., a density of 0.908 g./cc., a Ring and Ball softening point of 106° C. and a saponification number of 5.
Claim 16
Dependent Claim
45 words
A hot-melt adhesive composition according to claim 11 wherein said tackifier resin is a hydrocarbon tackifier resin having a density of 1.028 g./cc. at 21° C., a melt viscosity of 2150 cp. at 177° C., and a Ring and Ball softening point of 130° C.
References Cited (Backward Citations)
US3280062A
Cited
US3243395A
Cited
US3243396A
Cited
US3366589A
Cited
US3660336A
Cited
US4070316A
Cited
US4127619A
Cited
US4146521A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-11 | 1988-03-12 | 1988-09-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-11 | 1992-03-12 | 1992-09-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-11 | 1996-03-12 | 1996-09-11 | $7700.00 | Window Closed / Lapsed |