US4697041A
Expired / Lapsed
US
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Integrated solar cells
Assignee: New Energy and Industrial Technology Development Organization
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Filing: 1986-02-10
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Granted: 1987-09-29
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Expires: 2006-02-10
Abstract
Abstract An insulating strip is disposed between a top or/and bottom electrode layer and a photosensitive semiconductor layer, particularly an amorphous semiconductor layer, so that even if a groove traversing the top electrode layer and/or the semiconductor layer is formed along the insulating strip by laser scribing and damage occurs in respective layers, the damage does not affect the performance of the integrated solar cells. Thus, incorporation of a laser scribing process for dividing a solar cell is made practically possible. Moreover, application of a laser welding process for series-connection of divided parts of a solar cell is made practically possible.
Inventors
- 👤 Hiroshi Okaniwa
- 👤 Kenji Nakatani
- 👤 Tetsuo Sato
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 11:51
CPC Classifications
H; H10; H10F; H10F77/00; H10F77/10; H10F77/16; H10F77/169; H10F77/1692; H10F19/00; H10F19/30; H10F19/31; H10F19/33; H10F19/35; H10F77/20; H10F77/206; H10F77/211; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y10; Y10S; Y10S438/00; Y10S438/94
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
140 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate and comprising a plurality of series-connected unit cells, at least said bottom and top electrode layers being divided to form said unit cells, the series-connection being made by electrically connecting a bottom electrode layer of a unit cell of neighboring unit cells with a top electrode layer of another unit cell of said neighboring unit cells, in which at least one of the top electrode layer and the semiconductor layer of the laminate has a laser-scribed groove in a designated pattern and an insulating strip is disposed at at least one of: (a) between the top electrode layer and the semiconductor layer and (b) between the bottom electrode layer and the semiconductor layer along said designated pattern.
Claim 2
Dependent Claim
140 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate and comprising a plurality of series-connected unit cells, at least said bottom and top electrode layers being divided to form said unit cells, the series-connection being made by electrically connecting a bottom electrode layer of a unit cell of neighboring unit cells with a top electrode layer of another unit cell of said neighboring unit cells, in which at least one of the top electrode layer and the semiconductor layer of the laminate has a laser-scribed groove in a designated pattern and an insulating strip is disposed at at least one of: (a) between the top electrode layer and the semiconductor layer and (b) between the bottom electrode layer and the semiconductor layer along said designated pattern.
Claim 3
Dependent Claim
20 words
Integrated solar cells according to claim 1, wherein said insulating strip has a thickness of 0.5 μm to 50 μm.
Claim 4
Dependent Claim
17 words
Integrated solar cells according to claim 1, wherein said insulating strip in opaque to a laser beam.
Claim 5
Dependent Claim
43 words
Integrated solar cells according to claim 3, wherein said opaque insulating strip is disposed between the top electrode electrode layer and the semiconductor layer and along and under a laser-scribed groove traversing the top electrode layer but not penetrating into the semiconductor layer.
Claim 6
Dependent Claim
18 words
Integrated solar cells according to claim 1, wherein said laser-scribed groove traverses the entire thickness of said laminate.
Claim 7
Dependent Claim
26 words
Integrated solar cells according to claim 1, wherein at least one of said bottom and top electrode layers is made of a transparent electrically conductive material.
Claim 8
Dependent Claim
15 words
Integrated solar cells according to claim 1, wherein said substrate is a flexible insulating ribbon.
Claim 9
Dependent Claim
16 words
Integrated solar cells according to claim 1, wherein said photosensitive semiconductor layer is of amorphous silicon.
Claim 10
Dependent Claim
20 words
Integrated solar cells according to claim 8, wherein said photosensitive semiconductor layer comprises p-, i-, and n-type amorphous silicon layers.
Claim 11
Dependent Claim
188 words
Integrated solar cells, comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells and to electrically insulate the unit cells; each of the neighboring unit cells thus divided has a second groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; and said top and bottom electrode layers in said connection portion being electrically connected to each other; and the top electrode layer of said connection portion are electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof.
