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Fast fading photochromic glass

Assignee: Corning Glass Works
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Filing: 1986-02-10
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Granted: 1988-05-24
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Expires: 2006-02-10
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Abstract

Abstract This invention is directed to transparent photochromic glasses that can darken to a comfort range, i.e., between about 35-60%, or to a dark range, i.e., below 35%, depending upon glass composition, and will exhibit a faded transmittance after five minutes' removal from actinic radiation higher than 70%. The base compositions of the glasses consist essentially, in weight percent, of about ______________________________________ SiO 2 46-60 MgO 0-3.5 B 2 O 3 16-28 CaO 0-6 Al 2 O 3 4-11 SrO 0-6 ZrO 2 2-6 BaO 0-6 Al 2 O 3 + ZrO 2 6-13 MgO + CaO + SrO + BaO 0-7 Li 2 O 2-5 P 2 O 5 0-5 Na 2 O 0-4 TiO 2 0-3 K 2 O 2.5-9 ______________________________________ For a comfort glass the photochromic elements consist essentially, as analyzed, of______________________________________Ag 0.13-0.18 Br 0.08-0.14Cl 0.16-0.34 CuO 0.001-0.004______________________________________ For a dark glass the photochromic elements consist essentially, as analyzed, of______________________________________Ag 0.15-0.3 Br 0.07-0.14Cl 0.2-0.45 CuO 0.004-0.016______________________________________

Inventors

  • 👤 Jean-Pierre Mazeau
  • 👤 Michel Prassas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 15:51
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/04; C03C4/06; C03C3/00; C03C3/04; C03C3/076; C03C3/089; C03C3/091; C03C3/093; C03C3/097; C03C3/11; C03C3/112; C03C3/115; C03C3/118

