US4367113A
Expired / Lapsed
US
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Multicomponent polymer compositions
Assignee: Chevron USA Inc
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Filing: 1981-06-29
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Granted: 1983-01-04
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Expires: 2001-06-29
Abstract
Abstract Compatible blends of polymers are disclosed which contain (a) a high density ethylene polymer or an isotactic propylene polymer, (b) a copolymer of ethylene and an alkyl ester of acrylic or methacrylic acid or vinyl acetate, (c) an ionomer resin, and (d) a tackifying resin such as a terpene resin.
Inventors
- 👤 Khalid A. Karim
- 👤 Pallavoor R. Lakshmanan
- 👤 James H. Rea
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 11:30
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/06; B; B32; B32B; B32B27/00; B32B27/04; C08L23/10; B32B37/00; B32B37/12; B32B37/1207; B32B2037/1215; B32B2311/00; B32B2311/12; B32B2311/24; B32B2325/00; C08L2205/00; C08L2205/03; C08L2205/035; C08L23/08; C08L23/0846; C08L23/0869; C08L23/0876; C08L25/00; C08L25/02; C08L25/04; C08L25/06; C08L25/16; C08L57/00; C08L57/02; C08L57/06; C08L57/10; C08L61/00; C08L61/04; C08L61/06; C08L93/00; C08L93/04; Y; Y10; Y10S; Y10S264/00; Y10S264/57; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906; Y10T428/31938
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
320 words
A compatible blend of polymers consisting essentially of: (a) an olefin polymer, (b) an ethylene copolymer, (c) an ionomer resin, and (d) a tackifying resin; said olefin polymer being a polymer comprising polymerized ethylene with any comonomer polymerized therewith being a C 3 or higher alpha-olefin and having a density of at least about 0.95 gram/ml or an isotactic propylene polymer; said ethylene copolymer having polymerized therein about 70 to 90 weight % of ethylene and the balance an alkyl ester of acrylic or methacrylic acid or vinyl acetate; said ionomer resin having a high load melt index of at least about 1.0 and a normal load melt index of up to about 50, and being a metal salt of an ethylene-acid copolymer which is a copolymer of ethylene and acrylic or methacrylic acid having an acid content of about 1-10 mol %; and said tackifying resin being selected from the group consisting of: (a) terpene resins having a Ring and Ball softening point of about 10°-150° C., (b) aliphatic hydrocarbon resins having a Ring and Ball softening point of about 10°-135° C., (c) rosin esters having a Ring and Ball softening point of about 65°-140° C., (d) alpha-methylstyrene/vinyl toluene copolymers having a Ring and Ball softening point of about 75°-120° C., (e) polystyrene resins having a Ring and Ball softening point of about 25°-100° C., and (f) terpene-phenolic resins having a Ring and Ball softening point of about 80°-135° C.; and (g) rosin, said composition containing the olefin polymer and the ethylene copolymer in the combined amount of 100 parts by weight and containing the ionomer resin and the tackifying resin in the combined amount of about 15-200 parts by weight; and the olefin polymer and the ethylene copolymer being present in proportions such that the alkyl ester or vinyl acetate moiety of the ethylene copolymer constitutes about 4-12 weight % of the total weight of said two polymers.
Claim 2
Dependent Claim
320 words
A compatible blend of polymers consisting essentially of: (a) an olefin polymer, (b) an ethylene copolymer, (c) an ionomer resin, and (d) a tackifying resin; said olefin polymer being a polymer comprising polymerized ethylene with any comonomer polymerized therewith being a C 3 or higher alpha-olefin and having a density of at least about 0.95 gram/ml or an isotactic propylene polymer; said ethylene copolymer having polymerized therein about 70 to 90 weight % of ethylene and the balance an alkyl ester of acrylic or methacrylic acid or vinyl acetate; said ionomer resin having a high load melt index of at least about 1.0 and a normal load melt index of up to about 50, and being a metal salt of an ethylene-acid copolymer which is a copolymer of ethylene and acrylic or methacrylic acid having an acid content of about 1-10 mol %; and said tackifying resin being selected from the group consisting of: (a) terpene resins having a Ring and Ball softening point of about 10°-150° C., (b) aliphatic hydrocarbon resins having a Ring and Ball softening point of about 10°-135° C., (c) rosin esters having a Ring and Ball softening point of about 65°-140° C., (d) alpha-methylstyrene/vinyl toluene copolymers having a Ring and Ball softening point of about 75°-120° C., (e) polystyrene resins having a Ring and Ball softening point of about 25°-100° C., and (f) terpene-phenolic resins having a Ring and Ball softening point of about 80°-135° C.; and (g) rosin, said composition containing the olefin polymer and the ethylene copolymer in the combined amount of 100 parts by weight and containing the ionomer resin and the tackifying resin in the combined amount of about 15-200 parts by weight; and the olefin polymer and the ethylene copolymer being present in proportions such that the alkyl ester or vinyl acetate moiety of the ethylene copolymer constitutes about 4-12 weight % of the total weight of said two polymers.