Claim 12
Dependent Claim
188 words
Integrated solar cells, comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells and to electrically insulate the unit cells; each of the neighboring unit cells thus divided has a second groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; and said top and bottom electrode layers in said connection portion being electrically connected to each other; and the top electrode layer of said connection portion are electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof.
Claim 13
Dependent Claim
29 words
Integrated solar cells according to claim 10, wherein said connection electrode is made of gold, silver, copper, aluminum, or nickel, or an alloy thereof, or an electrically conductive resin.
Claim 14
Dependent Claim
58 words
Integrated solar cells according to claim 10, wherein said connection electrode has a shape of a comb comprising a bar and teeth extending from the bar, the bar of the comb extending along the connection portion and the teeth of the comb extending from the bar of the comb onto the top electrode layer of the unit cell.
Claim 15
Dependent Claim
39 words
Integrated solar cells according to claim 12, wherein said electrical connection between the top and bottom electrode layers in said connection portion is made by laser welding the laminate and the connection electrode along said bar of said comb.
Claim 16
Dependent Claim
15 words
Integrated solar cells according to claim 10, wherein said first groove is a laser-scribed groove.
Claim 17
Dependent Claim
15 words
Integrated solar cells according to claim 14, wherein said second groove is a laser-scribed groove.
Claim 18
Dependent Claim
34 words
Integrated solar cells according to claim 10, wherein said electrical connection between the top and bottom electrode layers in said connection portion is made by laser welding of the laminate in said connection portion.
Claim 19
Dependent Claim
16 words
Integrated solar cells according to claim 10, wherein said photosensitive semiconductor layer is of amorphous silicon.
Claim 20
Dependent Claim
20 words
Integrated solar cells according to claim 17, wherein said photosensitive semiconductor layer comprises p-, i-, and n-type amorphous silicon layers.
Claim 21
Dependent Claim
15 words
Integrated solar cells according to claim 10, wherein said substrate is a flexible insulating ribbon.
Claim 22
Dependent Claim
221 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first laser-scribed groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells; each of the neighboring unit cells thus divided has a second laser-scribed groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; and said top and bottom electrode layers in said connection portion are electrically connected to each other, the top electrode layer of said connection portion being electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof; and insulating strips are disposed at at least one of: (a) between the top electrode layer and the semiconductor layer and (b) between the bottom electrode layer and the semiconductor layer along said first and second laser-scribed grooves, respectively.
Claim 23
Dependent Claim
221 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first laser-scribed groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells; each of the neighboring unit cells thus divided has a second laser-scribed groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; and said top and bottom electrode layers in said connection portion are electrically connected to each other, the top electrode layer of said connection portion being electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof; and insulating strips are disposed at at least one of: (a) between the top electrode layer and the semiconductor layer and (b) between the bottom electrode layer and the semiconductor layer along said first and second laser-scribed grooves, respectively.
Claim 24
Dependent Claim
198 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells and to electrically insulate the unit cells; each of the neighboring unit cells thus divided has a second groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; said top and bottom electrode layers in said connection portion are electrically connected to each other, the top electrode layer of said connection portion being electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof; and said first and second grooves are filled with an insulating material.
Claim 25
Dependent Claim
198 words
Integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate, in which said laminate has a first groove traversing the bottom electrode layer, the semiconductor layer and the top electrode layer to divide said laminate into unit cells and to electrically insulate the unit cells; each of the neighboring unit cells thus divided has a second groove adjacent to and in parallel spaced adjacency to said first groove and traversing at least the top electrode layer but not traversing the bottom electrode layer to form a connection portion having the same laminate structure as that of said laminate of the bottom electrode layer, the semiconductor layer and the top electrode layer being between said first and second grooves; said top and bottom electrode layers in said connection portion are electrically connected to each other, the top electrode layer of said connection portion being electrically connected to the top electrode layer of the other one of said neighboring unit cells through a connection electrode made on and bridging the respective top electrode layers thereof; and said first and second grooves are filled with an insulating material.
