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US4076670A Expired / Lapsed US ⏱️ 0.0 years remaining

Hot-melt adhesives having improved properties at elevated temperatures

Assignee: Eastman Chemical Co
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Filing: 1977-01-27
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Granted: 1978-02-28
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Expires: 1997-01-27
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Abstract

Abstract The hot melt adhesives of the present invention comprise a blend of polyethylene, tackifying resin, and crystalline propylene containing polymer. These hot melt adhesive compositions have a novel combination of properties including high strength at elevated temperatures and pressures and resistance to creep.

Inventors

  • 👤 Darryl A. Godfrey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:30
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/06; C09J123/10; C08; C08L; C08L2666/00; C08L2666/02

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 108 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 30 to 70 weight percent polyethylene having a melt index at 190° C. of about 1 to about 50 and a density of about 0.910 g/cm 3 to about 0.940 g/cm 3 (2) 10 to 50 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters, and (3) 10 to 40 weight percent crystalline polypropylene or crystalline propylene/ethylene copolymers containing not more than 20 percent by weight ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 2
Dependent Claim 108 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 30 to 70 weight percent polyethylene having a melt index at 190° C. of about 1 to about 50 and a density of about 0.910 g/cm 3 to about 0.940 g/cm 3 (2) 10 to 50 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters, and (3) 10 to 40 weight percent crystalline polypropylene or crystalline propylene/ethylene copolymers containing not more than 20 percent by weight ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 3
Dependent Claim 37 words
An adhesive composition according to claim 1 wherein said polyethylene has a melt index at 190° C. of about 1 to about 50 and a density of about 0.920 g/cm 3 to about 0.930 g/cm 3 .
Claim 4
Dependent Claim 23 words
An adhesive composition according to claim 2 wherein said tackifying resin is hydrocarbon resin having a softening point of at least 100° C.
Claim 5
Dependent Claim 24 words
An adhesive composition according to claim 2 wherein said tackifying resin is a polyterpene resin having a softening point of at least 100° C.
Claim 6
Dependent Claim 36 words
An adhesive composition according to claim 2 wherein said crystalline polypropylene or crystalline propylene/ethylene copolymers containing not more than 20 percent ethylene by weight has a melt flow rate at 230° C. of 120 to 180.
Claim 7
Dependent Claim 108 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 10 to about 30 and a density of about 0.920 g/cm 3 to about 0.930 g/cm 3 , (2) 20 to 40 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline polypropylene having a melt flow rate at 230° C. of 30 to 180.
Claim 8
Dependent Claim 108 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 10 to about 30 and a density of about 0.920 g/cm 3 to about 0.930 g/cm 3 , (2) 20 to 40 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline polypropylene having a melt flow rate at 230° C. of 30 to 180.
Claim 9
Dependent Claim 23 words
An adhesive composition according to claim 6 wherein said tackifying resin is hydrocarbon resin having a softening point of at least 120° C.
Claim 10
Dependent Claim 24 words
An adhesive composition according to claim 6 wherein said tackifying resin is a polyterpene resin having a softening point of at least 120° C.
Claim 11
Dependent Claim 23 words
An adhesive composition according to claim 6 wherein said crystalline polypropylene has a melt flow rate at 230° C. of 120 to 180.
Claim 12
Dependent Claim 98 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 20 and a density of about 0.925 g/cm 3 , (2) 30 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline polypropylene having a melt flow rate at 230° C. of 30 to 180.
Claim 13
Dependent Claim 98 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 20 and a density of about 0.925 g/cm 3 , (2) 30 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline polypropylene having a melt flow rate at 230° C. of 30 to 180.
Claim 14
Dependent Claim 23 words
An adhesive composition according to claim 10 wherein said tackifying resin is hydrocarbon resin having a softening point of at least 120° C.
Claim 15
Dependent Claim 24 words
An adhesive composition according to claim 10 wherein said tackifying resin is a polyterpene resin having a softening point of at least 120° C.
Claim 16
Dependent Claim 23 words
An adhesive composition according to claim 10 wherein said crystalline polypropylene has a melt flow rate at 230° C. of 120 to 180.
Claim 17
Dependent Claim 114 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 10 to about 30 and a density of about 0.920 g/cm 3 to about 0.930 g/cm 3 , (2) 20 to 40 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline ethylene/propylene copolymer containing 1.4 weight percent ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 18
Dependent Claim 114 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 10 to about 30 and a density of about 0.920 g/cm 3 to about 0.930 g/cm 3 , (2) 20 to 40 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline ethylene/propylene copolymer containing 1.4 weight percent ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 19
Dependent Claim 23 words
An adhesive composition according to claim 14 wherein said tackifying resin is hydrocarbon resin having a softening point of at least 120° C.
Claim 20
Dependent Claim 24 words
An adhesive composition according to claim 14 wherein said tackifying resin is a polyterpene resin having a softening point of at least 120° C.
Claim 21
Dependent Claim 29 words
An adhesive composition according to claim 14 wherein said crystalline ethylene/propylene copolymer containing 1.4 weight percent ethylene has a melt flow rate at 230° C. of 120 to 180.
Claim 22
Dependent Claim 107 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 20 and a density of about 0.925 g/cm 3 , (2) 30 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline ethylene/propylene copolymer containing not more than 20 weight percent ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 23
Dependent Claim 107 words
An adhesive composition capable of being used as a hot melt adhesive comprising a blend of (1) 35 to 45 weight percent polyethylene having a melt index at 190° C. of about 20 and a density of about 0.925 g/cm 3 , (2) 30 weight percent of at least one tackifying resin selected from the group consisting of hydrocarbon resins, polyterpene resins, and rosin esters having a ring and ball softening point of at least 100° C., and (3) 25 to 35 weight percent crystalline ethylene/propylene copolymer containing not more than 20 weight percent ethylene having a melt flow rate at 230° C. of 30 to 180.
Claim 24
Dependent Claim 23 words
An adhesive composition according to claim 18 wherein said tackifying resin is hydrocarbon resin having a softening point of at least 120° C.
Claim 25
Dependent Claim 24 words
An adhesive composition according to claim 18 wherein said tackifying resin is a polyterpene resin having a softening point of at least 120° C.
Claim 26
Dependent Claim 29 words
An adhesive composition according to claim 18 wherein said crystalline ethylene/propylene copolymer containing 1.4 weight percent ethylene has a melt flow rate at 230° C. of 120 to 180.

References Cited (Backward Citations)

US3478131A Cited
US3492372A Cited
US3846349A Cited
US4022728A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-27 1981-08-29 1982-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-27 1985-08-29 1986-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-27 1989-08-29 1990-02-28 $7700.00 Window Closed / Lapsed

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