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 221 words
A transparent, comfort photochromic glass which, in bodies of 2 mm cross section, will exhibit the following optical properties: (a) a clear (undarkened) luminous transmittance higher than 88%; (b) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation over the temperature range of 0°-25° C. higher than 35%, but less than 60%; (c) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at a temperature of 40° C. lower than 63%; and (d) a faded luminous transmittance after five minutes' removal from actinic radiation of at least 75%; said glass having a base composition consisting essentially, expressed in terms of weight percent on the oxide basis, of about ______________________________________ SiO.sub.2 46-60 MgO 0-3.5 B.sub.2 O.sub.3 16-28 CaO 0-6 Al.sub.2 O.sub.3 4-11 SrO 0-6 ZrO.sub.2 2-6 BaO 0-6 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-7 Li.sub.2 O 2-5 P.sub.2 O.sub.5 0-5 Na.sub.2 O 0-4 TiO.sub.2 0-3 K.sub.2 O 2.5-9 ______________________________________ and containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.13-0.18 Br 0.08-0.14 Cl 0.16-0.34 CuO 0.001-0.004 ______________________________________ said photochromic elements satisfying the ratios Br:(Cl+Br)≧0.24 and 0.25≦Ag:(Cl+Br)≦0.60 and wherein 6≦Al 2 O 3 +ZrO 2 ≦15, when the composition contains P 2 O 5 , and wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.4-0.8.
Claim 2
Dependent Claim 221 words
A transparent, comfort photochromic glass which, in bodies of 2 mm cross section, will exhibit the following optical properties: (a) a clear (undarkened) luminous transmittance higher than 88%; (b) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation over the temperature range of 0°-25° C. higher than 35%, but less than 60%; (c) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at a temperature of 40° C. lower than 63%; and (d) a faded luminous transmittance after five minutes' removal from actinic radiation of at least 75%; said glass having a base composition consisting essentially, expressed in terms of weight percent on the oxide basis, of about ______________________________________ SiO.sub.2 46-60 MgO 0-3.5 B.sub.2 O.sub.3 16-28 CaO 0-6 Al.sub.2 O.sub.3 4-11 SrO 0-6 ZrO.sub.2 2-6 BaO 0-6 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-7 Li.sub.2 O 2-5 P.sub.2 O.sub.5 0-5 Na.sub.2 O 0-4 TiO.sub.2 0-3 K.sub.2 O 2.5-9 ______________________________________ and containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.13-0.18 Br 0.08-0.14 Cl 0.16-0.34 CuO 0.001-0.004 ______________________________________ said photochromic elements satisfying the ratios Br:(Cl+Br)≧0.24 and 0.25≦Ag:(Cl+Br)≦0.60 and wherein 6≦Al 2 O 3 +ZrO 2 ≦15, when the composition contains P 2 O 5 , and wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.4-0.8.
Claim 3
Dependent Claim 75 words
A photochromic glass according to claim 1 wherein said base composition consists essentially of about ______________________________________ SiO.sub.2 50-58 MgO 0-1 B.sub.2 O.sub.3 16-25 CaO 1-4 Al.sub.2 O.sub.3 6-9 SrO 0-4 ZrO.sub.2 2-5 BaO 0-4 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-4 Li.sub.2 O 2-4.5 P.sub.2 O.sub.5 0-3.5 Na.sub.2 O 0.4-3.5 TiO.sub.2 1-2.5 K.sub.2 O 4-8 ______________________________________ wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.45-0.75.
Claim 4
Dependent Claim 36 words
A photochromic glass according to claim 1 containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.13-0.165 Br 0.09-0.12 Cl 0.17-0.27 CuO 0.002-0.004 ______________________________________ said photochromic elements satisfying the ratios Br:(Cl+Br)≧0.30 and 0.25≦Ag:(Cl+Br)≦0.50.
Claim 5
Dependent Claim 14 words
A photochromic glass according to claim 1 also containing up to 4 ppm Pd.
Claim 6
Dependent Claim 217 words
A transparent, dark photochromic glass which, in bodies of 2 mm cross section, will exhibit the following optical properties: (a) a clear (undarkened) luminous transmittance higher than 88%; (b) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation over the temperature range of 0°-25° C. lower than 35%; (c) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at a temperature of 40° C. lower than 58%; and (d) a faded luminous transmittance after five minutes' removal from actinic radiation of at least 70%; said glass having a base composition consisting essentially, expressed in terms of weight percent on the oxide basis, of about ______________________________________ SiO.sub.2 46-60 MgO 0-3.5 B.sub.2 O.sub.3 16-28 CaO 0-6 Al.sub.2 O.sub.3 4-11 SrO 0-6 ZrO.sub.2 2-6 BaO 0-6 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-7 Li.sub.2 O 2-5 P.sub.2 O.sub.5 0-5 Na.sub.2 O 0-4 TiO.sub.2 0-3 K.sub.2 O 2.5-9 ______________________________________ and containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.15-0.3 Br 0.07-0.14 Cl 0.2-0.45 CuO 0.004-0.016 ______________________________________ said photochromic elements satisfying the ratios Br:(Cl+Br)≧0.24 and 0.25≦Ag:(Cl+Br)≦0.60 and wherein 6≦Al 2 O 3 +ZrO 2 ≦15, when the composition contains P 2 O 5 , and wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.4-0.8.
Claim 7
Dependent Claim 217 words
A transparent, dark photochromic glass which, in bodies of 2 mm cross section, will exhibit the following optical properties: (a) a clear (undarkened) luminous transmittance higher than 88%; (b) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation over the temperature range of 0°-25° C. lower than 35%; (c) a darkened luminous transmittance after 15 minutes' exposure to actinic radiation at a temperature of 40° C. lower than 58%; and (d) a faded luminous transmittance after five minutes' removal from actinic radiation of at least 70%; said glass having a base composition consisting essentially, expressed in terms of weight percent on the oxide basis, of about ______________________________________ SiO.sub.2 46-60 MgO 0-3.5 B.sub.2 O.sub.3 16-28 CaO 0-6 Al.sub.2 O.sub.3 4-11 SrO 0-6 ZrO.sub.2 2-6 BaO 0-6 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-7 Li.sub.2 O 2-5 P.sub.2 O.sub.5 0-5 Na.sub.2 O 0-4 TiO.sub.2 0-3 K.sub.2 O 2.5-9 ______________________________________ and containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.15-0.3 Br 0.07-0.14 Cl 0.2-0.45 CuO 0.004-0.016 ______________________________________ said photochromic elements satisfying the ratios Br:(Cl+Br)≧0.24 and 0.25≦Ag:(Cl+Br)≦0.60 and wherein 6≦Al 2 O 3 +ZrO 2 ≦15, when the composition contains P 2 O 5 , and wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.4-0.8.
Claim 8
Dependent Claim 75 words
A photochromic glass according to claim 5 wherein said base composition consists essentially of about ______________________________________ SiO.sub.2 50-58 MgO 0-1 B.sub.2 O.sub.3 16-25 CaO 1-4 Al.sub.2 O.sub.3 6-9 SrO 0-4 ZrO.sub.2 2-5 BaO 0-4 Al.sub.2 O.sub.3 + ZrO.sub.2 6-13 MgO + CaO + SrO + BaO 1-4 Li.sub.2 O 2-4.5 P.sub.2 O.sub.5 0-3.5 Na.sub.2 O 0.4-3.5 TiO.sub.2 1-2.5 K.sub.2 O 4-8 ______________________________________ wherein the cationic ratio Li 2 O:Li 2 O+Na 2 O+K 2 O=0.45-0.75.
Claim 9
Dependent Claim 27 words
A photochromic glass according to claim 5 containing photochromic elements, as analyzed in weight percent, of about ______________________________________ Ag 0.16-0.25 Br 0.07-0.13 Cl 0.2-0.35 CuO 0.0045-0.12 ______________________________________
Claim 10
Dependent Claim 14 words
A photochromic glass according to claim 5 also containing up to 4 ppm Pd.

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