Apparatus and process for the fabrication of large area thin film multilayers

Claim 3

An apparatus in accordance with claim 1 wherein means to introduce gases are introduced into a reaction zone between the first and the second electrode means in a crossflow direction perpendicular to the axis of the polygon means through an opening in the second electrode means are present.

Claim 4

An apparatus in accordance with claim 2 in which the opening is an elongated slit in the second electrode means parallel to the rotation axis of the polygon electrode means.

Claim 5

An apparatus in accordance with claim 1 wherein means to introduce gases are introduced into the reaction zone between the first and the second electrode means in a crossflow direction perpendicular to the axis of the polygon means through openings in the second electrode means followed by the exhaustion of and means to exhaust the unused gases are present.

Claim 6

An apparatus in accordance with claim 1 wherein the first polygon electrode means is electrically insulated from ground potential and the second electrode means is electrically grounded.

Claim 7

An apparatus in accordance with claim 1 wherein the first polygon electrode means is electrically grounded and the second electrode means is electrically insulated from ground potential.

Claim 8

An apparatus in accordance with claim 6 wherein the second electrode means is surrounded by and coaxial with a grounded shield.

Claim 9

An apparatus in accordance with claim 7 wherein the grounded shield contains gas inlet and exhaust openings which are oriented parallel to the rotational axis of the polygon first electrode means.

Claim 10

An apparatus in accordance with claim 1 wherein the inside of the first polygon electrode means is not in contact with the partial vacuum in the chamber means.

Claim 11

An apparatus in accordance with claim 7 wherein radiant heating elements are contained within the first polygon electrode means.

Claim 12

An apparatus in accordance with claim 1 wherein means to introduce gases are introduced into the chamber means at reduced pressure at a rate of from about 20 standard cubic centimeter per minute to about 1 standard cubic liter per minute are present.

Claim 13

An apparatus in accordance with claim 1 wherein the polygon is comprised of stainless steel or aluminum.

Claim 14

An apparatus in accordance with claim 1 wherein a plurality of first and second electrode means are contained in the chamber means.

Claim 15

A process for preparing thin film multilayers which comprises providing a vaccum chamber, containing therein a first polygon electrode means with substrates thereon, and a second counterelectrode means; heating the polygon means with heating elements contained therein; causing the polygon electrode means to axially rotate; introducing gases into the chamber means at a crossflow direction with respect to the polygon means; applying electrical power to the first and second electrode means whereby the gases are decomposed enabling deposition thereof on the substrates of the polygon means.

Claim 16

A process for preparing thin film multilayers which comprises providing a vaccum chamber, containing therein a first polygon electrode means with substrates thereon, and a second counterelectrode means; heating the polygon means with heating elements contained therein; causing the polygon electrode means to axially rotate; introducing gases into the chamber means at a crossflow direction with respect to the polygon means; applying electrical power to the first and second electrode means whereby the gases are decomposed enabling deposition thereof on the substrates of the polygon means.

Claim 17

A process in accordance with claim 14 wherein the first polygon electrode means is electrically powered by an alternating voltage power supply, whereas the second counterelectrode means is electrically grounded.

Claim 18

A process in accordance with claim 14 wherein the second counterelectrode means is electrically powered by an alternating voltage power supply.

Claim 19

A process in accordance with claim 15 wherein organosilanes and silane gases are introduced sequentially into the chamber means.

Claim 20

A process in accordance with claim 14 wherein the gases aluminum trichloride, nitrous oxide, and silane are introduced into the chamber means.

Claim 21

An apparatus in accordance with claim 1 wherein the polygon contains thereon facets.

Claim 22

An apparatus in accordance with claim 19 wherein the facets of the polygon have a width of 6 inches and a length of 17 inches.

Claim 23

An apparatus in accordance with claim 1 further including on the substrate means a coating thereover.

Claim 26

A process for preparing thin film multilayers consisting essentially of providing a vacuum chamber containing therein a first polygon electrode means with substrates thereon; and a second counterelectrode means; heating the polygon means to a temperature of from about 100° C. to about 500° C. with heating elements contained therein; causing the polygon electrode means to axially rotate with a power source; introducing means to introduce gases into the chamber means at a crossflow direction with respect to the polygon means; and applying electrical power to the first and second electrode means whereby the gases are decomposed enabling deposition thereof on the substrate of the polygon means.

Claim 27

A process for preparing thin film multilayers consisting essentially of providing a vacuum chamber containing therein a first polygon electrode means with substrates thereon; and a second counterelectrode means; heating the polygon means to a temperature of from about 100° C. to about 500° C. with heating elements contained therein; causing the polygon electrode means to axially rotate with a power source; introducing means to introduce gases into the chamber means at a crossflow direction with respect to the polygon means; and applying electrical power to the first and second electrode means whereby the gases are decomposed enabling deposition thereof on the substrate of the polygon means.

Claim 28

A process in accordance with claim 14 wherein there is selected silane gases resulting in the deposition of hydrogenated amorphous silicon.

Claim 29

A process in accordance with claim 14 wherein there is introduced sequentially into the chamber means gases selected from the group consisting of silane, and ammonia and silane.

Claim 30

A process in accordance with claim 14 wherein the gases silane and nitrous oxide and silane are introduced sequentially into the chamber means.