Claim 3
Dependent Claim
21 words
A composition of claim 1 in which the tackifying resin is present in an amount in excess of the ionomer resin.
Claim 4
Dependent Claim
38 words
A composition of claim 2 in which the tackifying resin is present in an amount not in excess of about 100 parts per weight per 100 parts of combined weight of said olefin polymer and said ethylene copolymer.
Claim 5
Dependent Claim
18 words
A composition of claim 2 in which the ethylene copolymer is a copolymer of ethylene and methyl acrylate.
Claim 6
Dependent Claim
18 words
A composition of claim 2 in which the ethylene copolymer is a copolymer of ethylene and ethyl acrylate.
Claim 7
Dependent Claim
18 words
A composition of claim 2 in which the ethylene copolymer is a copolymer of ethylene and vinyl acetate.
Claim 8
Dependent Claim
20 words
A composition of claim 2 in which the ionomer resin is a partial alkali metal salt of the ethylene-acid copolymer.
Claim 9
Dependent Claim
45 words
A composition of claim 1, 2, 3, 4, 5, 6, or 7 in which the olefin polymer is a polymer comprising polymerized ethylene with any comonomer polymerized therewith being a C 3 or higher alpha-olefin and having a density of at least about 0.95 gram/ml.
Claim 10
Dependent Claim
22 words
A composition of claim 1, 2, 3, 4, 5, 6, or 7 in which the olefin polymer is an isotactic propylene polymer.
Claim 11
Dependent Claim
59 words
A laminated sheet construction containing first and third laminae intimately fusion-bonded to a second lamina; each of said first and third laminae sheet being independently fabricated from paper, aluminum, copper, an ethylene homopolymer, an ethylene-vinyl alcohol copolymer, an isotactic propylene polymer, or a polyethylene terephthalate polyester; and said second lamina being fabricated from a polymer composition of claim 1.
Claim 12
Dependent Claim
86 words
In an adhesive method for bonding together two articles having surfaces of paper, aluminum, copper, and ethylene homopolymer, an ethylene-vinyl alcohol copolymer, an isotactic propylene polymer or a polyethylene terephthalate polyester in which a hot melt adhesive heated above its melting point is placed between the surfaces to be bonded together, said surfaces are assembled together and the assembly is cooled to ambient temperature to solidify such adhesive; the improvement which consists essentially of employing as the hot melt adhesive a polymer composition of claim 1.
Claim 13
Dependent Claim
121 words
In a coextrusion process for preparing a composite polymer film construction having polymers in the two surface layers which are fusion-bonded to each other by an intermediate polymer layer in which three polymer streams are fed into three channels of a film die, and the three polymer streams flow into the film die and are extruded to form an extrudate in which the three polymer streams form a film having three fusion-bonded layers; the improvement which consists of employing an ethylene homopolymer, an ethylene-vinyl alcohol copolymer, an isotactic propylene polymer, or a polyethylene terephthalate polyester as the polymer to form each of the two surface layers and employing a polymer composition of claim 1 and to form the intermediate polymer layer.
Claim 14
Dependent Claim
40 words
A composition of claim 1 in which the ionomer resin and the tackifying resin are present in the combined amount of about 20-100 parts by weight per 100 parts of combined weight of the olefin polymer and the ethylene copolymer.
Claim 15
Dependent Claim
26 words
A composition of claim 13 in which the ionomer resin and the tackifying resin are present in the combined amount of about 30-75 parts by weight.
Claim 16
Dependent Claim
17 words
A composition of claim 1, 2, or 14 in which the tackifying resin is a terpene resin.
Claim 17
Dependent Claim
18 words
A composition of claim 1, 2, or 14 in which the tackifying resin is an aliphatic hydrocarbon resin.
Claim 18
Dependent Claim
17 words
A composition of claim 1, 2, or 14 in which the tackifying resin is a rosin ester.
Claim 19
Dependent Claim
18 words
A composition of claim 1, 2, or 14 in which the tackifying resin is an alpha-methylstyrene/vinyl toluene copolymer.
Claim 20
Dependent Claim
17 words
A composition of claim 1, 2, or 14 in which the tackifying resin is a polystyrene resin.
Claim 21
Dependent Claim
17 words
A composition of claim 1, 2, or 14 in which the tackifying resin is a terpene-phenolic resin.
Claim 22
Dependent Claim
15 words
A composition of claim 1, 2, or 14 in which the tackifying resin is rosin.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-01-03 | 1986-07-05 | 1987-01-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-01-03 | 1990-07-05 | 1991-01-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-01-03 | 1994-07-05 | 1995-01-04 | $7700.00 | Window Closed / Lapsed |