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US4407966A Expired / Lapsed US ⏱️ 0.0 years remaining

Very fast fading photochromic glass

Assignee: Corning Glass Works
•
Filing: 1982-09-16
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Granted: 1983-10-04
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Expires: 2002-09-16
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Abstract

Abstract The present invention is directed to the preparation of photochromic glasses exhibiting a darkened luminous transmittance at 40° C. below 35% and a five-minute fading rate at 40° C. of at least 40 units of transmittance and a darkened transmittance at 25° C. below 25% and a five-minute fading rate at 25° C. of at least 35 units of transmittance. The glasses consist essentially, by weight, of: ______________________________________ SiO 2 56-60 Al 2 O 3 6-9 B 2 O 3 18-21 Li 2 O >2.5-3.5 Na 2 O 0.5-2.5 K 2 O 5-7 ZrO 2 3.75-5 PbO 0.1-0.15 Ag >0.15-0.25 Cl 0.2-0.35 Br 0.075-0.15 CuO 0.004-0.02 CeO 2 0-0.5 ______________________________________ wherein the levels of Ag, Br, Cl, and CuO represent values as analyzed in the glass.

Inventors

  • 👤 David J. Kerko
  • 👤 David L. Morse

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:51
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/04; C03C4/06; C03C3/00; C03C3/04; C03C3/076; C03C3/089; C03C3/091; C03C3/093

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 214 words
A photochromic glass composition consisting essentially, expressed in terms of weight percent on the oxide basis, with the levels of Ag, Br, Cl, and CuO representing values as analyzed in the glass, of ______________________________________ SiO.sub.2 56-60 Al.sub.2 O.sub.3 6-9 B.sub.2 O.sub.3 18-21 Li.sub.2 O >2.5-3.5 Na.sub.2 O 0.5-2.5 K.sub.2 O 5-7 ZrO.sub.2 3.75-5 PbO 0.1-0.15 Ag >0.15-0.25 Cl 0.2-0.35 Br 0.075-0.15 CuO 0.004-0.02 CeO.sub.2 0-0.5 ______________________________________ capable of being chemically strengthened to modulus of rupture values in excess of 35,000 psi with a depth of compression layer of at least 0.030 inch and demonstrating the following photochromic properties when present in cross section of about 1.5-3 mm; (a) a clear luminous transmittance of approximately 90% when free from added tint; (b) a darkened luminous transmittance at 40° C. below 35% when the glass is free from added tint and a fading rate at 40° C. such that after five minutes the luminous transmittance will have increased at least 40 percentage units; (b) a darkened luminous transmittance at 25° C. below 25% when the glass is free from added tint and a fading rate at 25° C. such that after five minutes the luminous transmittance will have increased at least 35 percentage units; and (c) a darkened luminous transmittance at 0° C. greater than 15%.
Claim 2
Dependent Claim 214 words
A photochromic glass composition consisting essentially, expressed in terms of weight percent on the oxide basis, with the levels of Ag, Br, Cl, and CuO representing values as analyzed in the glass, of ______________________________________ SiO.sub.2 56-60 Al.sub.2 O.sub.3 6-9 B.sub.2 O.sub.3 18-21 Li.sub.2 O >2.5-3.5 Na.sub.2 O 0.5-2.5 K.sub.2 O 5-7 ZrO.sub.2 3.75-5 PbO 0.1-0.15 Ag >0.15-0.25 Cl 0.2-0.35 Br 0.075-0.15 CuO 0.004-0.02 CeO.sub.2 0-0.5 ______________________________________ capable of being chemically strengthened to modulus of rupture values in excess of 35,000 psi with a depth of compression layer of at least 0.030 inch and demonstrating the following photochromic properties when present in cross section of about 1.5-3 mm; (a) a clear luminous transmittance of approximately 90% when free from added tint; (b) a darkened luminous transmittance at 40° C. below 35% when the glass is free from added tint and a fading rate at 40° C. such that after five minutes the luminous transmittance will have increased at least 40 percentage units; (b) a darkened luminous transmittance at 25° C. below 25% when the glass is free from added tint and a fading rate at 25° C. such that after five minutes the luminous transmittance will have increased at least 35 percentage units; and (c) a darkened luminous transmittance at 0° C. greater than 15%.
Claim 3
Dependent Claim 43 words
A photochromic glass according to claim 1 having the following approximate composition: ______________________________________ SiO.sub.2 58.9 B.sub.2 O.sub.3 20.0 Al.sub.2 O.sub.3 7.17 Li.sub.2 O 3.12 Na.sub.2 O 0.78 K.sub.2 O 5.89 ZrO.sub.2 3.86 PbO 0.12 Ag 0.175 Cl 0.24 Br 0.09 CuO 0.011 ______________________________________

References Cited (Backward Citations)

US3208860A Cited
US4043781A Cited
US4018965A Cited
US4290813A Cited
US4190451A Cited
US4130437A Cited
US4168339A Cited
US4358542A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-03 1987-04-04 1987-10-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-03 1991-04-04 1991-10-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-03 1995-04-04 1995-10-04 $7700.00 Window Closed / Lapsed

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