Claim 26
Dependent Claim
296 words
A process for manufacturing integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate and comprising a plurality of series-connected unit cells, the series-connection being made by electrically connecting a bottom electrode layer of a unit cell of neighboring unit cells with a top electrode layer of the other unit cell of said neighboring unit cells, said process comprising the steps of: preparing said substrate; forming said laminate on said substrate; disposing first and second insulating strips between said photosensitive semiconductor layer and said top or bottom electrode layer during said laminate forming step, said first and second insulating strips having designated patterns; laser scribing said laminate in and along the pattern of said first insulating strip to form a first groove cutting said laminate into said unit cells; laser scribing said top electrode layer in and along said pattern of said second insulating strip to form a second groove cutting said top electrode layer in parallel with said first groove; filling said first and second grooves with an insulating material; forming, on said top electrode layer and said insulating material filled in said first groove, a connection and collector electrode having a shape of a comb comprising a bar and teeth extending from the bar, the bar portion of said connection and collector electrode residing on said top electrode layer between said first and second groove, the teeth portion of said connection and collector electrode extending from said bar portion onto said top electrode layer of the neighboring unit cell; laser welding said connection and collector electrode and said laminate between said first and second grooves to make ohmic contact between said connection and collector electrode and said bottom electrode layer there.
Claim 27
Dependent Claim
296 words
A process for manufacturing integrated solar cells comprising a laminate of a bottom electrode layer, a photosensitive semiconductor layer, and a top electrode layer on a substrate and comprising a plurality of series-connected unit cells, the series-connection being made by electrically connecting a bottom electrode layer of a unit cell of neighboring unit cells with a top electrode layer of the other unit cell of said neighboring unit cells, said process comprising the steps of: preparing said substrate; forming said laminate on said substrate; disposing first and second insulating strips between said photosensitive semiconductor layer and said top or bottom electrode layer during said laminate forming step, said first and second insulating strips having designated patterns; laser scribing said laminate in and along the pattern of said first insulating strip to form a first groove cutting said laminate into said unit cells; laser scribing said top electrode layer in and along said pattern of said second insulating strip to form a second groove cutting said top electrode layer in parallel with said first groove; filling said first and second grooves with an insulating material; forming, on said top electrode layer and said insulating material filled in said first groove, a connection and collector electrode having a shape of a comb comprising a bar and teeth extending from the bar, the bar portion of said connection and collector electrode residing on said top electrode layer between said first and second groove, the teeth portion of said connection and collector electrode extending from said bar portion onto said top electrode layer of the neighboring unit cell; laser welding said connection and collector electrode and said laminate between said first and second grooves to make ohmic contact between said connection and collector electrode and said bottom electrode layer there.
Claim 28
Dependent Claim
18 words
A process according to claim 22, wherein said first and second insulating strips are formed by screen printing.
Claim 29
Dependent Claim
20 words
A process according to claim 22, wherein said insulating material is screen printed to fill said first and second grooves.
Claim 30
Dependent Claim
17 words
A process according to claim 22, wherein said connection and collector electrode is formed by screen printing.
Claim 31
Dependent Claim
14 words
A process according to claim 22, wherein said substrate is a flexible insulating ribbon.
Claim 32
Dependent Claim
26 words
A process according to claim 26, wherein each of said steps is conducted while said flexible insulating ribbon is transferred from a roll to another roll.
Claim 33
Dependent Claim
41 words
A process according to claim 26, wherein said photosensitive semiconductor layer comprises a plurality of amorphous silicon layers and said plurality of amorphous silicon layers are consecutively formed while said flexible insulating ribbon is transferred from a roll to another roll.
Claim 34
Dependent Claim
29 words
A process according to claim 26, wherein at least two of said steps are consecutively conducted while said flexible insulating ribbon is transferred from one roll to another roll.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-09-28 | 1991-03-30 | 1991-09-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-09-28 | 1995-03-30 | 1995-09-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-09-28 | 1999-03-30 | 1999-09-29 | $7700.00 | Window Closed / Lapsed |